In some applications semi-conductive paint is applied to reduce corona affect and in other applications the coating protects the component from ozone damage and/or to improve the insulation rating.
Contact with the associated breaker manufacturer technical support department should provide specific answers to your questions.
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They said; "Brain size?" I heard; "Train size?" so I said: "I'll take a small one, thank you."
As rightly said by Shockshiscan , painting allows to reduce distances as the dielectric constant of epoxy paint is different from the gas itself, this allows to minimize the electromagnetic field on the conductor, where the discharge may start.
In my opinion, the conductive painting -on
the inner part of the insulated corona shield-is connected with the
conductor-at high voltage potential. Doing so no electrical field will be
between the conductor and the corona shield mainly in the connection area where
the electrical field usually it would be higher due to presence of many edges.
High electric field in the air gap between conductor and the corona shield would
produce electric arc which could damage the corona shield insulation.
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