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E&E Exchange
Welcome to the Energy & Environment (E&E) Exchange,
a blog dedicated to science and engineering topics that are (generally) related
to energy and the environment. This blog is meant to encourage discussion about
the challenges and possibilities surrounding sustainability through science and
technology. The blog's owner, David Lates (aka cheme_wordsmithy), is a technical
writer and engineering editor at GlobalSpec, the company that powers CR4.
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Posted October 31, 2012 12:00 AM
by cheme_wordsmithy
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"The power of the sun… in the palm of my hand."
So said Dr. Otto Octavius, the infamous scientist turned
supervillain, in the movie Spiderman 2.

What he was referring to in that quote was the fusion
reactor he had created, a device that generated a self-sustaining energy source
like that of the sun. It was this device that quickly turned out of control,
generating a strong magnetic force that nearly leveled the building and resulted in the death of his wife. From then on, Dr. Octavius was Doctor Octopus -
Doc Ock.
(<--It will stabilize! Credit:
Chanmainor.com)
The reality of fusion is not too far off from the Hollywood
version. Fusion is the process of combining two atomic nuclei together to
create one new (heavier) atom. Its simplest form involves two hydrogen atoms
(one proton each) combining to form one helium atom (two protons). This process
of fusion produces massive amounts of energy, as exemplified most prominently
by the sun that heats our planet. The hydrogen bomb, which uses a nuclear explosion
to generate the high temperatures needed for the reaction, is the most
prominent working example of fusion we have.

(Fusion reaction. Credit:
CCFE-->)
Harnessing that energy in a useful (i.e. none destructive)
manner though is a real challenge for the physicists and engineers working to
build fusion reactors. To achieve high enough fusion reaction rates to make
fusion viable as an energy source, the fuel (two types of hydrogen - deuterium
and tritium) must be heated to form a plasma at over 100 million degrees
Celsius. Wow that's hot! When these
temperatures are achieved, the fuel begins fusing to create helium atoms. The
heat from fusion then provides the energy to sustain the plasma's temperature,
and the excess heat can be harnessed to heat steam to drive a turbine and
generate electricity.
The most promising fusion technology involves a machine
called a tokamak. The tokamak utilizes a ringed magnetic confinement system; a
circular bottle surrounded by strong magnetic fields. This confinement isolates
the plasma from the outside environment in order to maintain stable
temperatures and prevent contamination with impurities. Check this link for a picture of ITER: the
world's largest tokamak.
The latest developments in fusion technology involve the
Joint European Torus (JET), Europe's premier magnetic confinement fusion
facility based at Culham, UK. It has
completed eleven months of tests to simulate the environment inside the ITER
fusion facility being built in the South of France, and to prototype key
components. JET is basically a mini-version of ITER, using the same materials
for its wall - beryllium and tungsten. These materials have been carefully
selected in order to minimize plasma contamination and prevent fusion fuels
from becoming trapped in the wall.

(The interior of JET, showing its new wall of beryllium and
tungsten. Credit: EFDA)
Initial tests with beryllium and tungsten have proven that
they work much better than carbon-based wall materials. Specifically,
experimenters found the amount of fuel retained in the wall was at least ten
times less with the new design. These results may convince the ITER project to
skip its initial operation with carbon, which would save the project both time
and money.
Experiments at JET will restart in 2013, with the goal of
demonstrating full deuterium-tritium based plasma tests by 2015. This is an
exciting prospect for the development of the ITER, which plans to create its
own first plasma by 2020. The possibility of commercial fusion energy is definitely
a bright light amidst the clouded future of sustainability, and I will be
keeping my eye on the progress.
Paving the
Way for Commercial Fusion Power Plants - Science Daily
How
Fusion Works - CCFE
The Science -
ITER
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Posted October 08, 2012 12:00 AM
by cheme_wordsmithy
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Since global warming became a hot topic, methane (CH4) gas
emissions have been a point of concern on the backburners of carbon dioxide. Considering
that methane's global warming potential is 72 times that of carbon dioxide over
20 years and 25 times over 100 years, it shouldn't be ignored. Two primary
contributors to methane gas production in the atmosphere are cows and
automobiles, raising the infamous question 'does a cow pollute more than a
car?' For those concerned about that debate, here is some insightful reading on
cow backpacks.
One of the ways methane emissions are curbed in cars (and
gas turbines, another big methane producer) is through the use of catalysts to
encourage combustion. In cars, these are found in catalytic converters, which facilitate
the oxidation (burning) of methane along with many other nasties produced by
the engine. The combustion reaction for methane is:
CH4 + 2O2 --> CO2 + 2H2O

