There are companies that specialize in "hard facing" and utilize plasma deposition of hot gas vapors or hot gas streams to deposit stellite, boron nitrides and the like. Spray deposition and even hard chrome plating are methods. Try Googling some
And one of my Valve Vendors tells me he cannot supply as scheduled due to a dire lack or shortage of boron in the world and now cannot provide tungsten carbide trim for the valves. I asked him about stellite and hardfacing and was talked to in circles for about 15 minutes. lol.