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Water Content In Oil. Units Equivalences.

02/21/2012 9:57 AM

Dear all,

checking the quality of some oils, found in the analysis tickets the water content expressed as "% water saturation" , I am familiar with ppm and percentage in volume.

The fluid and the conditions influence the value of saturation, but I have not been able to find a table or formula to convert it into other units.

Could you please indicate how to do it, or where to find?

I have explored some dozens of pages without luck.

Salu2 cordiales,

Abel

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#1

Re: Water Content In Oil. Units Equivalences.

02/21/2012 10:08 AM

This might help.

http://www.rapidtables.com/convert/number/Percent_to_PPM.htm

Here's a table from another site.

It looks like the conversion site is accurate.

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#2
In reply to #1

Re: Water Content In Oil. Units Equivalences.

02/21/2012 5:14 PM

Dear Kramarat,

many thanks for your answer.

It is near but not what I look for.

I do have "% of water saturation in oil" at hand.

It is not the same than absolute % of water content.

And I do need to translate it into ppm or absolute %.

Some hint about it?

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#3
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Re: Water Content In Oil. Units Equivalences.

02/21/2012 7:28 PM

You lost me.

But, if I was charged with finding the exact amount of water in a particular sample of oil, I would set up a small distillery, heat the oil until the water vaporized, send it to a cooling container, and measure the amount of water compared to the total initial sample. This could be measured by weight or volume. I would think that you could obtain very accurate measurements.

This entire site looks like a good resource and includes methods that I'm not familiar with.

http://www.machinerylubrication.com/Read/2149/dry-oil

The more details you include about what you are doing, the better the chances of getting an answer. Somebody here will know.

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#4

Re: Water Content In Oil. Units Equivalences.

02/22/2012 12:14 AM

I think you may find the answer to your question here:

http://www.machinerylubrication.com/Read/200/water-saturation-screening-oil

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#5

Re: Water Content In Oil. Units Equivalences.

02/22/2012 12:54 AM

Dear all,

The preliminaries are:

Barrels of oil for hydraulic circuit were filtered and cleaned to NAS 6 level, getting them ready to fill the circuit once this was flushed.

These barrels were stored for some time and, being suspicious about the storage conditions, I requested the oil to be checked before marking it as "ready to go".

Now, I went trough the articles you indicated earlier, and they state very clearly that the measurement of water saturation in the oil is a more reliable method to stablish the amount of water that certain oil, at certain specific conditions, can contain safely.

I do have several values of "% water saturation" given by a HYDAC oil analiser,

With the oil type (Shell Tellus VG 68) , being the pressure atmospheric during the measurements , there should be some way to convert this value in ppm or simple %.

More in the line of the results that would be obtained in the distillery that Kramarat suggest (and althought appealing, I do have the means to do that, unfortunately).

Maybe they can not be converted, and I am hitting my head with a wall??

Some idea??

In any case thanks for the time and the attention,

Salu2

Abel

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#6
In reply to #5

Re: Water Content In Oil. Units Equivalences.

02/22/2012 5:17 AM

The topic is new for me but it is drawing interest. It seems from the analyser results that it is giving relative content of water in percentage with respect to maximum water at saturation at those test conditions.

Maximum saturation content of water at the test condition shall be given by manufacturer, i hope.

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#7
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Re: Water Content In Oil. Units Equivalences.

02/22/2012 6:52 AM

What does the manual say?

What does 46.6 mean? If it's the percentage of water saturation in the oil, no conversion in the world is going to make the oil usable.

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#10
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Re: Water Content In Oil. Units Equivalences.

02/22/2012 9:35 AM

I wouldn't worry about conversions. Use the data that the analyser provides, and remedy the situation accordingly.

Q: What is the desired saturation level in hydraulic and lubrication systems?
A: Since the effects of free and emulsified water are more harmful than those of dissolved water, water levels should remain well below the saturation point. However, even water in solution can cause damage and therefore every reasonable effort should be made to keep saturation levels as low as possible. There is no such thing as too little water. As a guideline, we recommend maintaining saturation levels below 45% in all equipment.

