Login | Register
The Engineer's Place for News and Discussion®

Previous in Forum: Orifice Plate Sizing   Next in Forum: Carbon/Stainless Cross Contamination
Close

Comments Format:






Close

Subscribe to Discussion:

CR4 allows you to "subscribe" to a discussion
so that you can be notified of new comments to
the discussion via email.

Close

Rating Vote:







12 comments
Guru

Join Date: Jul 2008
Posts: 929
Good Answers: 55

What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/10/2012 2:16 AM

I am having difficulty identifying the metal alloy that was developed to have the same thermal expansion properties as borosilicate glass and Pyrex.

Thanks

L.J.

__________________
"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer
Register to Reply
Interested in this topic? By joining CR4 you can "subscribe" to
this discussion and receive notification when new comments are added.

Comments rated to be Good Answers:

These comments received enough positive ratings to make them "good answers".

Comments rated to be "almost" Good Answers:

Check out these comments that don't yet have enough votes to be "official" good answers and, if you agree with them, rate them!
2
Guru

Join Date: Apr 2011
Posts: 1850
Good Answers: 64
#1

Re: What alloy has the same C of TE as borosilicate glass & Pyrex?

05/10/2012 4:31 AM

Kovar

Tungsten or Molybdenum can also work.

Register to Reply Good Answer (Score 2)
Guru

Join Date: Jul 2006
Posts: 919
Good Answers: 74
#2

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/10/2012 10:34 PM

L.J.

Answer #1 is correct. You can purchase kovar seals commercially. Also, you can purchase tubular graded seals in which a series of glasses are sealed, so the differences in thermal expansion from one to the next is always low enough to avoid cracking or shattering. At least, all the above was true back in my chemistry days.

--JMM

Register to Reply
Guru

Join Date: Jan 2008
Posts: 1698
Good Answers: 57
#3

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/10/2012 11:11 PM

Sorry to be vague. But This is definitely rarified area. I saw a Nature / Science ? program about the casting of a very large parabolic reflector (by the University of Arizona?) It was pyrex, with hexagonal mineral foam cores to make the thermal mass minimal. They needed minimal thermal expansion. And succeeded.

Look into it.

Register to Reply Score 1 for Good Answer
Guru

Join Date: Jul 2008
Posts: 929
Good Answers: 55
#9
In reply to #3

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 3:59 PM

You are not being vague Leveles and your response is appropriate to the context. Thank you.

However, I am only attempting mechanical fixturing.

The material I am using in casting these blanks is not a borosilicate or other low expansion glass but common plate glass. I can get away with using this material.

The mirror is so light for it's size and has such low thermal mass, that it reaches thermal equilibrium quickly and stays close to ambient temperatures easily.

The optical figure is not impacted under changing temperature conditions and is usable most all the time.

L.J.

__________________
"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer
Register to Reply
Guru
Hobbies - DIY Welding - New Member

Join Date: Sep 2007
Posts: 1332
Good Answers: 49
#4

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 7:23 AM

Kovar (NiFeCo) is often used. In order to make a gas tight seal to borosilicate glass, the kovar must be oxidized. There are volumes written about proper oxidation of kovar. There are also methods for making gas tight seals (housekeeper seals) that don't require expansion matching.

Register to Reply
Guru
United Kingdom - Member - Old New Member

Join Date: Jul 2005
Location: South east U.K.
Posts: 2296
Good Answers: 31
#6
In reply to #4

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 10:53 AM

This is correct, the kovar must have an oxide layer if you are sealing by melting the glass. If you use a pyroceramic seal or frit then the kovar needs to be clean but will oxidise when the pyro is air baked to cure it. Worth noting that kovar is the common trade name for this controlled expansion alloy but it is still also known as telcoseal 2 or (I think) nilo 42.

__________________
Choose a job you love, and you will never have to work a day in your life. (Confucius)
Register to Reply Score 1 for Good Answer
Power-User

Join Date: Mar 2008
Location: MA 01864, USA
Posts: 453
Good Answers: 7
#7
In reply to #6

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 12:09 PM

Any time when we do metal to glass seal we do one of the following

1. Have glass which is really a mix of glass and metal like lead boroate glass which is still very common for Kovar, invar and ally 42 sealing

2. If we have glass chemistry based on silicate then we have to go through control oxidation that is commonly done at 40 to 50% humidity at 850oC temperature with no dual. This is one of the common practice since most of the thickfilm furnaces run at that temperature and I was lazy to change it and controlled with ramp rate

__________________
Masyood
Register to Reply Score 1 for Good Answer
Guru

Join Date: Jul 2008
Posts: 929
Good Answers: 55
#10
In reply to #7

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 4:11 PM

Masyood wrote: "If we have glass chemistry based on silicate then we have to go through control oxidation that is commonly done at 40 to 50% humidity at 850oC"

Been there, done that!

