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Active Contributor

Join Date: Feb 2010
Location: Jordan
Posts: 11

Nickel Corrosion and Compatibility in KOH Unit

02/26/2010 10:44 AM

Hi Dears, in our KOH Unit we produce a 90%KOH flakes from 50%KOH liquid through evaporator "tube heat exchanger" then a receiver " drum". the liquid 50%KOH is being heated for 380 deg.C. the problem is we have a corrosion of nickel drum which contaminate the product. i searched in ASME II, i found no data about the minimum strength of Nickel 200/201 above 350 deg.C. Could this be the root cause?? Waiting your reply Kind regards

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Pathfinder Tags: KOH with Nickel
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Guru

Join Date: Feb 2009
Location: Tamilnadu, India
Posts: 836
Good Answers: 42
#1

Re: Nickel Corrosion and Compatibility in KOH Unit

02/27/2010 12:56 AM

Think of corrosion inhibitors addition[mild dosage of reducing agents of good temperature resistance[stannous chloride, sodium bisulphite, glucose or glucose substitutes like Hydrol] to the 50%KOH liquor.

Heat, alkalinity, dissolved oxygen with metals-corrosion is unavoidable.

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Guru
Hobbies - DIY Welding - New Member

Join Date: Sep 2007
Posts: 1601
Good Answers: 58
#2

Re: Nickel Corrosion and Compatibility in KOH Unit

02/27/2010 8:26 AM

Information on corrosion of nickel in caustic potash (KOH)can be found at http://www.specialmetals.com/documents/Nickel%20200%20&%20201.pdf

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Power-User

Join Date: May 2007
Posts: 225
Good Answers: 4
#3

Re: Nickel Corrosion and Compatibility in KOH Unit

03/02/2010 6:33 AM

Have a look also at this publications from NIDI

ALLOY SELECTION FOR CAUSTIC SODA SERVICE

http://www.corrosionsource.com/technicallibrary/nidi/literature/pdf/10019.pdf

hope this help u

S

corrosion & rust protection

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