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Anonymous Poster

Wastewater treatment

07/26/2007 10:38 AM

Hello All!

I'm looking for a small list of companies who have a good scrubber water treating process. It needs to operate at 75 gal/hr, and be able to filter out 5-10 kg of salts, disolved solvents such as HCl, Dioxins, and PCBs. I'm trying to compare prices and processes. We currently have a bid from a company called CASTION. They use a two stage process involving reverse osmosis and vacuum distillation. We are just nervous that the vacuum distiller will evaporate solvents such as HCL with the recycled water yielding an impure product. Any insight to this would be greatly appreciated. I'm looking for quotes, FDs and PFDs. Thanks!

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Guru

Join Date: Jul 2007
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#1

Re: Wastewater treatment

07/27/2007 4:46 AM

Why RO? Wouldn't a membrane bioreactor [MBR] installation be a more appropriate solution? And what happens to the dioxin-laden sludge?

HCl has a high affinity for water, so the risk of carry-over in the evaporator is low. One way to minimise the risk would be to apply pH correction by proportionally dosing alkali.

Be afraid of free chlorine near membranes. Be very afraid. One way of eliminating it is to dose sodium metabisulphite upstream, static-mix, monitor ORP upstream and dump any water that contains free chlorine.

Also, advise the suppliers of the levels of impurities, then ask for process guarantees to achieve the required discharge consent limits, and see what happens.

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Power-User

Join Date: Jan 2007
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#2

Re: Wastewater treatment

07/27/2007 5:31 AM

Hello,

a nice coctail you have - I propose because of that you should complete your selected solution (whatever that might be at last) with a UV wet oxidation stage.
In which country are you ?

Regards Uwe

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Guru
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#3

Re: Wastewater treatment

07/29/2007 9:48 PM

You are right. The vacuum still will cause dissolved volatile solvents to carry over with the water. However, the solvent vapors will be released into the atmosphere, so it's not advisable to do this unless you have a means of removing the fumes e.g. an activated carbon filter. Dissolved organics can also be destroyed by oxidation and UV light in the 185 nm spectrum. HCl should best be neutralized with NaOH to form NaCl and water. The RO process can then easily remove it.

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