I just stumbled upon a very interesting Web site: listeningtowords. Here's where you can "find, listen, and discuss free lectures from around the web."
At first glance I see:
A Scientist in Space/Searching for Earth-like Planets: NASA's Kepler Mission
by Janice Voss @ Astronomical Society (2007-03-07)
Glimpsing the Edge of the Universe: Results from the Hubble Space Telescope
by Bruce Margon @ Astronomical Society (2007-01-24)
The Planet Pluto: Maligned but Not Forgotten
by Dale Cruikshank @ Astronomical Society (2006-11-08)
Dark Energy and the Runaway Universe
by Alex Filippenko @ Astronomical Society (2006-11-04)
Estimating the Chances of Life Out There
by Frank Drake @ Astronomical Society (2005-04-20)