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Oxygen and Ozone in the Atmosphere

03/25/2009 6:37 PM

please any help me..........., & explain me as we all know ozone molecule (03) is heaver then oxygen (02) but still ozone molecule is still present in atmosphere above the oxygen why ?????????????????

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#1

Re: presence of oxygen & ozone

03/25/2009 8:01 PM

Ozone is generated in the upper atmosphere when normal oxygen is exposed to UV light of the appropriate frequency. It is very unstable, or, in other words, highly reactive. So as it mixes with layers outside the generating layer, it converts to O2.

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#2
In reply to #1

Re: presence of oxygen & ozone

03/25/2009 8:12 PM

sir thnx for reply...., its o.k that ozone is generated in upper surface but me question is that it is oxygen & may other gases present in atmosphere is lighter than ozone but they are still present below ozone in atmosphere.....

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#3
In reply to #2

Re: presence of oxygen & ozone

03/25/2009 9:20 PM

That's because the O3 is generated in the upper atmosphere. It then either reacts with solar radiation or reacts with atmospheric pollutants and gets broken down back into normal O2 before it can settle down into the lower atmosphere.

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#8
In reply to #2

Re: presence of oxygen & ozone

03/27/2009 1:43 AM

If I get this section of your question well, then the answer you are seeking is this: True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer.

I hope that this helps

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#9
In reply to #8

Re: presence of oxygen & ozone

03/28/2009 11:07 AM

>>> '...the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer. ' <<<

EDITORgbANALYST : Two problems in your explanation.

1. At this level and all the way down to the surface of the earth, there is no meaningful separation or stratification of gasses by density. Luckily diffusion and circulation, keeps gasses from layering by density.

2. Your answer suggests you believe the Ozone Layer is a layer of predominantly O3. This is not the case. The ozone layer is distinct for the elevated level of Ozone, which is at most about 8 ppm, a very minor component. There is no boundary layer where other gas molecules are precluded from diffusion. Only a marked rise in O3 concentration in an area.

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#10
In reply to #9

Re: presence of oxygen & ozone

03/28/2009 11:45 AM

Gas diffusion boundaries are generally blurred - there exists a region of overlap that may be called "reaction zone" within which the reaction is occurring, after all, as everyone in reaction engineering knows, those reactions between gases are not instantaneous reactions that there will be a clear boundary; that is also known. However, generally there is a boundary or front lower done towards Earth so to say at which there are no ozone molecules of perceptible concentration and there is also a front higher up at which there will not be other "co-reactant" gases of perceptible concentration. This concept is quite similar to adsorption dynamics we explained on our site at:

www.gbanalysts.com/Reading%20Room/Situation%20Analysis/BiodieselTechs/adsbfrntswaterfreewashbdsep.html

That said perhaps the gases that react with ozone are in much negligible concentration in the ozone layer while the products of the reactions which can not undergo further reactions are in much higher concentration. Clearly such would explain the mixing you are talking about.

Now let us go back to the question itself (and I paraphrase ): "why are the lighter gas beneath the ozone layer when in fact ozone is heavier than the lighter gases?" Very simple, the lighter gases "co-reactant gases" readily react with the ozone while the equally heavy gases are most likely the products of the reactions and therefore will also be mixed in with the ozone in the ozone layer, thus accounting for the low concentration of ozone you have noted.

Next, the Coriolis Effect you are referring to for the mixing of the gases and the attendant atmospheric dynamics [I believe] does not have much effect up there as the mass of gases or the density of the atmosphere is not high enough to support the vortex dynamics characteristic of the Coriolis Effect.

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#11
In reply to #10

Re: presence of oxygen & ozone

03/30/2009 7:15 AM

You worry me EDITORGBANALYST.

You speak with such authority, and some may be tempted to trust what you write. However, many of your statements, assumptions, and conclusions are either highly questionable, or flat out wrong.

Rather than just say that you are wrong and leave it to everyone to figure it out for themspeves, I am going to detail the problems with what you ahve written. This is no small feat, for you have packed an incredible amount of misunderstanding into your relatively short 2 comments.

I can't be sure that I have caught and covered all of the untruths you have introduced, but I will briefly cover at least the following:

1. Earth's Atmosphere, composition variations with alltitude.

2. Ozone reactions.

3. Coreolis, the fictitious force.

Let's begin:

Atmosphere

The earth's atmosphere is relatively uniformly mixed from the surface up to about 100Km from the surface. I say relatively because there are some minor variations, such as that creating the ozone layer, and rather large variations in water vapor. Below 100K the percentages of the magor constituents do not significanltly change with height. The portions of N2, O2, Ar, and CO2 will be very close to 78.1%, 20.9%, 0.93%, and 0.04% respectively, whether you are measuring at a 5 km, 20km, or 50km height.

This region of well mixed gas is called the homosphere. The ozone layer occurs within only the homoshpere. The Ozone layer is a layer of increased concentrations of o3 that occurs from about 15km to 40 km altitude. Because at the peak o3 is at about 8ppm, it doesn't significantly change the percentage composition of the atmosphere.

Above 100km altitude, the atmosphere begins to separate based on molecular weight. This area is called the Herterosphere. the Ozone layer is not within the Heterosphere. It plays for the other team.

Hopefully this will help you better understand the air you breathe. It should at least assure you that you will still have Oxygen to breathe, even if you lay on the floor, and that you need not fear suffocating from all the argon that has settled...

You shold also understand now that the 'co-reactant' gas boundary and depletion explanation you have been pushing is completely off base. Although you left the identity of these 'co-reactants' mystereous, and although you deemed these to be lighter before reaction and heavier after reaction, the lack of significant changes in percentage composition of atmosphere should prompt you to stop selling that snake oil.

OZONE

o3 is highly reactive, however in the Ozone Layer, reaction with other gases is not the dominant process of removal. Explaining the process in the way you do, is completely off base:

>>> '... Very simple, the lighter gases "co-reactant gases" readily react with the ozone while the equally heavy gases are most likely the products of the reactions and therefore will also be mixed in with the ozone in the ozone layer...' <<<

What actually occurs in the Ozone layer that is significant is called the Ozone-Oxygen Cycle. o2 in the presence of ultraviolet light is split into 2 0, the atomic O, then reacts with 02 yieling 03. 03 in the presence of ultraviolet light is broken in to o2 and O.

At times CFC and BFC will make it high enough in the atmosphere to reach the Ozone layer (these are very heavy molecules, further discrediting the idea you were pushing about ligher gas molecules rising above heavier gas molecuules). In the presence of ultraviolet light the BFC and CFC break down releasing Fl and Cl.

Fl and Cl act as catalysts ewith each free radical causing hundreds of thousands of 03 molecules to break down into o and o2. and to borrow a line from you, as every engineer should know the catalyst is not depleted depleted during this process.

This pretty much tosses your fuzzy boundary layer explanation out the window... perhaps it and your layered gas theory company can keep each other company.

You stated that there is no ozone at perceptable levels near the earth. Here is a graph showing you the reality.

3. Coreolis - To clarify, no one else brought this up. You started in with the Coreolis effect stating that it was 'refered to'. It has little bearing on the discussion, but you managed to introduce some falsehoods as fact, so i feel compelled to point these out.

Coreolis describes the fictitious force that appears to influence an object if observation is made from a rotating reference. If you were on afast turning merry-go-round, and you threw a ball towards the center of the axis of rotation, and as the merry-go-round (and you) traveled quickly around in time, you then caught the ball on the other side, a person also on the merry-go-round, would need to use the coreolis force to explain the strange flight path of the ball you threw. A person on the ground would have seen a normal trajectory and would not need a fictional force to describe the ball's path.

As you can see from the previous example, vortex dynamics are not a requirement or the Coreolis effect.

Furthermore, In a hermetically sealed greehouse situated on the equator of the earth (to remove the influence of your Coreolis effect, heaveir and ligher gases would still diffuse into a well mixed atmosphere. You could take a nap at the bottom without fearing that the atmosphere woudl separate into layers suffocating you....

I don't want to be completely negative on your comments. That would risk quelling your enthusiastic desire to be a provider of answers (even if you currently lack any useful information). So in an effort to preserve your enthusiasm and creativity, here is a positive look at your comments:

Your comments are not totally without merit. Your comments do serve as an excellent motivator encouraging people to look skeptically at the comments of others, even if the comment are written in an authoritative tone and make reference to professional knowledge. The authoritative tone and liberal addition of unrelated scientific jargon provide a good example of warning signs to alert a reader that the comments should receive additional scrutiny.

