I cut and pasted the info below from the Emoteq Megaflux catalog (emoteq.com). It supports Guests' definition from above, and also includes a mechanical definition of a motors time constant.
Electrical Time Constant (TE)
is the ratio of inductance
LM in Henries, to the resistance RM in Ohms. This is the
inductance and resistance as measured across any two
phases in a delta or wye configuration.
TE = LM/RM
Note: This definition is from a brushless motor catalog, You would measure through the armature leads with a brush motor.
Mechanical Time Constant (TM)
is the time required to
reach 63.2% of the motors maximum speed after the
application of constant DC voltage through the commutation