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Engineering Fields - Piping Design Engineering - New Member

Join Date: Mar 2009
Location: Mumbai
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Hydrogen Peroxide Material

09/25/2010 1:00 AM

I have seen SS316 being used for Hydrogen Peroxide service and that too preferable SS316 L. My doubt is why we cant use Alloy 20 or Hastealloy material for this hydrogen peroxide service? Could have raised this issue in Chemical Section also but looking for a mechanical reply.

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Guru

Join Date: Jul 2005
Location: Stoke-on-Trent, UK
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#1

Re: Hydrogen Peroxide Material

09/25/2010 12:50 PM

You probably could, I would check with supplier of H2O2 e.g. Interox. But likely to be more expensive than SS316L.

Cheers.......Codey

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Commentator

Join Date: Sep 2008
Location: Vancouver, BC
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#2

Re: Hydrogen Peroxide Material

09/26/2010 12:47 AM
The Material Selected

Hastelloy-Cr

Interacting with the Chemical

Hydrogen Peroxide 100%

Has a Compatibility Level of

A-Excellent

source: http://www.coleparmer.com/techinfo/chemcompresults.asp

Explanation of Footnotes
1. Satisfactory to 72°F (22° C)
2. Satisfactory to 120°F (48° C)

Ratings -- Chemical Effect
A = Excellent.
B = Good -- Minor Effect, slight corrosion
or discoloration.
C = Fair -- Moderate Effect, not recommended
for continuous use. Softening, loss of strength,
swelling may occur.
D = Severe Effect, not recommended for ANY use.
N/A = Information Not Available.

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Anonymous Poster
#3

Re: Hydrogen Peroxide Material

09/26/2010 1:51 AM

Check for decomposition in presence of trace metals before changing the containers etc.

H2O2 can violently decompose in presence of trace metals such as transition metals, Manganese etc.

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Guru

Join Date: Jul 2005
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#4

Re: Hydrogen Peroxide Material

09/26/2010 9:06 AM

I worked on a water treatment job some years ago and if I remember right the spec said SS tanks had to be polished internally.

Also if ball valves are used they must have a hole drilled through the ball so there is no trapped volume of liquid. Otherwise this could decompose and liberate oxygen, causing high pressure.

Cheers.......Codey

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Power-User

Join Date: May 2007
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#5

Re: Hydrogen Peroxide Material

09/27/2010 3:24 AM

You can use Alloy 20 but the corrosion rate depends on the H2O2 conc and operating temperature, i've found data on Alloy 20 and at 100% conc the max corrosion rate is < 20 mpy. (NACE CORSUR)

here you have some good info on materials compatibility with H2O2:

http://www.outokumpu.com/applications/corrosion/view_details.asp?name=HY18

Materials of Construction for the Storage of Hydrogen Peroxide

http://books.google.it/books?id=KXwgAZJBWb0C&amp;pg=RA1-PT421&lpg=RA1-PT421&dq=alloy+20+hydrogen+peroxide+corrosion&source=bl&ots=ReNWAuzuXg&sig=I4hLzXdmY-jJRPnZixwptRVoEbM&hl=it&ei=t0OgTOK4ApCMswadja3mDg&sa=X&oi=book_result&ct=result&resnum=2&ved=0CCMQ6AEwAQ#v=onepage&q=alloy%2020%20hydrogen%20peroxide%20corrosion&f=false

S

corrosion & rust prevention

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