The boogie-man can be a valuable tool in keeping those who woudl not govern their own actions within at least some bounds....

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#12
In reply to #11

Re: presence of oxygen & ozone

03/30/2009 8:05 AM

Sir,

I will not address all your answers except some as I do not have the time to answer all of them. So I will ask you some questions to highlight some flaws in your thinking:

Now consider first [I quote you]: "At times CFC and BFC will make it high enough in the atmosphere to reach the Ozone layer (these are very heavy molecules, further discrediting the idea you were pushing about ligher gas molecules rising above heavier gas molecuules). In the presence of ultraviolet light the BFC and CFC break down releasing Fl and Cl." where have I written this assertion; and of all the gases you have listed CO2, N2, Ar that are co-mingled with O3, which one is reactive with O3 at the prevailing temperature and what is the prevailing reaction equilibrium?

One more follow up, have you ever heard of the concept of Ozonolysis? Please refresh yourself that ozonolysis was the technique by which CFC and BFC were destroyed as pollutants in the factories of production in the 1980s. Now I ask you again these CFC which were already known to be destroyed by Ozone you assert rose to the Ozone Layer and [by your silence on what happened to these gases] then stayed intact? Then what was depleting the ozone layer in some sections of the atmosphere "The Hole" that was causing all the fear about UV rays causing cancer here on earth the result of which was the banning of most uses of CFC and BFC products?

Now consider this [again I quote you ]: "Above 100km altitude, the atmosphere begins to separate based on molecular weight. This area is called the Herterosphere. the Ozone layer is not within the Heterosphere. It plays for the other team."; now how exactly do the gases separate according to the molecular weight? You failed to tell us that.

Finally one more consideration [and again I quote you]; "Fl and Cl act as catalysts ewith each free radical causing hundreds of thousands of 03 molecules to break down into o and o2. and to borrow a line from you, as every engineer should know the catalyst is not depleted depleted during this process.", here I have to wonder if you have ever heard of compounds of Chlorine and Oxygen and of Fluorine and Oxygen, and acid rains and how acid rains are formed? Chlorine and Fluorine are atoms and as such highly reactive to form their octate states, however, these molecules are neutral; radicals are ions of some sort hence have net charges; and then, of course, O atom does not exist by itself except under conditions of ionization, so when the your so-called "catalysts" breakdown the O3 to O2 and O what becomes of the O? You mean the ozone layer is also populated with free floating O atoms under some heretofore undefined equilibrium conditions?

I now leave you, and unlike you I should have no comments about your knowledge of chemistry, or pollution engineering, or reactions, or Chemical thermodynamics, or even atmospheric fluid dynamics.

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#13
In reply to #12

Re: presence of oxygen & ozone

04/07/2009 6:21 PM

Your argument is absurd on so many levels.

Oxygen- Ozone Cycle is not a theoretical model. It isn't even really disputed (except by you). One of the goofy things is that you state exactly the point that you keep ignoring.

>>>>Chlorine and Fluorine are atoms and as such highly reactive to form their octate states, however, these molecules are neutral; radicals are ions of some sort hence have net charges; and then, of course, O atom does not exist by itself except under conditions of ionization, so when the your so-called "catalysts" breakdown the O3 to O2 and O what becomes of the O? <<<<

That is exactly it. You shouldn't be able to miss it, those are your words..... 'conditions of inonization'.

To answer one of your many questions, the 'O' typically either meets another 'O' and shazam O2, or in the presence of ionizing radiation (which is definitely not in short supply at that altitude... this is your hint... take it this time) reacts with O2 to make O3...

Your idea that FL and CL couldn't be catalysts because 'what becomes of the O?' is perhaps the most egocentric bit of rediculousness i have ever seen. The probabilities are not changed nor onset delayed by your protest, nor by my lack of notating minutia ad naseum.

This is the catalizing reaction:

Cl + O3 —> ClO + O2 ClO + O —> Cl + O2

The overall reaction is:

O3 + O —> O2 + O2

Notice the Cl is not consumed. The same thing happens with Fl.

What DOESN'T happen, HAS NEVER happened and WON'T EVER HAPPEN is what you describe:

>>>ozonolysis was the technique by which CFC and BFC were destroyed as pollutants in the factories of production in the 1980s<<<

CFC and BFC are not destroyed by ozone. CFCs and BFC are very tough cookies to crack, and all but the most harsh chemicals have no effect..... (I can feel it, you are about to miss it again.... Ionizing radiation is th reason CFCs and BFCs break down in the upper atmosphere, and leave CL and FL to catalyze O3)

Ozonolysis is a real process but it is not used to 'destroy' CFC nor BFCs

Ozonolysis of alkenes was originally used to help determine the structure of organic molecules by ozonizing an unknown alkene into fragments that would be more recognizable.

I really got a kick out of the end of your last comment:

>>>I now leave you, and unlike you I should have no comments about your knowledge of chemistry, or pollution engineering, or reactions, or Chemical thermodynamics, or even atmospheric fluid dynamics.<<<

I can tell you, that after your comments, the quality of your 'knowledge' is not really in question anymore. You have demonstrated for everyone quite clearly your degee of competency.

(hint: Dunning-Kruger)

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#14
In reply to #13

Re: presence of oxygen & ozone

04/07/2009 8:58 PM

Sir,

Here is a list of all the Chlorine oxides you can form from the reactions between ozone and Chlorine and from atomic oxygen and atomic chlorine:

Structure and Bonding of Chlorine Oxides and Peroxides: ClOx, ClOx- (x = 1−4), and Cl2Ox (x = 1−8) title of the material the Chemistry of which is well explained in the Journal of Physical Chemistry:http://pubs.acs.org/doi/abs/10.1021/jp983999%2B

Do please explain the limitation of your reactions.

Second please also see this ref:

Thermochemistry of the higher chlorine oxides ClOx (x=3, 4) and Cl2Ox (x=3–7)†

at the link: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGT-4773214-3&_user=10&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000050221&_version=1&_urlVersion=0&_userid=10&md5=3c622aa9bcbcc00bb63e985b741c180f

explaining that the Ozone Hole was caused by those species of Chlorine oxides. Notice that the Chlorine oxides by the formula are ClO3, ClO4, Cl2O7(?)

No where in your equations have you yet shown the roles of these Chlorine Oxides. Perhaps you need to return to your studies and review the materials again.

After you have finally learnt the reaction steps by which the rest of the Chlorine oxides form and then learnt the mechanism by which the Ozone Hole forms perhaps you will rethink your understanding.

I had written privately to you explaining some of the flaws in your thinking in an effort to inform you without acrimony the bases of my information, and here you are again being your boorish self.

I particularly wanted to call your attention to the fact that the stratosphere has vertically concentration gradients and is not homogeneous as per your new ideas of homosphere, and that mixing occurs only at the horizontal levels.

<QUOTE>
http://en.wikipedia.org/wiki/Stratosphere

The vertical stratification, with warmer layers above and cooler layers below, makes the stratosphere dynamically stable: there is no regular convection and associated turbulence in this part of the atmosphere.

The stratosphere is a region of intense interactions among radiative, dynamical, and chemical processes, in which horizontal mixing of gaseous components proceeds much more rapidly than vertical mixing.
</QUOTE>

I also attempted to let you know that I had never in my posting indicated that heavy molecules do not rise as you ascribed to me, a fact you seem to have brushed off, because of its glaring testimony of your obvious attempt at misrepresentation.

Given these your omissions, you obviously have issues and therefore you and boorish self may however really want to speck with someone better qualified to help you resolve your facultative issues.

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#17
In reply to #14

Re: presence of oxygen & ozone

04/08/2009 3:47 AM

You confuse possibility with probability.

You are stating as fact your hypothesis. If you had presented it as such, that would be fine. But I take issue with your insistance on your idea as an experimentally verified truth. It is dishonest.

Your misrepresentation of 'Ozonation' destroying CFC in factories in the 80's is another example of your blatant dishonesty.

You are now altering your statement from your original boundary layer ascertions and trying to make it look as if you've kind of been suggesting that CL and FL were catalysts all along which is dishonest. But at least it means you have been reading and aren't just 100% pulling this out of your 'donkey' now.

For anyone who wants the correct information, here is what MIT says is correct.

