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Radioactivity in Pure Lead

09/30/2015 7:08 AM

Pure Lead used for Shielding Radio activity , also has its own radionucleide. When they say Pure Lead with < 50 Bq./Kg or <10 Bq./Kg, they perhaps mean the property / quality of Lead.

Is this quality by virtue of its occurrence/origin or is it metallurgy that control it.

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#1

Re: Radioactivity in Pure Lead

09/30/2015 7:35 AM

Lead for keeping radiation out (e.g. low-background shielding for a detector) differs from lead for keeping radiation in (i.e. for radiological protection) in that it must contain as little by way of radioactive materials as possible, to avoid interference with the measurements being made.

It is generally selected by test, and depends on the origin of the lead (and any processing it may have been through which may have contaminated it - e.g. recycled lead which may have had impurities in the melt).

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#2

Re: Radioactivity in Pure Lead

09/30/2015 7:45 AM

One of the factors is how "old" the lead is since lead is in the decay path of other radioactive elements:

http://chemistry.stackexchange.com/questions/29196/why-is-lead-radioactive

" Important naturally-occurring radioactive lead nuclides are:

214Pb (t1/2 =26.8 min) from 238U

210Pb (t1/2 =22.3 a) from 238U

211Pb (t1/2 =36.1 min) from 235U

212Pb (t 1/2 =10.64 h) from 232Th

On a geological time scale, their half-lives are very short. Nevertheless, these lead nuclides are members of the 238U, 235U, and 232Th decay series. Thus, they are constantly reproduced by decay of their respective mother nuclides. Therefore, all environmental samples (including soil, water, air, plants, and animals) naturally contain significant amounts of radioactive lead nuclides. However, in various materials (e.g. residues from mining or oil and gas production, fertilizers, building materials), the concentration of natural lead nuclides can be strongly enhanced by technology.

When lead is freshly refined (chemically purified), most of the mother nuclides are removed and the short-lived lead nuclides quickly decay. Nevertheless, the lead still contains significant amounts of 210Pb (t1/2 =22.3 years) . The presence of 210Pb is a source of background mainly through the lead X-rays and bremsstrahlung caused by high-energy beta radiation emitted by its decay product 210Bi. This background is a real problem when lead is used as a shielding material for low-background detectors. Therefore, some shields are made from selected lead with certified low 210Pb content. Preferably, very old lead is used. Since 210Pb decays with a half-life of 22.3 years, samples of lead that are many decades old are relatively free of this activity. In one extreme example, 2000-year-old lead was salvaged from a sunken Roman ship."

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#3
In reply to #2

Re: Radioactivity in Pure Lead

09/30/2015 9:15 AM

Assuming these Pb, lead you just cited are from decayed radioactive material. Are there pure lead Pb (stable nucleus-where protons, neutrons and electrons counts the same and stay the same overtime) aside from Pb by radioactive decay?-there must be-the table of elements tells us so.

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#4
In reply to #3

Re: Radioactivity in Pure Lead

09/30/2015 9:57 AM

204Pb is primordial (not a radioactive decay product) and is stable.

https://en.wikipedia.org/wiki/Isotopes_of_lead

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#6
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Re: Radioactivity in Pure Lead

09/30/2015 10:23 AM

I was right, the first time though. hehehe. Thanks Rix, you really are a nice fella around, I observed.

I don't mind the OT every time. For me it has a new meaning, it goes like "Occupational Therapist". I don't know.

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Re: Radioactivity in Pure Lead

09/30/2015 6:39 PM

Remember, troll also starts with "T".

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#9
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Re: Radioactivity in Pure Lead

10/01/2015 1:51 AM

You know what's the problem here

1) Anonymous poster

2) Anonymous poster

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#7
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Re: Radioactivity in Pure Lead

09/30/2015 3:01 PM

There is an implication here that many people will miss. When these these lead atoms transmute they become a different element. Thus the "pure" lead now becomes lead with impurities.

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#5

Re: Radioactivity in Pure Lead

09/30/2015 10:14 AM

If you're interested in low-background detection and shielding, this application note (click) from Canberra makes good reading.

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#10

Re: Radioactivity in Pure Lead

10/26/2017 5:45 AM

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