(<-- The catalytic converter - an asset to the environment and a target for car thieves... Credit: Wired)
In traditional catalytic converters, though, it's hard to
find catalysts that fit the bill for encouraging this reaction. Catalysts are
designed to assist chemical reactions by making them happen more efficiently
and effectively. Currently available catalysts for methane combustion are not
100% efficient however, allowing a lot of unburned fumes to leave with the
exhaust. The difficulty is, methane combustion catalysts need to be both active
enough to do their job effectively, and stable enough to withstand the harsh
conditions surrounding the process - particularly in regards to temperature.
A new catalyst for methane, developed by a collaboration of
catalysis and energy specialists, could potentially fix these problems. It achieves
complete methane combustion at 400°C, the approximate exhaust temperature for
normal cars. This is crucial, considering most other catalysts can only achieve
100% efficiency at temperatures above 600°C. The catalyst also resists
breakdown from hotter temperatures up to 850°C, which can occur when more load
is put on the engine (climbing hills and driving fast).
(Representation of the catalyst's core-shell structure on an
aluminum oxide surface. Credit:
University of Pennsylvania -->)
The new catalyst has yet to be tested under real-world
conditions, which could be drastically different than the performance recorded
in lab. Vehicle exhaust in particular, which contains catalyst-disabling
components (like sulfurous compounds, oil-additives, and steam), could deter
the effectiveness of the substance. However, this development is a big first
step towards a real solution, and opens the doors for creating similar
structures which may perform better.
References
Catalyst
Could Zap Methane Emissions - CR4
Cheaper
and Cleaner Catalyst for Burning Methane - Science Daily
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Posted September 27, 2012 12:00 AM
by cheme_wordsmithy
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In the last decade, particularly the last four years, we
have seen a tremendous push for electric vehicles (EVs). The end goal of many
advocates of EVs is to see them replace conventional gasoline powered cars to
reduce exhaust pollution and limit the use of fossil fuels.
And while this goal in some ways has more to do with the
source of grid power, there are already enough difficulties with the cars
themselves. In comparison to conventional cars, EVs are much less practical and
more expensive. But newly developed fast chargers are looking to change this.
One of the biggest challenges for EVs is battery charging.
Most designs have an average range of less than 100 or so miles per charge. Tesla's
Model S has one of the highest ranges, at ~300 miles per charge. But even a 300
mile range presents a problem for long distance travelers looking to go
hundreds of miles in one trip, since charging can take hours or days.
Specifically, it takes the Chevy Volt four hours, the Nissan Leaf seven hours,
and the Tesla Model S nearly twelve hours (whoa!)
to charge on a regular outlet modified for 240V (the voltage of most charging stations). In this way, the 450 mile road trip I took
many times from my hometown to my college would take two days rather than 7 ½
hours. That's just not happening.

(A Tesla Roadster at a traditional charging station. Credit: AP Photo | Rick Bowmer)
A new DC fast charging station developed by Tesla Motors presents a solution to this problem. These stations deliver DC power directly to the
battery, bypassing the car's on-board charger by converting AC grid to DC
outside the car. A communications link in the charging cord allows the car's
battery management system to control the rate of charge to avoid damage to the
battery. In this way, the fast chargers are designed to limit charging to 80%
of full capacity to avoid overcharging or battery damage.
While standard 240V stations provide only 3.3 kW power, fast
chargers can deliver from 20 kW to 100 kW depending on the design. This reduces
charging times by hours, allowing most EVs to charge to 80% in just around half
an hour or so.
As convenient as the fast-chargers seem, they have many drawbacks.
First and foremost, the capital costs are reportedly very high, with individual
charging units costing tens of thousands of dollars. In addition, fast-chargers
may not be as frequently used, considering that most EVs are purchased for
commuting and are charged overnight or during the day. Compounded together,
these factors make it difficult to justify an investment in these stations.
Other foreseeable barriers include the hefty demand that
these stations put on the grid. Utilities often charge a demand fee each month
for stations that expect to draw a lot of power. This fee is paid regardless of
how much use the station gets.
Finally, even if battery costs come down and the grid
expands to allow for more electric vehicles, I can't see Americans choosing
electric over gasoline. Often people are willing to pay more for convenience,
but right now conventional cars are both less expensive and better performing. EVs
will need to grasp at least one edge in the marketplace before they can
feasibly compete for our wallets.
References
Battle
of the Batteries - Gigaom.com
Technology
Review
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Posted September 03, 2012 12:00 AM
by cheme_wordsmithy
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Battery technology is something I tend to take for granted.
Without it, I couldn't run my car or my cell phone or my mp3 player or (heaven
forbid) my watch. And the technology has come a long way since its invention in
1800; from Alessandro
Volta's expansive setup of electrochemical cells all the way down to those
button-sized pieces used in calculators.
As our world is becoming smarter and more mobile, batteries
are becoming increasingly important. In the smartphone realm, sadly, batteries
are having a tough time keeping pace with the race to the first handheld
supercomputer. With bright displays, lots of processing power, and more
capabilities in a small and lightweight package, smartphones fly in the face of
everything good battery life entails. It's the only thing those flip-phone
owners (me) can still brag about (besides lower phone bills).
Efforts to increase battery life usually revolve around
finding new ways to decrease power consumption. But a new product in
development by LG Chem is taking a different approach. The project is for
"cable batteries", batteries made to be flexible like cables or wires. They are
designed to work even when tied into knots or bent in any number of ways. The
idea is to incorporate these batteries into headphones, phone cases, clothing,
jewelry, and other on-person items and accessories in order to help charge or
provide power for small electronic devices.