With that the people who are interested in the truth have a great source, and those who enjoy fiction can continue absorbing your slowly-shifting-as-to-never-have-been-viewed-as-incorrect-absurdism of pseudosciencefiction.

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#21
In reply to #17

Re: presence of oxygen & ozone

04/08/2009 8:11 AM

Sir,

First of all I did not write those papers I cited for you to read. You are yet to read them and disprove the people. So I could not have presented any hypothesis. Do you even realize that your summations are misrepresentations?

Second, the reactions in the Ozone layer has vertical gradients meaning that the same type of reactions do not occur at the same level. Did you even get the significance of "there are no uniform mixing in the ozone layer" which I have been telling you?

Third since you seem unable to absorb knowledge, understand this, note from what I had sent to you [- these are references that I did not write], the NO and other reactants form not just in the ozone layers but everywhere in the atmosphere and as they rise into the ozone layers react with the ozone. Did you not read that? Was that my hypothesis too? what is the concentration gradient of the NO in the ozone layer? Clearly you just regurgitate knowledge, you are not even an analytical reader. Does that constitute a reaction zone for you? Get it again you slow brain, there is no uniform mixing in the Ozone Layer therefore there are reaction regions for certain reactions though mixed horizontally.

Finally, I spent all of the later half of the 1980s working on Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC and then scrubbed with alkaline solution. Did you not see the formation of HCl in the links given to you by your colleague? Did I not ask you of your awareness of the formation of acid rains?

Do you see why I do waste time with people like you. BTW the 1980s development and use of ozone were also not my work, so before you accuse me of hypothesizing again you should rethink your assertions.

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#34
In reply to #21

Re: presence of oxygen & ozone

04/15/2009 3:12 AM

It is as if you cannot write a comment without introducing a new inaccuracy. (This time) You wrote:

>>>'...I spent all of the later half of the 1980s working on Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC and then scrubbed with alkaline solution...'<<<

How frustrating it must have been to work for several year in the late 80's on Pollution 'control' (notice: not 'clean up', but 'control') for PCBs, production of which has been BANNED since the 1970s!!!

I imagine it might be equally frustrating for you when you realize that PCBs are not CFCs:

PCB: Polychlorinated biphenyls all have a chemical formula that can be described as C 12 H (10-x) CL x

CFC: ChloroFluoroCarbons are composed of Carbon, Fluorine, Chlorine, and Hydrogen.

PCBs lacking fluorine are not CFCs.

.... as before. Your attempts to obfuscate are ineffective. The fact remains that you have made inacurate assertions and presented unsupportable descriptions. No amount of complexiites you reference gets you away from that original fact. It is your character that suffers, in your refusal to admit your error.

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#22
In reply to #18

Re: presence of oxygen & ozone

04/08/2009 8:18 AM

However, you have failed to state that the turbospause is between the Stratosphere and the Troposhere and that the Ozone Layer is in the stratosphere. Why is that? Are you beginning to see the contradictions?

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#27
In reply to #18

Re: presence of oxygen & ozone

04/08/2009 12:02 PM

Do you even realize the confusion you are suffering? You quoted Wikipedia in defining the Homosphere as above with uniform mixing of gases.

I had given you the reason for the mixing of gases in this link as well: QUOTE:

http://en.citizendium.org/wiki/Homosphere

The homosphere is the layer of Earth's atmosphere where chemical constituents are well-mixed. The main reason for this well-mixed condition is that the mean free path between molecules is small compared to the scale of bulk motions of the air. Thus, gases do not separate according to their molecular weight, as bulk air motions keep mixing the atmosphere.

Then I gave you this link from Wikipedia:

http://en.wikipedia.org/wiki/Stratosphere

The vertical stratification, with warmer layers above and cooler layers below, makes the stratosphere dynamically stable: there is no regular convection and associated turbulence in this part of the atmosphere.

The stratosphere is a region of intense interactions among radiative, dynamical, and chemical processes, in which horizontal mixing of gaseous components proceeds much more rapidly than vertical mixing.

Now since the Stratosphere does not suffer uniform mixing as is characteristic of the homosphere, then either the stratosphere is not in the homosphere or the entire concept is crap. Do you get it as yet? That there is no wind dynamics in the Stratosphere which is where the ozone Layer is should also tell you that the ozone Layer is not unformly mixed.

The fact that uniform mixing occurs in the Tropospause being the boundary of such mixing is the reason why aeroplanes fly within this region, and the Tropopause is the boundary between the Troposhere and the Stratosphere. Now if there is no wind dynamics in the Stratosphere and the presence of wind dynamics is what defines the property of the Homosphere, does it stand to reason to question the "Internal self-consistency" of the definition of the Homosphere as being inclusive of the Stratosphere?

Now I ask you again: Are you confused enough? Did I not tell you that you simply read and repeat what you have read without putting one iota of rational analysis into it? You should better understand what you read when you begin to put some rational analysis into what you read.

These exchanges with you, benbenben, are really a waste of my time, and are beginning to be boring

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#28
In reply to #27

Re: presence of oxygen & ozone

04/09/2009 7:24 AM

Let us cut back through all your attempts to obfuscate. Here is your original statement (your original untruth, presented as fact):

>>>...'If I get this section of your question well, then the answer you are seeking is this: True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer....<<<

You have heaped untruth upon untruth upon this original falsehood (not the least of which, is your lie about CFC being broken down through ozonation to clean up factories in the 80s). Let us ignore (for a moment) all the other that came after this original untruth. If you can, please justify this orginal statement.

I suspect we will have another shifting of your original statement, or another bout of your magical misdirection via pseudoscience, because this is not supportable. The idea that other gasses (and i quote) ' are not able to diffuse into the O3 layer because of the continuous reaction of O3 and the other gasses at the bottom of the boundary layer' is hogwash, just like the remainder of your statements.

At most we are talking about 8ppm O3, nothing is being kept from diffusing by this process.

After you admit that you mispokle on this, we can proceed to why you insist on misrepresenting other facts.

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#29
In reply to #28

Re: presence of oxygen & ozone

04/09/2009 8:46 AM

Sir,

Because, have determined you to be a liar and a badly behaved person, I shall not engage you or even attempt to try to think with you. There is nothing scholarly about you and you are a waste of my time. That said here is one of many links I sent to you privately, you should go and read it:

<QUOTE>

First please observe here that there are reactions always going on in the atmosphere as explained here and particularly in the Ozone Layer:

http://www.ace.mmu.ac.uk/eae/Atmosphere/Older/Ozone_Layer.html

Ozone is also naturally broken down in the stratosphere by sunlight and by a chemical reaction with various compounds containing nitrogen, hydrogen and chlorine. These chemicals all occur naturally in the atmosphere in very small amounts.

</QUOTE>

Funny that you now want to discuss science rationally, when you have never even bothered to go out there and read far and wide? Could it be that your argument of homosphere being well-mixed when the stratosphere also said to be in the supposed homosphere is not well-mixed is beginning to catch up with you?

First go out there and read all the other references I have given to you and educate yourself, learn to speak as a curious person and then come back.

When you have finished reading that I shall now in public give more references until you have acquired some more knowledge. Did you notice the very simple equation I wrote about the ozone layer:

2Cl + O3 -> Cl2O + O2;

Cl2O + UV -> Cl + ClO;

when you finish studying these simple equations you will learn alot about your views of the ozone layer; you will also come to the realization that you need to learn even more.

For now I will only give you references so that you will become educated. I shall spend not a moment attempting to explain anything to you. I make every effort to avoid slanderous loudmouths as you, I generally associate and reason with curiuos and rational minds.

Good luck.

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#35
In reply to #29

Re: presence of oxygen & ozone

04/15/2009 4:09 AM

It is amusing that you call me names and state 'I shall not engage you', and then proceed with your multi-paragraph multi-entry diatribe, which contains wide ranging references from 'gravity waves' to 'nitrogen', and (regrettably) very little in the way of ration development of support of your argument.

The links are interesting, though not pertinent. The links do nothing to support your original assertion that:

>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

....Nor do the links provide any support for your numerous other erroneous assertions, such as ....

>>>...the vortex dynamics characteristic of the Coriolis Effect...<<< (there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics)

>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<< (CFC and BFC are not destroyed by ozonolysis)

>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<< (PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not).

