The % of NDT, particularly X-Ray (radiography) is specified by the governing Code. It is intuitive that for High pressure steam systems, 100% is most typically required. But, check the Code, first. A good place to start is with you supplier. they may have a metallurgist that can render a the help you need. Also, check your contract documents for the Code required, and engineering requirements that may specify more stringent testing that may be required by the Code.
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"Careful planning followed by rapid execution." Napoleon