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Is it Possible to Generate 3 Fuels from the Same Algae?

07/18/2012 10:31 PM

I am not a chemist so I have run into a question I need to ask the help of others in regards to using algae for a fuel source. If you first extract the oil from the algae you are left with biomass. This can be fermented to create ethanol. Would the leftover biomass from that process be able to then produce methane or would the necessary ingredients already be extracted? Or is it a matter of order? That is should you take the biomass and then produce the methane first and then the resulting biomass could then be used to create the methanol??

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#1

Re: Is it possible to generate 3 fuels from the same algae?

07/18/2012 11:01 PM

Your questions start in the middle of nowhere and go in all different directions.....You state no motive or purpose and no goal....What would be left after each process would depend on what algae strain you are using, the method of process treatment, basically you would need to know pretty much what your fuel production goals were etc etc.....

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#2

Re: Is it possible to generate 3 fuels from the same algae?

07/18/2012 11:36 PM

In reply to your questions:

1.No, yes.

2.Yes.

3. Why do you think this can work?

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#3

Re: Is it possible to generate 3 fuels from the same algae?

07/19/2012 5:03 AM

What is the point, what is the expected efficiency at every step? Plenty of things can be done with dismal efficiencies. That is the question you have to answer to yourself.

Very smart people have difficulties with the first step alone.

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#4

Re: Is It Possible to Generate 3 Fuels from the Same Algae?

07/19/2012 10:51 AM

Chemistry is a complicated science that baffles many laymen. Bio-chemistry baffles many chemists. So it is natural for a layman to miss phrase a bio-chemistry question. How you've phrased your questions will give you nearly useless information so I will try to answer both your actual question and then what I think you meant to actually ask.

If you first extract the oil from the algae you are left with biomass. This can be fermented to create ethanol. Would the leftover biomass from that process be able to then produce methane or would the necessary ingredients already be extracted ?

As long as Carbon and Hydrogen atoms exist in this dross then methane can be produced. However, with today's technology the energy return from this methane will be far less than the energy required to make this transformation. Possibly in the future a catalyst or bacterium maybe engineered to make this a productive transformation. I suspect that more energy will be extracted by on site combustion of the dross than trying to obtain a second refined fuel from the remains. The uncertainty here is the chemical make up of this residue that has been produced. I suspect different algae will produce different oils and different oil extract techniques will leave different residues.

However, co-generation in general is a good idea. This dross, once analyzed, maybe suitable for feed stock, other chemical resources or who knows what.

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#5
In reply to #4

Re: Is It Possible to Generate 3 Fuels from the Same Algae?

07/19/2012 4:10 PM

Thank you redfred. Appreciate your thoughtful answer. You understood my question. One of the other replies seemed to think all I said was totally unclear. Anyway, what you said is interesting. I was unaware of the possible chemical variations of algal oil from different strains.If I understand you then you may be suggesting that different species may be generating oils with different chemical compositions? I have read that there are various physical structures for each species of algae and that each of these may demand a seperate approach to extraction of the oil. What works for one is inefficient for another. I remember an entry on Oilgae.com that was encouraging people to think of more purposes for algae than just using it to generate fuel. I realize that has been the bent I have taken here but your answer brings this point up again. Thank you.

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#6

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/19/2012 10:46 PM

Yes. First select an algae that has a fair lipid content. Extract the lipids as diesel fuel, reacting them with ethanol from step 2 if they won't work direct. Run the residue from the lipid extraction through the IRE multimicrobe process to convert the polysaccharides to ethanol, and burn the residue left to generate electricity to charge electric vehicles. Doing it and making money doing it may not have a positive correlation.

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#7

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/20/2012 12:29 AM

I've experimented with bio-fuel in my backyard, and I would extract the oil, then I would cook the dross and extract syngas after drying it, then I would compress the charcoal that was left. The oil extraction part might be tricky unless the oil can be separated easily by flotation or TSP. I haven't used algae or extracted oil from algae yet.

As to the syngas part, that I know for sure will produce quite a bit of hydrocarbons that can be used to fuel the syngas process itself. And the charcoal leftovers from the syngas process are nearly pure carbon. If the algae is dried and put directly into the syngas pot, and the draw pipe from that is sent up as a feed to a distillation column, then it may be possible to get the oil that way.

I use my charcoal from syngas process as activated charcoal for filtration, and as a base for creating pure carbon stuff like small crucibles for metal refining or just as fuel.

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#9
In reply to #7

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/20/2012 1:38 AM

Hello Deefburger. I am not clear on something. What process were you using to extract the oil in your backyard? It sounded like you are talking about extracting it from algae but later you say that "I haven't used algae or extracted oil from algae yet." So I am needing a little clarification here. Btw, what were you using your syngas for? Was it running an engine? Interesting about the distillation column. That wouldnt be too hard to try. Thanks.