VRBARNETT asks the pertinent question >>>'...The argument between you and benbenben appears to be just between you two. Is it really informative to others?...<<<

I ask myself this question each time, and were it not for editorgbanalysts continual addition of new grossly inaccurate or overtly misleading information, I would quit responding. However I feel compelled to warn someone might otherwise take editorgbanalyst at their word (mistakenly viewing numerous links to academic papers as a sign that editorgbanalyst could be a knowledgeable or trustworthy source of information).

I don't think anything new of value is being added, but it is difficult for me to sit idly by as EDITORGBANALYST introduces new grossly inaccurate information or additional faulty logic. With these rash reactionary comments, one wanders if the information at GBanalysts.com could be any better.

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#31
In reply to #28

Re: presence of oxygen & ozone

04/11/2009 2:07 AM

benbenben,

I hope that you have read the limited information in the link I had given to you in relation to my answer that you seemed to have been having difficulty understanding, I am now ready to give you the next reference - this one is crucial, as it explains the concept of reaction zone and height of reaction zones:

Free and moving boundary problems

by John Crank - Technology & Engineering - 1987 - 425 pages
This book presents a comprehensive account of the mathematical formulation of such problems and many new methods of solution.Limited preview - About this book

Do master this book, and then you will begin to understand my answer to the OP, then pick up some more books on the same topic.

By the way you will have to integrate the knowledge in the link and of this book to begin to get somewhere.

I shall come back and give you another reference as I promised so that you may become educated.

BTW please also read the reference in the my post #30, that has to do with your scope of knowledge of the reaction of the Ozone Layer, but nothing to do with my asnwer to the OP of this thread.

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#33
In reply to #13

Re: presence of oxygen & ozone

04/14/2009 3:28 PM

benbenben,

Finally we come to the atmospheric reactions and the effect of gravity waves on reactions and reactants mixing, and the effect of photoreactions on gravity waves; in effect the coupled interactive effects of gravity waves and chemical reactions on each other.

I hope you did read my posts of #30, 31, & 32. In particular you were to pay attention to the NASA scientist calculations about the Molina & Molina Chemistry being a suspect, and therefore your assertion of absoluteness of the reactions being vacuous, or just plain crap.

Now for today, read the following:

An Introduction to Atmospheric Gravity Waves (International Geophysics, Volume 85) by Carmen J. Nappo

The influence of photochemistry on gravity waves in the middle atmosphere by Jiyao Xu

Stratosphere Troposphere Interactions: An Introduction by K. Mohanakumar

After you have acquired the knowledge in these references come back again so that we may now address the issues rationally, and intellectually. I shall now leave you to wallow in your issues.

My advice to you is that when it comes to science be very circumspect at all times, and stay on the subject matter always.

I hope that this helps.

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#32
In reply to #11

Re: presence of oxygen & ozone

04/12/2009 8:15 AM

Benbenben,

I hope that you have picked up the last reference I gave to you on my post #31. The references of this post form the knowledge base for my answer to the OP, they provide the principles on which my answer - to the OP you wished to understand - rests.

The object of the references is "the nonexclusivity of the dominant reaction in the consumption of reactants". For a start read

"Chemically reacting Systems" published by Springer Verlag by an author with a Greek name;

I do not quite remember the name, but it is the only such book by Springer. Then you should get hold of a book on Lie Algebra and learn

The Pfaffian Proof of the existence of Entropy based on the use of Lie Algebraic "Pfaffian Expression" The original proof by Pfaffian is about 65 pages long and you will take too long to understand what is in it.

In particular look for a book entitled "Lie Algebra" by Edlene - I think that is the name of the spelling, start with it, and look for his use of this branch of mathematics to prove the entropy inequality.

Relating the dimensions of the Pfaffian Expression and the multiplicity of reactions defining the entropy generation function or entropy inequality should give the knowledge you need to understanding my answer to the OP.

Explanation? other minor reactions still go on simultaneously with the Ozone Depletion Reactions. The latter does not preclude the occurrence of the former.

I shall be back to give more references that may become educated.

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#38
In reply to #32

Re: presence of oxygen & ozone

04/15/2009 4:11 AM

It is amusing that you call me names and state 'I shall not engage you', and then proceed with your multi-paragraph multi-entry diatribe, which contains wide ranging references from 'gravity waves' to 'nitrogen', and (regrettably) very little in the way of ration development of support of your argument.

The links are interesting, though not pertinent. The links do nothing to support your original assertion that:

>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

....Nor do the links provide any support for your numerous other erroneous assertions, such as ....

>>>...the vortex dynamics characteristic of the Coriolis Effect...<<< (there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics)

>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<< (CFC and BFC are not destroyed by ozonolysis)

>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<< (PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not).

VRBARNETT asks the pertinent question >>>'...The argument between you and benbenben appears to be just between you two. Is it really informative to others?...<<<

I ask myself this question each time, and were it not for editorgbanalysts continual addition of new grossly inaccurate or overtly misleading information, I would quit responding. However I feel compelled to warn someone might otherwise take editorgbanalyst at their word (mistakenly viewing numerous links to academic papers as a sign that editorgbanalyst could be a knowledgeable or trustworthy source of information).

I don't think anything new of value is being added, but it is difficult for me to sit idly by as EDITORGBANALYST introduces new grossly inaccurate information or additional faulty logic. With these rash reactionary comments, one wanders if the information at GBanalysts.com could be any better.

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#4

Re: presence of oxygen & ozone

03/25/2009 11:38 PM

I think it has to do with the concentration of the gas, too. I don't remember the gas laws, but if mass of the molecule was the determinant our atmosphere would be in layers.

This might explain it.

http://www.engineeringtoolbox.com/gas-mixture-properties-d_586.html

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#5

Re: presence of oxygen & ozone

03/25/2009 11:55 PM

As cwarner7_11 stated, UV light is one way of creating O3, corona discharge (think lightning), is another. But if I remember correctly, UV light also helps to break O3 down as well.

But the biggest thing, is how quickly it breaks back down. Chemical engineering is not my strong point, but I have worked with O3 for the past 4 years at a water plant (it's used for disinfection), and I can tell you it will not last long enough to get to the earths surface. If you have an ozone generator in a building, you will sometimes get a whiff of it, if there is a serious leak. But once the generator is turned off, it will dissipate very quickly.

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#6

Re: presence of oxygen & ozone

03/26/2009 12:03 AM

Your question is a good one. Luckily the interactions of gas molecules are dominated by diffusion and not separation into layers according to density in the lower atmosphere.

There is enough energy mixing, that the composition is pretty much uniform up to an altitude of about 60 miles. above that in the absence of significant mixing, there begins to be some separation due to molecular density. This is the distinction between the Homosphere and the Herterosphere.

The higher concentration of Ozone (up to about 8ppm) is due to proximity to the conversion from O2.

Can you imagine what woudl happen if all the gas molecule interactions were dominated by stratification due to density? Each gas in a distinct layer?

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#7

Re: presence of oxygen & ozone

03/26/2009 12:06 AM

One more point. The O3 is not above the O2. There is still O2 up there. A very small portion of the O2 is continually being converted to O3. The O3 is unstable and a significant portion of it reacts before it is fully dispersed into the lower atmosphere.

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#15

Re: Oxygen and Ozone in the Atmosphere

04/07/2009 11:05 PM

These links may cut though the crap. That is if one does not think all government research is crap.

http://www.epa.gov/Ozone/science/myths/heavier.html

http://www.nas.nasa.gov/About/Education/Ozone/chemistry.html

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#16
In reply to #15

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 12:41 AM

I do not wish to write copiously on this topic and hence I have been rather terse. However, I took the time to read, some of the posts on the links you have provided, for the contents and to also ascertain the relative currency of the contents with respect to the references I have suggested. Some facts are clear from that:

  • The contents you have offered are older of 1993/4, while the references I have offered are of 2003; then of course we know that science is always advancing.
  • The atoms of Chlorine and oxygen do not exist freely in the ozone layer even as I had asserted, but rather as inactive compounds, even if as determined in 1993/4.
  • The stratosphere and the troposphere are demarcated by a region of overlap where the effect of wind movement dies off just below the stratosphere, hence mixing in the stratosphere occurs only by gravity waves hence most mixing is horizontal with prevailing vertical concentration gradients.
  • Further it is curious that UV can reach the nitrogen molecule within the Ozone layer and break it up and cause the formation of NO yet the UV can not reach the CFC until it has risen above the Ozone Layer - this is very interesting, I should say.

