I am looking for information on usage of stainless steel grade 304l as material of construction for hydrogen peroxide manufacture in the organic loop (auto oxidation plant). I will be very thankful if readers can share their experience.
Depending oon the purity required- the peroxide will coorrode the 304L, you just might be better using Zirconium ...
Todays metal prices, whatever you select will be too expensive to use.
milo
milo
__________________
People say between two opposed opinions the truth lies in the middle. Not at all! Between them lies the problem, what is unseeable,eternally active life, contemplated in repose. Goethe
Contrary to previous advice, 304 will work well-depending on temperature and H2O2 strength. All metals contacting H2O2 MUST be passivated with a wash of dilute nitric acid. You should contact SOLVAY technical service for particular details. Generally H2O2 concentration is limited to 34% or lower to avoid self ignition dangers on accidental release on combustible materials. Higher concentrations require careful management and adherence to exacting storage and containment conditions.
Even with the 'best' storage & handling, H2O2 WILL spontaneously decomose slowly, releasing oxygen--which must be removed from the 'vapor space' to pevent deadly conflagration potential. Please contact SOLVAY and get well educated and follow the advice of some real EXPERTS--you ARE dealing with a dangerous material.
Just read the pdf link http://www.wahchanglabs.com/pdf/zirconium/0004.pdf and understand that 304L is not without its drawbacks. "depending on temperature and H2O2 strength" sounds like more of a disclaimer than "Zirconium should be considered an ideal option for working safely and efficiently with hydrogen peroxide."
Mssr Agent for Solvay correctly establishes that it is the nature of peroxide that creates dangers. He just fails to see advantages of the suggestion of zirconium materials based on data of catalysis, decomposition initiation, and comparative rates of gas evolved and corrosion between the metals being discussed.
BTW, I sign my posts
milo
Not working for a pharmaceutical company that might not want competition in their product space
__________________
People say between two opposed opinions the truth lies in the middle. Not at all! Between them lies the problem, what is unseeable,eternally active life, contemplated in repose. Goethe
Users who posted comments:
Anonymous Poster (1); Milo (2); MUKULMAHANT (1)