Making the battery starts with thin strands of copper wire
coated with nickel and tin - two active electrode materials. The strands are
woven into a yarn and formed into a strong spring to serve as the battery's
backbone and anode. The other parts of the battery are wound around the anode,
including an aluminum wire as the main component of the cathode. Next, the
battery is drawn through a slurry containing lithium cobalt oxide cathode
material and then dried. After being wrapped in protective layers, the product
is completed by pouring in a liquid electrolyte used to carry charge when the
battery is hooked up.
Currently, these batteries don't output a ton of energy. IG
Chem says a 25 centimeter long prototype can run a small fourth generation iPod
shuffle for 10 hours while in its bent shape. But compared to other flexible
batteries that have been developed in the past, the discharge of these cable
versions is relatively stable under stress. Also, previous types of flexible
batteries were mostly made as flat sheets, which severely limitwwed their
practical application. Cable batteries offer a lot more creative options for
designers.

(A cable-shaped lithium-ion battery powers an LED display
even when twisted and strained. Credit:
LG Chem)
IG Chem hopes to boost the performance of these batteries as
their work continues. Several design aspects, such as new anode materials
currently being tested, could significantly increase efficiency and
performance. Researchers at the company have high hopes, and say the technology
could be ready for mass production in about five years.
I think this type of innovation has a lot of promise,
especially for making everyday items "smarter". For instance, wearable
electronics have been the focus of efforts to give sportswear the ability to
monitor an athlete's health and performance during training. Considering the
flexibility of the bendable battery design and the breadth if possibilities,
this is just one of the potential applications that could be utilized in years
to come.
References
Cable-Type
Flexible Lithium-Ion Battery - Advanced Materials
Technology
Review
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Posted August 20, 2012 9:00 AM
by cheme_wordsmithy
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Wind power has always been an interesting area of technology
to look at, if for no other reason than the idea of harvesting "free" energy
from something as simple as wind currents. But the technology itself is also
pretty fascinating. Let's just say we've come a long way from old fashioned
windmills…
From:

to

(Credit: Siemens AG,
Munich/Berlin)
Here's a rotor blade of the world's largest wind turbine (5 MW)
being transported to the construction site through a small town.