Then, of course, some one is yet to explain how exactly the gases are separated by molecular weight in the heterosphere, keeping in mind that wind movements do not occur in the heterosphere, so then if the gases could separate by molecular weight in the heterosphere where mixing can not be forced by wind movement, then by abstraction conjure an answer about what would happen if there was no wind movements also in the "homosphere" and relate this situation to the question of the OP. An abstract extrapolation(?) Intellectual thought experiment, may be(?)

I am curious as can be reflected by this question: How many research experiments of the Government have been forged? How many of the Star Wars Defense Technology are actually working, including even the ones that test have shown to be working? Darned I forgot, Pluto was never classified by the Government as a Planet.

Clearly, this discussion is not even instructive to me any more, at this time.

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#19
In reply to #16

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 4:00 AM

>>>>>I am curious as can be reflected by this question: How many research experiments of the Government have been forged? How many of the Star Wars Defense Technology are actually working, including even the ones that test have shown to be working? Darned I forgot, Pluto was never classified by the Government as a Planet.<<<<<

Yes! Of course! Why didn't i see that from the outset? How could I have been so foolish? It is obviously a government consiracy to discredit your impecable logic and limitless knowledge. That can be the only reason for your shifting, dishonest comments. Without a doubt.

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#23
In reply to #19

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 8:25 AM

Government conspiracy to discredit what logic? Logic of an hypothesis that has never been written? Logic as defined by a mind that misrepresents information of others? What logic?

A well-known fact given as an answer to a statement that was made with broad implications has now become a conspiracy theory? A fact suggested in advise of caution is now a conspiracy theory? That is how you comprehend? Sad. What foolishness we display from poor scholarship.

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#37
In reply to #23

Re: Oxygen and Ozone in the Atmosphere

04/15/2009 4:10 AM

It is amusing that you call me names and state 'I shall not engage you', and then proceed with your multi-paragraph multi-entry diatribe, which contains wide ranging references from 'gravity waves' to 'nitrogen', and (regrettably) very little in the way of ration development of support of your argument.

The links are interesting, though not pertinent. The links do nothing to support your original assertion that:

>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

....Nor do the links provide any support for your numerous other erroneous assertions, such as ....

>>>...the vortex dynamics characteristic of the Coriolis Effect...<<< (there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics)

>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<< (CFC and BFC are not destroyed by ozonolysis)

>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<< (PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not).

VRBARNETT asks the pertinent question >>>'...The argument between you and benbenben appears to be just between you two. Is it really informative to others?...<<<

I ask myself this question each time, and were it not for editorgbanalysts continual addition of new grossly inaccurate or overtly misleading information, I would quit responding. However I feel compelled to warn someone might otherwise take editorgbanalyst at their word (mistakenly viewing numerous links to academic papers as a sign that editorgbanalyst could be a knowledgeable or trustworthy source of information).

I don't think anything new of value is being added, but it is difficult for me to sit idly by as EDITORGBANALYST introduces new grossly inaccurate information or additional faulty logic. With these rash reactionary comments, one wanders if the information at GBanalysts.com could be any better.

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#20

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 6:57 AM

Actually I wasn't trying to engage in argument, I was trying to add a simpler answer to the original question. Some how I didn't think Chemistry would change over time since it wasn't discussed in quantum terms. I made the statement about the government, because on this forum, which is weird to me, there are always so many conspiracy theorist.

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#24
In reply to #20

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 8:37 AM

First of all I am not a conspiracy theorist, and I have no reason to be. In fact I had done some of my work with the help of the Govt. I have often had to submit my proposals to others for review before being accepted and worked on.

Yet I am also fully aware of the implications of the broad statement about everything of the government being correct. Let me ask you the following:

2Cl + O3 -> Cl2O + O2;

Cl2O + UV -> Cl + ClO;

these and rest of the mechanism are written by others in scientific journals, and are consistent with the observations in the ozone layer. This is not even the areas where I do research.

Concepts are simply refined incrementally as a matter of professional courtesy with additional details.

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#25
In reply to #24

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 9:55 AM

editorgbanalysts,

I am curious as can be reflected by this question: How many research experiments of the Government have been forged? How many of the Star Wars Defense Technology are actually working, including even the ones that test have shown to be working? Darned I forgot, Pluto was never classified by the Government as a Planet.

I didn't know what to make of this statement. Usually follows from this reasoning some conspiracy thinking, which I find quite common in this forum. Initially I was not singling you out. As I said I was not arguing with you, just presenting a more layman's POV to answer original post. That is why I linked, as I assumed you were, when you linked to wikipedia. Not being or pretending to be an expert I was looking for an explanation that someone with a resonable chemistry background could understand, including myself. The argument between you and benbenben appears to be just between you two. Is it really informative to others?

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#26
In reply to #25

Re: Oxygen and Ozone in the Atmosphere

04/08/2009 11:27 AM

There is a debate going on in another thread entitled "PCBs and Soil Remediation", and one of the debaters wrote this and it is response #5 second paragraph - you may want to check it out: http://cr4.globalspec.com/thread/36031#newcomments [and I quote]:

<QUOTE>If your PCB does not burn (at low temp, 800-1000 degrees) it will do little harm. The whole issue arose from a mistake in the 70s. The folks in Japan knew there were PCB in some food, but did not know until years later that some of it had been transformed by overheating into Polychlorinated dioxins, which are very harmful, but harder to find with 70s lab technology. Media hysteria led to new laws and regs worldwide. Once the Government had made that error, and blamed PCB, they could never admit that the 'EMPEROR HAD NO CLOTHES' as the kiddie fable goes.</QUOTE>

The point I am making is there are many times when information have been published too early and mistakes have been found but never corrected, for many reasons. One such reason is that the original publisher is too powerful to be contradicted, or the information just is in accurate. I remember many years ago I wrote a paper on analyzing Random Media, the paper disproved another work done by a Prof at U of Buffalo, very popular in the Chem E field at the time; my paper was reviewed by two Profs at Courant Institute of NYU and found to be very interesting fundamental treatment of the problem. However, I was also told by the NYU Profs, that the paper will never be published by the Chem E field because of the contradictions of Profs, "That is just the way it is" I was told. Yet because of that paper I was granted admission, at my preference, into a top notch math-U PhD program - if I wanted to.

My statement is a matter of caution, not of conspiracy.

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#30
In reply to #26

Re: Oxygen and Ozone in the Atmosphere

04/10/2009 1:18 PM

The ozone depletion theory was based on the dimer theory of Molina & Molina as given in this reference:

For anyone who wants the correct information, here is what MIT says is correct.

It must also be correct well because after all it is being taught in a course in MIT, but wait a minute, Thermodynamic analysis, by a NASA scientists demolishes the chemistry - the reaction mechanism:

http://www.mitosyfraudes.org/Ozo/vortex.html

Then, of course, let us not forget even for a moment that Molina and Molina never performed a single experiment, but rather performed reaction-rates comparative analysis in arriving at their chemistry:

http://www.beyonddiscovery.org/content/view.page.asp?I=89

I shall give the references to newer experiments determining the minimum energy paths followed by Chlorine oxides, further raisng questions.

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#36
In reply to #30

Re: Oxygen and Ozone in the Atmosphere

04/15/2009 4:09 AM

It is amusing that you call me names and state 'I shall not engage you', and then proceed with your multi-paragraph multi-entry diatribe, which contains wide ranging references from 'gravity waves' to 'nitrogen', and (regrettably) very little in the way of ration development of support of your argument.

The links are interesting, though not pertinent. The links do nothing to support your original assertion that:

>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

....Nor do the links provide any support for your numerous other erroneous assertions, such as ....

>>>...the vortex dynamics characteristic of the Coriolis Effect...<<< (there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics)

>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<< (CFC and BFC are not destroyed by ozonolysis)

>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<< (PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not).

VRBARNETT asks the pertinent question >>>'...The argument between you and benbenben appears to be just between you two. Is it really informative to others?...<<<

I ask myself this question each time, and were it not for editorgbanalysts continual addition of new grossly inaccurate or overtly misleading information, I would quit responding. However I feel compelled to warn someone might otherwise take editorgbanalyst at their word (mistakenly viewing numerous links to academic papers as a sign that editorgbanalyst could be a knowledgeable or trustworthy source of information).