From here:

http://www.hydacusa.com/techsupport/faq_fluidservice.htm#6

Tech support may be able to help with conversions, but they will only provide a different way of looking at the data collected. Personally, I would use the numbers from the Hydac analyser as they are.

This explains why:

Q: What is the advantage of measuring the saturation level rather than PPM?
A: Using readings in PPM to ascertain a harmful level of water is difficult due to differences in fluid properties, including oil age, fluid type, and additive levels. Furthermore, this gives only a quantitative measure and does not answer the question whether or not the water content is still acceptable. By contrast, the saturation level provides a clear indication of the fluid's condition.

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#11
In reply to #10

Re: Water Content In Oil. Units Equivalences.

02/22/2012 9:53 AM

What you are attempting to do is akin to expressing millimeters as parts per kilometer/percentage of kilometer, rather than just using them as the more accurate units of measurement that they are.

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#14
In reply to #11

Re: Water Content In Oil. Units Equivalences.

02/24/2012 9:26 AM

You hit the nail.

Now that I understand the difference and the principle, I requested to the supplier of the equipment his standards in the "new" units.

Actual values are ranging 30% / 50ºC, and going down.

I will install a water oil filter on each circuit after the initial filling, and request the customer to use higroscopic breathers in the reservoirs. A must here, really.

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#8

Re: Water Content In Oil. Units Equivalences.

02/22/2012 9:15 AM

I guess this particular measurement is new to many of us, but assuming that what you are trying to determine is the relationship between percent saturation and ppm,you must determine how many ppm is equal to 100% saturation under specified conditions (probably temperature and pressure). You should then be able to simply scale to the number you are looking for. For example, if saturation at the specified conditions is 8800 ppm and your measurement reads .60 saturation, the water content is .6 X 8800 = 5280 ppm.

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#9

Re: Water Content In Oil. Units Equivalences.

02/22/2012 9:24 AM

% saturation can be seen as equivalent to relative humidity in air. As the air warms up, it can hold more water. Similarly, oil when heated, can hold more dissolved water.

Another way of looking at it is, when air cools far enough, it rains. The total water content while cooling did not change, only the ability of the air to hold the water. When oil cools, water can precipitate out as free water. Even though no one has added water to the oil, its ability to hold dissolved water is reduced at low temperatures.

There is a way to relate % saturation to ppm. The parts per million is an absolute measure of the amount of water contained the oil. The % saturation is a measure of how close to saturation level the oil is, i.e. relative humidity.

In order to convert % saturation to ppm or vice versa, you need to conduct tests on each individual oil to create a saturation curve. This will tell you the maximum amount of water that can be held in solution by that oil at every temperature. If an instrument then reads 40% saturation at 45 degrees C, you can go along the curve to the 45 degree mark, and see the maximum water content. If it is 600 ppm at 45 C, for example, then you know that the water content is 240 ppm, 40 % of 600.

Creating saturation curves is something that needs to be done in an oil analysis lab. It is possible that your oil supplier can provide this. You may also have to go to an oil analysis lab.

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#12
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Re: Water Content In Oil. Units Equivalences.

02/22/2012 12:43 PM

You are almost correct, but made a common error. Air doesn't "hold" water. Water saturation is independent of what gas the water vapor happens to be mixed with, or whether it is even mixed with another gas. The same rules apply in a vacuum. It is the partial pressure of water vapor alone that is the determining factor. I believe meteorologists have propagated the myth of air "holding" water.

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#13
In reply to #12

Re: Water Content In Oil. Units Equivalences.

02/22/2012 12:50 PM

OK. You are correct. I didn't want to get into a deep technical explanation here, so I used the colloquial language that most are used to. The intent was to explain the issue in understandable terms. It wasn't really a "myth"-take.

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#15

Re: Water Content In Oil. Units Equivalences.

02/24/2012 9:30 AM

Dear all,

I got it, finally.

With your detailed and kind help, and the necessary dosis of personal effort, switched to the new units. Moving forward instead of backward.

Many thanks to you all.

Abel

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