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Pulp Batch Digester Cracking Problem

05/16/2008 4:07 PM

Hello, we currently run 15 batch digesters at the paper mill where I work. I am responsible for the ASME repairs to the vessels and I do yearly inspections. We have an R-stamp and we make the repairs "in house" with our on qualified welders. The vessels are 14' OD 1.5"-2"wall and roughly 40' tall. 14 of these vessels are carbon steel and of these 3 have a 309/316L s/s corrosion resistant cladding on the inside. I also have one new digester that is made from SA 240 32304 duplex material. We run the vessels at 360 degrees F at 130-135 PSI steam pressure and a very caustic "white liquor" to break down the wood chips. All the carbon steel digesters used to have the same 309/316 L cladding on the 12" lower cone nozzle but after fighting with cracking, Spalding and other problems I decided to go to a 312 s/s cladding a couple of years ago. In the last couple of years I have had very good results with the 312 and seen very few problems. This all changed yesterday when #13 digester which had been in service for about 2 months since its yearly inspection started to leak at the bottom flange. We removed the piping to find a radial crack had occurred in both the cladding on the pipe flange and the adjacent area of vessel flange. After grinding the crack out I dye checked the flange and found the crack was only in the top 1/8" face of the flange and had not gotten down into the base metal. The crack was shallow but it did have a few "legs" coming out from the main crack about 3/8" long. we went through our repair procedure preheated to 200degrees F, welded the crack and applied another layer of cladding to the face and milled the gasket surface back onto it. I found basically the same crack on the vessel flange but it was a good bit deeper. We repaired it the same way and re-milled the face when it was complete. It sounds like it was a faulty weld but after inspection the weld is very sound. I have also considered if some of the old 316L was missed and the 312 was applied over it in an area would this cause a crack to start? I have sent a inquiry to the metallurgist I use but have not heard back from him yet. I was wondering if anyone has had this or a similar thing happen with the 312 stainless material or might have any ideas?

pipewelder

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Join Date: May 2007
Location: Sweet home Alabama
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#1

Re: Pulp Batch Digester Cracking Problem

05/19/2008 2:52 PM

I would consider evaluating the situation for chloride ion induced SCC (stress corrosion cracking). What makes me think that are:

1. High temperates

2. Cracks in heat affected (weld) zones

3. Presence of chloride ions in most paper process chemistry.

A visual exam should indicate by the presence if inter granular verses intra granular cracking.

Welders describe welding in many SCC areas as spider-webbing or chasing the cracks while they are welded.

This could aslo explain the success of the duplex steels and raise questions about welding materials.

I hope this helps.

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#2

Re: Pulp Batch Digester Cracking Problem

05/19/2008 3:14 PM

My experience with 312 weld overlay it has high stresses after application which can lead to cracking issues and under bead corrosion problems. I have a number of vessels metallized with plain Inconel 625 that has lasted for over 14 years. Now there is a better material than Inconel 625 which is better for the process chemistry. This material out last anything currently being use until your retirement ("It is that good"). If interested in knowing more visit arcmelt.com web site and review their 3201 material and contact their Field Service Manager.

Good Luck

Tin-Man

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#3

Re: Pulp Batch Digester Cracking Problem

05/19/2008 3:42 PM

Thanks for the replies. The reason we switched from 316 to 312 is because we were getting allot of SCC. This is the first 312 cladded flange I have had any cracks in so far out of all the ones I have put into service in the past 3 years. I have a job starting on 6/2/08 where a contractor utilizing a patented process will apply a 3/16" thick 312 s/s weld metal overlay to the entire inside wall of one of our digesters. I would like to have inconel cladding installed here but the cost is prohibitive in our case (we could just build a new digester for nearly the same amount) We get a 7 year "fix it for free" warranty on material and workmanship with the 312 cladding and this is the best warranty I have seen from the many different contractors. As I said we have one digester that is made from duplex stainless and we get hardly no wear or corrosion on this material. Duplex stainless steel has went up so much in cost that building any more from duplex is out of the question when one compares the ROI of the duplex digester with the carbon steel digester. Again, thanks for the replies all.

pipewelder

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#4
In reply to #3

Re: Pulp Batch Digester Cracking Problem

05/20/2008 8:09 AM

Pipewelder,

I would be interested on the 312 overlay detials and success. You indicated it was a patented process, could you provide more information, contractors, suppliers or website?

Paddler

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#5
In reply to #4

Re: Pulp Batch Digester Cracking Problem

05/20/2008 8:42 AM

paddler, I see your from "Sweet home Alabama". I am just across the line in North Georgia. Actually I was raised in (LA "Lower Alabama") myself. The contractor that is doing the cladding on our digester is Welding Service Inc. out of Norcross Georgia. The patented process they use is called Unifuse 312. They also do other alloys as well. Welding Services Inc. is one of the largest automated welding companies in the US if not the world. I had them do some base metal build up on one of my other digesters earlier this year and I was impressed with the whole operation. If you would like more information including contact names and phone numbers I can e-mail you direct if you give me your address. We are required to get at least 3 bidders on a job this size and I have a list of other companies that do this type of work as well.

pipewelder

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