I don't think anything new of value is being added, but it is difficult for me to sit idly by as EDITORGBANALYST introduces new grossly inaccurate information or additional faulty logic. With these rash reactionary comments, one wanders if the information at GBanalysts.com could be any better.

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#39
In reply to #36

Re: Oxygen and Ozone in the Atmosphere

04/15/2009 11:33 AM

Benbenben,

Now I know for a fact that I was correct when I described you as a person who is not an analytical reader, and as a person who does not bring an iota of rational analysis to anything you read. I should now substantiate this assertion:

  • First please note that the Molina and Molina subsumed use of the Ozone Depletion Reaction, as partly developed by Rowland, was based on the implicit use of Inductive Logic: Given the ozone reaction that is accepted - keyword "accepted" and not "proven" - as the operation reaction for Ozone destruction, then it follows that the same reaction must prevail in the vortex seeding the Ozone.
  • The NASA Scientist's analysis constitutes a Proof by Counter-Example [the inductive logic of the use of the Ozone depletion reaction in the vortex enables a propagating effect of the NASA Scientist's analysis]: If it does not work here then it does not work anywhere else.

Unfortunately, you could not recognize all this on your own, attesting to my assertions about you and why I am wasting my time debating both my answer to the Op and the irrelevance of your introduction of the Ozone depletion issue into the discourse.

Good luck to you.

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#40
In reply to #39

Re: Oxygen and Ozone in the Atmosphere

04/18/2009 6:47 AM

Regardless of your personal attacks, the fact remains you have introduced (and refused to correct once indicated) several statements which are either outright false, or at the very least, very misleading by suggestion. These statements include (and are unfortunately not limited to):

>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

(this is your original falsehood upon which you have heaped untruth upon untruth.....it is simply not true that a concentration of O3 which is 88ppm at greatest is keeping other lighter gasses from diffusing into the O3 layer. Despite all your attempts to obfuscate, this is simply not supportable. A simple mea culpa would have sufficed. It certainly would have been more honorable than this desperate attempt to be seen correct at all costs, displayed in the following attempts to divert, distort and confuse.)

>>>...the vortex dynamics characteristic of the Coriolis Effect...<<<

(there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics. Coriolis is a fictitional force which corrects the movement when viewed from a rotating frame of reference.)

>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<<

(CFC and BFC are not destroyed by ozonolysis.)

>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<<

(PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not. What is even more amusing is that in another post you completely contradict what you have said here.)

So, all in all, whether or not you truly see me as a 'poor scholar' or a 'badly behaved person' or 'a person who is not an analytical thinker' or even 'a person who does not bring an iota of rational analysis to anything I read', or any of the other negative discriptions you have made for me, the fact remains, you have made numerous false and misleading statements. Worse yet is that when these are brought to light, you refuse to correct your mistakes and attack the person pointing these out (me).

One can only assume your actions are not only indicative of great misunderstandinging in your own mind, but surely must also indicate substantial inaccuracies in any catalogue of information overwhich you exert control... such as www.gbanalysts.com who could trust such a source that is so quick to offer opinion as fact, and then so ready to vehemently defend that position when it is questioned.

Those interested in the truth, have enough here to judge. Your attempts to confuse the issue by siting articles concerning gravity waves and referencing Molina or Rowland (as if you were best friends), are transparent to all but the most caual observer. Anyone with a genuine interest will not be fooled. While your insistence on name calling is a dead give-away, even without that childishness, your arguments fall apart on close inspection. You fail to support your original assertions, and with good reason. Your original assertions are not supportable.

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#41
In reply to #40

Re: Oxygen and Ozone in the Atmosphere

04/18/2009 11:41 AM

Benbenben,

Regarding your statement above [and I quote]: "but surely must also indicate substantial inaccuracies in any catalogue of information overwhich you exert control... such as www.gbanalysts.com who could trust such a source that is so quick to offer opinion as fact, and then so ready to vehemently defend that position when it is questioned"

I have to tell you, I am surprised that you would read a website without understanding its mission, and then determine from the mission whether or not you can consider yourself as being part of the target audience.

For your benefit, let me recall to you that the mission of GB-Analysts Reports is the "Integrated Knowledge based Analyses of Socio-Economic Issues" The key-words here are "integrated knowledge" and "analyses". So the site is targeted to people who can integrate knowledge as it deals with integrated knowledge, and the site does not provide answers rather the site provides analyses from which knowledge integrators than develop their answers.

Clarifying the mission even more, please recognize that The object of the site is constructive abstraction of knowledge. the keyword here is abstraction, and let me explain that to you just in case so that you may better understand: A good illustration comes from Mathematics: In real life people can only think in concrete terms with respect to two and three dimensional spaces, however, to deal with four or more dimensional spaces one has to abstract the general knowledge of 2-D and 3-D and abstract it using inductive logic.

So do please, do not fret over GB-Analaysts Reports if you do not understand the reports posted there; the posts are for those Universities, and Chemical and Biotechnology Companies, and Telecommunications Companies, and the myriad of core readers constituting it consumer-base for whom the posts are targeted.

Indeed, the site does have its core readership and followers and you may choose not to be one them, but that is alright, as the site is not aimed at everybody, but aimed rather at that slice of society that can be deemed of the Thinkers category of society, and as asserted in Corporate Culture by Deal and Kennedy at most only twenty-five percent of society have that quality, while Myers-Briggs asserts that only about 18.75 percent of society can think abstractly.

So if you do not read the site, and seemingly you are not qualified member of the target audience, it would not impact the core readers who have recognized the quality of the posts; and I thank you.

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#42
In reply to #40

Re: Oxygen and Ozone in the Atmosphere

04/18/2009 12:26 PM

Benbenben,

Regarding your submissions in relation to the discourse, which I should address below, I want to start however, by explaining my Moniker to you - a subject of some interest to some readesr on this forum: "Give a boy fish and he eats may be for a day, teach a boy how to fish and he will eat everyday" and by this I mean give solutions to people and they will continue to come back for solutions, but teach them the thinking process about finding solutions and they will always be able to find their own solutions.

So as a matter of principle I do not give answers to any question on this forum, rather I evolve the thougt process involved in finding the answers, and let the person find the answer as a matter of self-accomplishment. That said, I am sure that you will now appreciate my response to your remarks, if you will task yourself to think about my responses and also find answers for yourself.

Benbenben:
>>>...the vortex dynamics characteristic of the Coriolis Effect...<<<

(there are numerous examples which can be described by the Coriolis force without consideration of vortex dynamics. Coriolis is a fictitional force which corrects the movement when viewed from a rotating frame of reference.)

My Response:

Coriolis Effects while a result of the movement of the Earth and consequentially a rotational effect accounting for wind dynamics, large scale wind movements and hurricanes and tornadoes are also ascribed to this some effects. Tornadoes and hurricanes are of the class of large scale vortex dynamics. Do please see this short reference, it is not long so you should be able to hold your attention span long enough to finish reading it.

However perhaps, I should remind you that my introduction of Coriolis effects was to point out to you that the Ozone layer is not well-mixed as per message # 10 and your assertion of message #11. This rebuttal by me was borne out by my reference to you:<QUOTE>: The vertical stratification, with warmer layers above and cooler layers below, makes the stratosphere dynamically stable: there is no regular convection and associated turbulence in this part of the atmosphere. The stratosphere is a region of intense interactions among radiative, dynamical, and chemical processes, in which horizontal mixing of gaseous components proceeds much more rapidly than vertical mixing.</QUOTE>The next thing you did was to try to run away from the baseless assertion you made to attempt to discredit my statement.

Benbenben:
>>>...ozonolysis was the technique by which CFC and BFC were destroyed...<<<

(CFC and BFC are not destroyed by ozonolysis.)

My response:
In 1987 I was in Happauge , Long island, NY in a company that was using it. As I said you should be circumspect as you can know everything that is happening everywhere, and people keep a lot of trade secrets, even as I do.

Benbenben:
>>>...Pollution control particularly the destruction of PCB and know for a fact that "ozonation" was used to destroy these chemicals CFC...<<<

(PCBs are not CFC. CFC by definition contain Fluorine, PCBs do not. What is even more amusing is that in another post you completely contradict what you have said here.)