Make Way! (Credit:
Siemens AG, Munich/Berlin)
Wind power has been a steadily growing renewable energy
source in the U.S. over the last decade. In this time, improvements in
technology have made wind turbines larger, lighter, and longer to increase
efficiency and capacity. In 2011, wind power comprised 32% of additions to U.S.
electric generating capacity. Unfortunately, much of this growth has stemmed
from federal monies and tax credits such as the Product Tax Credit (PTC) and
Advanced Energy Manufacturing Tax Credit. These are likely to expire by the end
of 2012.
Some new projects in the country are still pushing forward,
however. While all current wind energy in the U.S. is land-based (mostly located
in the Midwest and Great Plains), some 20 offshore wind projects representing
2000 MW of capacity are in the works. This includes Cape Wind, a company that since
the early 2000's has aimed to construct 130 wind turbines with a max capacity
of 420 MW on Horseshoe Shoal in Nantucket Sound. Just last week the company received FAA approval for their
project, which certifies the farm will pose no hazard to aircraft flying in the
region.
Offshore wind provides a number of advantages over
land-based generation, most notably higher average wind speeds. Noise
pollution, loss in scenery, and injuries to birds are also not problems when
building offshore. Cost is really the biggest problem, which is affected by
construction, operation, and grid connection difficulties due to being located
on the water. Specifically, there is no existing infrastructure for connecting
offshore wind to the grid, so each project must create its own solution. And
assembling these massive machines out on the water, as you can imagine, is not
an easy task.
Still, Cape Wind and other projects like it promise lower
electricity costs for their local customers through the 'price suppression' effect
of renewable sources, which has been documented in Europe.
Despite all the incentives and apparent progress, wind power currently chips in only 3% of the nation's total electricity output, and its true economic
sustainability will be realized a year from now if existing and startup wind
projects are left on their own financially.
Cost-effectiveness has always been the question, specifically if the money used to build wind-farms could not be better used someplace else (such as insulating homes to reduce energy consumption and waste). The prospect of cost-effectively
utilizing personal (residential) wind turbines is not yet an effective alternative either. At $6,000
and 400 kWh a month, it would take the average homeowner 12 years or more
to make back the initial cost in energy savings. Safe to say, wind power still
has a long ways to go.
References
Ars
technica - Wind power
Boston
Globe - FAA rules Cape Wind will not affect air traffic
Technology
Review - A Mighty Wind Turbine
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Posted August 06, 2012 12:00 PM
by cheme_wordsmithy
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I always thought ice was pretty cool. We cool things down
with it, skate and play hockey on it, make sculptures from it, and sometimes
even fight evil mutants with it…


(Credit: X-men Wiki |
The Adventurers Club)
But when dealing with a lot of technologies, ice is not so
much fun. Icing (no, not the hockey penalty HUSH) is a big problem for roads,
carbureted engines, wind
turbines, air conditioners, refrigerators, planes, and electrical
and telecommunications equipment. The buildup of ice can cause poor equipment
performance or failure and can be a severe safety hazard in certain situations.
Icing Problems
A number of ice-related accidents and hazards are related to
extreme weather. Those of us in the northeastern U.S. know particularly well
the dangers and damage that ice storms can cause to roads and power lines. In
these cases, the best we can hope to do is avoid the bad weather where we can,
and have safety measures and procedures in place to deal with it when it comes.
But even in warm climates, certain technologies face icing
problems during normal operation. For example, as airplanes pass through clouds
on takeoff and landing, they can strike ice particles and cloud-borne water
droplets that can be transformed into ice. Refrigerators and air conditioners
can also lose their cooling capacity due to accumulated ice. In these cases, anti-icing
technology would be a convenient solution.

(Credit: Ice
accumulation on a rotor blade)
At GE Global Research in Niskayuna, NY, a team of scientists
led by Azar Alizadeh is working on just that: anti-icing surfaces.
Understanding the
Freeze
Research into ice-phobic materials has been going on for the
past 50 years, but scientists say the limited level of success shows a lack of
understanding of the fundamentals of water-surface interactions. This includes
an understanding of the process through which water cools when in contact with
a surface, the onset of ice nucleation, and the detailed nature of water layers
adjacent to a cold surface.
By conducting freezing and heating experiments on a number
of different types of surfaces, and using instruments such as a high speed
camera and infrared thermometers, the team at GE pinpointed that surface structure
(roughness) and surface chemistry (hydrophobicity) can dictate heat transfer as well as the rate of ice nucleation.
These parameters have been the focus of new superhydrophobic anti-icing
materials being developed by GE and other organizations.

One example includes SLIPS (slippery liquid-infused porous
surfaces) aluminum developed by Harvard University. In a recently-published
study, the material demonstrated resistance to icing in high humidity and
cold temperature environments.
(<-- Still images simulating ice formation by deep freezing and
subsequent deicing. Credit: Harvard
University)
What's So E&E
About It?
You may be wondering what makes anti-icing technology an
environmental/energy topic. The reality is that anti-ice materials have the
potential to save a lot of energy and reduce current dependence on certain
chemical agents. In regards to aircraft, some 25 million gallons of deicing
agents are currently used on planes taking off from U.S. commercial airports
each year, and there is also a lot of energy wasted on electrical heating
systems used for ice prevention in-flight. Using materials like the SLIPS aluminum
for aircraft could eliminate the need for these chemical and heat treatments.
Anti-icing materials could also potentially prevent failure and help maintain
an effective cooling capacity for air conditioners and refrigerators in humid
environments.
References
GE Scientists Demonstrate Promising Anti-Icing Nano Surfaces
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