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Anonymous Poster

Refractive Index of a Solvent

08/19/2005 11:01 PM

Safiyet Kurklu writes:
I work for a manufacturing company. In the production plant we use neat mineral oil for processing metal parts. Afterwards we degrease the parts using a solvent degreasing agent in a dip tank. The solvent is non aromatic alyphatic hydrocarbon. The degreased parts are then electrostatic powder coated.

As we degrease the parts, the amount of oil in the solvent is increased. And after reaching a certain amount of oil level, naturally we cannot degrease the parts properly and we replace the used solvent with the fresh one.

Until know we decided on replacing used solvent with the fresh one experimetally. It was ok for the small quantities of parts and solvent.

But now we will increase the production quantity. This means our production speed will increase and we will not be able to make eye control to determine the oil level in the solvent in order to decide on the time we will replace the used solvent with the fresh one.

Therefore, I need a methodology to determine the time to replace the used solvent.

I thought of getting samples from the "solvent with oil" everyday and tracking the refractive index of it.

Continued below - click Reply / Read More I made some searches and obtained the following info:

1)I should use a hand refractometer. Because they are cheaper than the desktop ones.

2) I learned the refractive index value of the solvent from its manufacture. It is 1.4150 for the clean solvent

3) I learned the refractive index value of the mineral oil from its manufacture. It varies between 1.482 and 1.492

4) The refractive index(nD) scala of the refractomer must be between 1.4000 - 1.500. As far as I see, the only hand held refractometer with such wider range is Atago R-5000

When you read the above explanation, you may think that the above methodology is usable.

However, During my searches and talks, I could not find any one who is using the above methodology for the solvents.

I need to talk to the people who have experience about the above subject and discuss the con's and pro's of the above methodology.

I would appreciate any comment and bit of info.

Many thanks

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The Engineer
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Join Date: Feb 2005
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#1

Concerns with the method

08/22/2005 9:43 AM

The method may work fine, I just would be worried about the oil sticking to the sensor and throwing off the reading. I would imagine a Photoelectric sensor would work well if the refractometer doesn't do a good enough job, though again, the oil might stick to the sensor, throwing it off.

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Join Date: Aug 2005
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#2
In reply to #1

Re:Concerns with the method

08/22/2005 4:02 PM

Thanks alot for your comments. I had not thought about that the oil might stick to the sensor and throw off the reading. I will keep this in mind. The oil manufacturer informed me that they have been measuring the refractive index of the oil for each production batch and the refractive index must be between 1.482 and 1.492 in order to guarantie the quality. But he did not tell me what tool he is using for measuring the refractive index. So I will ask him. Thanks again for the comments.

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Join Date: May 2005
Posts: 92
#3
In reply to #2

Re:Concerns with the method

08/23/2005 6:25 AM

Is it possible to avoid this problem by measuring the viscosity of the contaminated solvent? Just a thought

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