My Response:

I told you once before that you are a "slanderous person" by constantly misrepresenting people. In 1987 through 1994, I was involve in Pollution Control, particularly PCB, and I course of that I meant with various companies and researchers, one of which was the company working with ozonolysis and Ozonation. I was in Pollution Control would mean to any research-oriented person that I had to have been investigating all methods being used for various pollutants to see their applicability to PCBs, but that is not the way your mind interpreted it, instead your mind interpreted that statement as meaning I do not know the difference PCBs and CFCs? You see my point, and why I would brand you a "slanderous person". Clearly you are just not educated, again an assertion I now confirm. Research people study knowledge both in their areas of interest and outside of the areas as well.

Benbenben:
>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

(this is your original falsehood upon which you have heaped untruth upon untruth.....it is simply not true that a concentration of O3 which is 88ppm at greatest is keeping other lighter gasses from diffusing into the O3 layer. Despite all your attempts to obfuscate, this is simply not supportable. A simple mea culpa would have sufficed. It certainly would have been more honorable than this desperate attempt to be seen correct at all costs, displayed in the following attempts to divert, distort and confuse.)

My Response:
Message Post: #10: <QUOTE>Gas diffusion boundaries are generally blurred - there exists a region of overlap that may be called "reaction zone" within which the reaction is occurring, after all, as everyone in reaction engineering knows, those reactions between gases are not instantaneous reactions that there will be a clear boundary; that is also known. However, generally there is a boundary or front lower done towards Earth so to say at which there are no ozone molecules of perceptible concentration and there is also a front higher up at which there will not be other "co-reactant" gases of perceptible concentration. </QUOTE>

It is not my fault that you are not able to process the information here; note the key phrases: "reaction Zone", "no ozone molecules of perceptible concentration" and "other "co-reactant" gases of perceptible concentration"It is not clear to me why you have found it so difficult to understand these statements other than that you have got issues.

Now let me begin by telling you that the Ozone Layer is not called that just because of elevated concentration of Ozone in that region as you would like to believe as per one of your other message#11. Please note that the Ozone Layer is called that also because that is the region where it is produced primarily. The Atmospheric layers were primarily defined according to the temperature changes. So then as I had stated previously, the ozone concentration therefore suffers drop off towards the earth as other gases suffers drop-off towards the top of the stratosphere – the temperature-based define Atmospheric Layer where the Ozone Layer is. Unfortunately you have already confirmed this observation all by yourself so I will not even waste my time.

Benbenben:
>>>...True the other gases may be lighter than the O3, however, their molecules are also not able to diffuse into the O3 layer because of the continuous reaction of the O3 and the other gases at the bottom boundary of the O3 layer...<<<

(this is your original falsehood upon which you have heaped untruth upon untruth.....it is simply not true that a concentration of O3 which is 88ppm at greatest is keeping other lighter gasses from diffusing into the O3 layer. Despite all your attempts to obfuscate, this is simply not supportable. A simple mea culpa would have sufficed. It certainly would have been more honorable than this desperate attempt to be seen correct at all costs, displayed in the following attempts to divert, distort and confuse.)

My Response:

I do not obfuscate. I try to explain to you the knowledge base you seem unable to grasp. I can tell when I am dealing with someone not knowledgeable enough and is being obnoxious to cover up the ignorance while expecting to learn from the answers given in return to their obnoxious attitude. You are such a person, and hence I do not answer you instead I continue to dismiss you with questions none of which you have been able to answer.

Now I shall repeat my quote again that seem unable to get through into your head: Message Post: #10: <QUOTE>Gas diffusion boundaries are generally blurred - there exists a region of overlap that may be called "reaction zone" within which the reaction is occurring, after all, as everyone in reaction engineering knows, those reactions between gases are not instantaneous reactions that there will be a clear boundary; that is also known. However, generally there is a boundary or front lower done towards Earth so to say at which there are no ozone molecules of perceptible concentration and there is also a front higher up at which there will not be other "co-reactant" gases of perceptible concentration. </QUOTE>

Please recall that I have since followed this up with disproving you on your citation of the Molina & Molina chemistry as the reactions that occur exclusively in the Ozone layer by the following references:

First please observe here that there are reactions always going on in the atmosphere as explained here and particularly in the Ozone Layer: <QUOTE>Ozone is also naturally broken down in the stratosphere by sunlight and by a chemical reaction with various compounds containing nitrogen, hydrogen and chlorine. These chemicals all occur naturally in the atmosphere in very small amounts.</QUOTE>

I then gave you in message #31 these books to read before spoke any further:

Textbook: Free and moving boundary problems‎ by John Crank - Technology & Engineering - 1987 - 425 pages

Then I gave you in message #32 these books to read within the message: The object of the references is "the nonexclusivity of the dominant reaction in the consumption of reactants". Textbook: "Chemically reacting Systems" published by Springer Verlag by an author with a Greek name;

Textbook "Lie Algebra" by Edlene - I think that is the name of the spelling, start with it, and look for his use of this branch of mathematics to prove the entropy inequality.

The Pfaffian Proof of the existence of Entropy based on the use of Lie Algebraic "Pfaffian Expression" The original proof by Pfaffian is about 65 pages long and you will take too long to understand what is in it.

Relating the dimensions of the Pfaffian Expression and the multiplicity of reactions defining the entropy generation function or entropy inequality should give the knowledge you need to understand my answer to the OP.

Please observe the last statement of the above paragraph, I have already told you that I am correct.

Now if you are going to insist that I am wrong, do you think that you should at least bring yourself to the same quality of knowledge by which I have made my assertions?

  • Consider that you made reference to Molina & Molina chemistry as part of your answer, I then went off and researched it together with all related works and came back to prove your assertions outright wrong in some respects and in others as suspected wrong answers. That I am able to and willing to bring myself to the same level of knowledge base should tell you how I operate and what I expected of you.
  • Consider that by not knowing every research related to the ozone reactions before coming out here to shout about being right shows you as nothing more than a knowledge consumer and not a knowledge generator;
  • Consider that I have given you many references none of which you have come out here to admit as having read and acquired any knowledge from;
  • Consider that without leaving room for variance in meaning, you came out here and called me a Conspiracy Theorist only to find out that the caution I was suggesting to V Barnett was well-founded by virtue of the work of the NASA Scientist, that I have also given as reference, and yet you accuse me of calling you names.

Do you now recognize the degree of recklessness with which you utter baseless and "slanderous" statements that can only come from a person with problems, that is, if you should reject your ignorance?

I am not here to teach anything to you or people like you who are not capable of originating independent thought, I am here to have discourses with people who are constructive and rational thinkers, and I am afraid you seem not to be one of such.

About the knowledgeable people on this forum you are talking about, are they not part of the human community, really you are not well-read or even widely read, so I refer you yet again to Corporate Culture by Deal and Kennedy, get that book and read all about the Dummy Theorem. You really are pedestrian in your thinking

Now Good day.

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#43
In reply to #42

Re: Oxygen and Ozone in the Atmosphere

04/26/2009 11:12 PM

'The lady doth protest too much, methinks.'

You have again referenced the work of many authors (I would be surprised if a single author of a work you have referenced would wholeheartedly agree with the majority of your outlandish assertions, I am sure most would not be elated to have their name attached to this particular style of ego-think-pseudoscience). You have again called me names. And most predictably you have once again failed to either, admit your errors, or support these wild assertions. I have detailed these sufficiently, so i won't rehash.

I am curious if you have actually read the papers you reference, or if perchance, you are in the habit of google-ing for argument fodder?

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#44
In reply to #43

Re: Oxygen and Ozone in the Atmosphere

04/26/2009 11:38 PM

Why don,t you go off and read them then return to debate the issues. Stop obfuscating to hide your inability to read with comprehension. Interestingly I see that one of your dummy friends has already given your irrelevant-to-the-issue remark a good answer. No no I get it, it is you who also marks your answers good answer under a different name? You are pathetic.

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#45
In reply to #44

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 12:43 AM

If you don't find my remark relevant, then rate it accordingly.

An even better alternative would be: if you don't find my comments so very relevant to the conversation between us (pointing out what you obviously cannot stand; the suggestion that you have made glaring and uncorrected errors) then simply stop responding. The conversation long ago veered from the original topic... about the time you began emphatically asserting that...

'..other gasses..... are NOT able to diffuse into the O3 layer because of the continuous reaction of the O3...'

If what you have written is sufficient to support you assertions, then let it stand. If I am so pathetic, then why dignify my comment with a response?