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#11
In reply to #9

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/20/2012 2:09 AM

I was using bio mass. Algae is just one form. As for the process, you can do a decent job creating syngas from bio mass using an old pressure cooker. Put dry(as in little or no water) bio mass inside and run a pipe from the vent down to the underside of the pressure cooker. Install a gas burner there and let the gases vent into the burner.

You don't need all of the gasses to run the process, so if you split the pipe to a condenser, you can capture some of the lightweight hydrocarbons and most of the heavier ones in a cold tank. The rest you burn under the pressure cooker. You have to start the process with another fuel, but only until the syngas starts to form. Then it should run on it's own gas.

CAUTION! Make sure your pipe and vent don't clog or just install a pressure relief valve in the lid of the pressure cooker or you may be making a bomb! An over pressure valve from a water heater should work fine and is cheap and easy to get. Heck, install two for good measure.

If your algae has a lot of oil in it, then this method using the splitter on the pipe to a cold tank should capture it. Another way with oily bio mass is to send ALL of the syngas to the cold tank, and then tap the top of the cold tank for the lighter gasses and send those to the burner.

Oil extraction without heat is trickier. TSP can break the cell walls and help to float the oil out, but then you have to remove the TSP. I prefer just making syngas and condensing the oils out, burn the lighter fuel and the cooker will be holding only charcoal when the process is complete.

Some coal fired power plants use this method on a large scale to fuel turbines, and then they use the charcoal to fuel steam turbines. More efficient plants take the waste heat from the syngas process and feed it into the steam process.

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#12
In reply to #11

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/21/2012 12:57 AM

That is interesting about condensing the oils out. I havent heard that one yet but I have to tell you that it does make sense. I got the opportunity to go to a tire recycling plant in Albuquerque that heated tire shreddings until near their flash point and then at different points they had taps on this pipline and extracted various petrochemicals one of them being diesel. ( stunk to high heaven. smelled just like burning tires. lol) . They mentioned also extracting monomers for making ....plexi?? or some type of plastic. It was interesting because this setup also worked for any kind of plastics that you could imagine even thermosetting plastics like fiberglass. So for instance instead of burning the fiberglass off of circuit boards, it was recycled back into petrochemicals and the electronics with the precious metal content were gathered at the end of the process. When you say "cold tank" I am not absolutely sure of what you mean but I am envisioning that the pipe with the mixture of hot gasses passing through it is surrounded by a tank with cold circulating water in it? Basically a heat exchanger??

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#13
In reply to #11

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/21/2012 1:04 AM

I was thinking later that if I have an inkling of what this condensing cold tank is it may work like hydrothermal activity in geology. Not sure if you are familiar. As superheated steam rises from down below, it carries with it various minerals in suspension. As the steam travels towards the surface of the earth, it all gradually cools. Each mineral has a temperature that is needed for it to stay in suspension. When the steam drops below that temperature, that mineral will drop out and gather with other molecules of the same compound forming crystals. So I am thinking of this column as possibly operating on the same general principle that as temperature drops in the mixture of gasses, that at different points along the ascent, that different things drop out also. Is that what we are talking about?

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#8

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/20/2012 1:10 AM

The methane would have to be last. After the algae has been "eaten" by the thermophilic bacteria of a methane digester, it is fertilizer and that's about all it's good for. I studied methane digesters and what I found is that you can put just about any biomass in it, feces works best, of the various feces, bird feces is best (birds have very inefficient digestive tracts). but any biomass will work. Stuff with a lot of cellulose in it (wood chips and the like) is a very poor candidate for a methane digester. Lastly, the effluent from the digester (what you are left with after the thermophilic bacteria are done converting the biomass) is a near perfect hydroponic fertilizer. Methane is ideal for stationary diesel applications and can replace most of the diesel fuel. it can also be used in pretty much all the ways propane and natural gas are used. It's only drawback is low BTUs per unit volume. It can be "scrubbed" with steel wool or iron filings or the like to remove the caustic chemicals that are associated with the output of a methane digester; said chemicals can be hard on steel and iron and possibly other metals. I gather plastics are relatively immune. It's been a decade or more since I studied this; I forget what those chemicals are.

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#10
In reply to #8

Re: Is it Possible to Generate 3 Fuels from the Same Algae?

07/20/2012 1:49 AM

Hi Jerry. Sounds like you were working on the kind of projects I am interested in. Did you use algae alot in your digester? Interesting about methane replacing most of the diesel fuel.I do recall reading , I think about the gobar setups in India, that they would mix diesel and methane. I do know about scrubbing the methane with iron filings. You're changing the filings into iron sulphide and with the sulphur gone out of the H2s , you are sending hydrogen of with the methane to the carburetor or fuel intake. Then you just have a percentage of CO2 to get rid of. Wonder if that can just be sent through a water tank with growing algae in it and the gas collected after it has passed through? You can also contact me at

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