My first experience with Kovar was in the design of hermetically sealed. nitrogen filled housings which had INGAS arrays for IR and Near-IR imaging sensors. The optical window was a borosilicate and was soldered to a Kovar aperture plate.

I could not remember the material and couldn't locate it using conventional search engines.

Hence this inquiry.

Thanks

L.J.

__________________
"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer
Register to Reply
Power-User

Join Date: Mar 2008
Location: MA 01864, USA
Posts: 453
Good Answers: 7
#5

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 10:20 AM

Alloy 42, invar, kovar, Moly and list goes on will be compatible with Borosilicate glass and pyrex

__________________
Masyood
Register to Reply Score 1 for Good Answer
Guru

Join Date: Jul 2008
Posts: 929
Good Answers: 55
#8

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 3:49 PM

It was not my intention to cast glass around the metal.

I am looking for an easy method of providing redundant security for a large telescope; something that would constrain a 55 pound, 24 inch, honeycombed mirror and prevent damage in the event that the primary fixturing failed. (A solid disk of the same approximate geometry would weigh in excess of 125 pounds!)

Conventional mechanical clips introduce too many problems.

I considered bonding an array of narrow straps to the back of the mirror, each with an appropriate adhesive, and using the strips to provide anchors for "Hail Mary" tethers, each made from a loosely fitted, multi-stranded stainless steel cable (fishing leader?)

My concern for thermal expansion developed when I tried to anticipate the effects of bonding a 3 inch long by 1 inch wide metal strip to a vitrified substrate with a different C of TE.

Would the different rates of thermal expansion generate astigmatism in the optical figure?

When you consider that the optical surface is accurate to better than 1/30th of a wave of light in the visible spectrum, my concern at preventing stress in the glass is more easily appreciated.

However, once you gentlemen successfully identified the material for me (Thank you!) I went and priced it. Talk about a cold shower!

Big as this mirror is, I'm not building another Hubble and do not have NASA's budget! (In fact even NASA doesn't have NASA's budget any more!)

I had bad experiences working with Molybdenum (too brittle) but Tungsten might work.

Thanks, all of you, for your support.

"Time to bake the donuts!"

Laughing Jaguar.

__________________
"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer
Register to Reply
Guru
Hobbies - DIY Welding - New Member

Join Date: Sep 2007
Posts: 1332
Good Answers: 49
#11
In reply to #8

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

05/11/2012 7:24 PM

Remember, 1) that anything you attach to the mirror is only matched over a limited temperature range and 2) that the expansion match is good only when the two parts (glass and metal) change temperature at the same rate. Since you require a safety harness, I suggest you design something that doesn't contact the mirror unless the primary support fails.

Register to Reply
Guru
Popular Science - Weaponology - bwire Hobbies - Car Customizing - New Member

Join Date: Dec 2007
Location: Upper Mid-west USA
Posts: 7544
Good Answers: 97
#12
In reply to #8

Re: What Alloy Has the Same C of TE as Borosilicate Glass & Pyrex?

06/17/2012 6:36 PM

an air cushion type suspension maybe; pulling answer out of i think i think out of well where is that fortune cookie calculator.....?

__________________
If death came with a warning there would be a whole lot less of it.
Register to Reply
Register to Reply 12 comments
Interested in this topic? By joining CR4 you can "subscribe" to
this discussion and receive notification when new comments are added.

Comments rated to be Good Answers:

These comments received enough positive ratings to make them "good answers".

Comments rated to be "almost" Good Answers:

Check out these comments that don't yet have enough votes to be "official" good answers and, if you agree with them, rate them!
Copy to Clipboard

Users who posted comments:

bwire (1); jmueller (1); Laughing Jaguar (3); leveles (1); Masyood (2); Nigh (1); truth is not a compromise (1); welderman (2)

Previous in Forum: Orifice Plate Sizing   Next in Forum: Carbon/Stainless Cross Contamination