I do have a friend with whom I share certain curiosities. In this way, your vehement denial of any misstatement and excessive referencing, have earned you a fan-club of sorts between us, as a running joke. In this light, my friend used your screen name as a verb the other day. I believe her exact words were "...let's see you B.G.Analyze your way out of this one!..." So one might say you are on the similar track as Google, yet not so promising. I won't see her till the morning, but my suspicion is that you (for once) are correct in one respect: that she rec'd my posting since i showed it too her before she went to bed. She however is no 'dummy', but don't worry I'm sure she will put about as much stock in your evaluation of her as anyone should put in just about anything you write, judging what I have seen thus far.

At any rate, one thing is highly probable. You will be compelled to attempt to 'B.G Analyze' your way into writing more of your drivel. Perhaps you will take some comfort in knowing that you have at least two people in the world looking forward to hearing your response. Even if you do realize the interest in your comments stems mostly from the value as a sort of informal single subject research on extreme cognitive biases (possible abnormal psych?), you should think of the bright side: two people are anxiously awaiting what you have to say! When was the last time you could say that?

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#46
In reply to #45

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 12:57 AM

Funny, how I also have friends who read your responses and laugh at your foolishness. They even spend time contemplating your mental state regarding this matter. What they have not been able to understand is your determination to convince me that you are right. what they can not understand is why you would put so much effort in something for which you are apparently not being paid.

Or are you being paid to keep up this foolishness? Perhaps that explains it, if not what is in it for you?

If you were an intelligent person you would have understood why I respond to you. But alas you are not.

Let me repeat again, this is what you ought to have done, go and read the books I have referenced as the bases of my responses and then come back and make your assertions based on the contents. So very interesting how you refuse the read the references I give you but you also come here to argue that I always respond to your queries, why do you not respond to my challenges of reading the books to gain the foundation knowledge and then resume the debate?

Really, you should stop diverting attention. then, of course, why have you not stop writing the nonsense knowing fully well that you have not been able to acquire the requisite knowledge of which I challenge you.

You can not read with comprehension, can you?

BTW, at least I know that it is that your girlfriend the dummy who keeps marking your responses good answers were relevant or irrelevant to the issue. Thank you for proving me right after all. Really as Deal and kennedy noted you dummys really self-select into groups.

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#48
In reply to #46

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 2:51 AM

Bravo! No really, you are truly unbelievable. It is obvious that you are definitely something special, like a new strain of Ebola virus. The confirmation bias you exhibit is without parallel. Case in point, your last response (emphasis added):

>>>'....at least I know that it is that your girlfriend the dummy who keeps marking your responses good answers were relevant or irrelevant to the issue......'<<<

Consistent with your M.O., based on no understanding and too little information to definitively ascertain the truth, you have drawn numerous inaccurate conclusions:

- She marked my response tonight. (Though i suspect this, it is not yet known to me, nor you)

- She is responsible for marking my other responses.

- This in some way 'Proves' you 'right after all'.

- That she is my girlfriend (once again unknown to you with current information, but I am sure that you will attempt to BGAnalyze your way out of this one and claim that i indicated that she is female and that she is my friend, and you only meant 'girlfriend' as a friend who is female, and not the standard meaning with romantic implications. I would certainly be fortunate to have her as my girlfriend, but whether that is the case remains unknown to you).

Throw in a little dash of paranoia:

>>>'...Or are you being paid to keep up this foolishness?...'<<<

Nothing says psychosis like a good paranoid delusion, does it? Yeah, I'm an agent with the IBG (Imaginary Bureau of Gosh-you-certainly-are-free-thinker-we'd-better-keep-tabs-on-you) and my assignment to stop you and your new un- reality from gaining a foothold in the real world. Um, yeah. Oh, I almost forgot. And my 'girlfriend' is my co-agent, tasked with undermining your self worth by cheering for me, and not at all for you.

Wow, that is kind of cathartic, just to spew out complete nonsense! You probably feel better when you spew out a stream like that, the way a drunk must feel better after vomiting, no critical evaluation necessary, just empty that worthlessness. Is that how you got caught up in your whatever-pops-into-my-head-must-be-the-undeniable-truth way of thinking? Perhaps those qualities are what continue to make it irresistible to you, and yet the hangover continues.

And top it off with a generous helping of disordered thought...

>>>.'..If you were an intelligent person you would have understood why I respond to you. But alas you are not.

Let me repeat again, this is what you ought to have done...'<<<

-If it is your belief that I cannot understand what you are writing to me, why do you choose to 'repeat again'? One definition of insanity is repeating the same thing again and again, but expecting a different result.

>>>'...You can not read with comprehension, can you?...'<<<

- Once again, the degree of disorganization in your thoughts shows through here. If you believe me unable to comprehend what you write, how foolish is it to attempt to communicate this idea to me in writing? You would probably find it equally sensible to yell 'you cannot hear me can you?' to a person you believe is deaf. Perhaps your solution for bridging a language barrier is slower and louder speech.

....and that is you, or at least the very consistent self-portrait of you have painted in your numerous responses.

I don't mind considering whether I am peering into or out of the cage at the zoo when looking at you, it is just a frame of reference. I can't help but be amused however when you react by going completely ape-schit.

Thank you for the base amusement. No one should say that fecal tossing primates are in a category of their own, you are certainly provide ample competition.

My interest in your extreme peculiarities dwindles. I am turning to leave the spectacle you have made of yourself. You will have to step outside your now expected pabulum and do something unexpected, something shocking. Tell the truth perhaps.

Can't wait to read it, really.

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#47
In reply to #45

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 1:57 AM

benbenben,

On a second thought perhaps I shold be more explicit about the point I madeabove in recognition of your poor reading skills.

The point is by your inability to accept the differences in opinion between us, your inability to read materials given to you in reference to better equip yourself prior to coming out to write some more, and given to mental acceptance of my assertion that I am correct and you are well not-so-well-informed, my friends and I are convinced that

You are suffering from schizophrenia.

The same we think is also true of your gang, whom you have now admitted is your girlfriend.

Now the Proof of the above assertion:

The simple tell-tale sign: A person who does one thing again and again while expecting a different answer is a schizophrenic. Your repeated assertion that I am wrong and expecting me to accept such irrespective of the number of times I have asserted to the negative, and given you references none of which you have read, while expecting that my reaction to you will change is the tell-tale of your being a schizophrenic.

benbenben, [or whatever your real name is] seek psychiatric help.

I have earlier suspected that yo have issues, but with this your last communication - even after I have said to you "Good day", which any self-respecting same person would take as a cue to move on still escapes you - you gave a confirmation of your mental problems.

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#49
In reply to #47

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 3:19 AM

>>>.'...The simple tell-tale sign...'<<<

This demonstrates one of the major dysfunctions in your thinking. You are not a psychologist nor a psychiatrist, and yet you have convinced yourself that you 'know' there is a simple tell tale sign of schizophrenia.

Have you realized that you are mimicking what I am saying? Or do you believe that what you have typed is original? what do you and all your friends sitting around your computer think. The record is there....

I say you are obfuscating and ignoring the question at hand.

You say the same thing.

I relate a story to you about how your name has changed into verb with a negative connotation, leading to a running joke between a friend and I.

You write that you and your friends laugh at me.

I suggest to you that one definition of insanity if repeating something again and again and expecting a different result. I also note that you are exhibiting paranoid delusions and disorganized thoughts which are symptoms of psychosis.

You diagnose me as schizophrenic.

While you are certainly tipping the 'how-crazy-is-this-one scale', your are comming up very light in the originality department.

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#50
In reply to #49

Re: Oxygen and Ozone in the Atmosphere

04/27/2009 5:21 AM

Still would rather not see a psychiatrist, right?

Delayed telling you about my friends laughing about your insanity because they wanted the assertion to be defensible and true, so they waited until you wrote again.

Really you should see a psychiatrist.

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#51
In reply to #50

Re: Oxygen and Ozone in the Atmosphere

04/28/2009 12:20 AM

Really? That all?

I mean I expected the weak explanation. What surprises me isthat your last coment lacks the fiery passion in defense of indefensible positions. Are you truly through? Or was this a fluke?

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#52
In reply to #51

Re: Oxygen and Ozone in the Atmosphere

04/28/2009 12:31 AM

Schizophrenic Benbenben,

Still would rather not go on your mental medication, right? Really you should see a psychiatrist for support. You are schizophrenic, and apparently strikes most active only at late hours of the day.

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