I have a 2002 Volvo V70 Cross Country that might need a catalytic converter. In the past, I'd add a bottle of Pass or Don't Pay to the gas and it would help. My mechanic told me it's a waste of money and I need a cat (the car has 240K miles and he said the cat is done). So, I did some thinking and I came to the following conclusion. Maybe someone can shed some light on this.
1. Since it's a catalytic converter, the catalysts (platinum and palladium) start the chemical reaction, but are not consumed.
2. The chemical change happens by running the exhaust gas over the catalyst (must be hot). A lot of surface area is required and only a very thin catalyst layer is needed. A honeycomb type structure is coated with the catalyst. Exhaust gasses are passed through the honeycomb and the catalyst starts the chemical change - clean the exhaust gasses.
3. OEM catalytic converters have a thicker catalyst layer vs the cheapo aftermarket cats.
4. If the cat is bad, the downflow oxygen sensor will give out a fluttering signal - not a constant output voltage, like with a good cat.
5. The catalyst may be stripped from the honeycomb material through normal ablation of the exhaust gasses, but I don't believe this is the case with my car.
6. If the honeycomb gets covered in soot or debris, the cat won't work properly and the OBD II will throw a P420 or P430 code. It usually will just fail the catalyst part of the test, not just leave the monitor incompleted.
7. If the cat is less than 95% operational, the OBD II computer will throw a catalyst code. The cat has to be working well to pass the test.
8. The OBD II computer must clear it's monitors before giving a pass to the smog test. One of the monitors is catalyst.
My car didn't throw the P420 or P430 code. In fact, the CEL isn't on. I did have to jump start the car (sitting too long) and it reset the smog computer - all monitors are reset and must be cleared. As of today, all the monitors have cleared except for catalyst and evap. California will give me a pass if the evap hasn't cleared, but not if the catalyst hasn't. My mechanic is going nuts trying to get the catalyst to clear. He told me he's driven over 400 miles and it still won't clear. He's thinking that I need a new cat, but he hasn't run a test on the O2 downflow sensor, so to me, he's guessing, which I'm not too pleased with. I don't want him to buy an aftermarket cat, because I don't think it'll last a long time. And I don't want to buy a new OEM, because it's expensive and it may not help solve the problem. Before changing the cat, I'd like to try cleaning it, but before doing this, I'd like to know if the cat is bad or why it won't clear the catalyst monitor. I was thinking that cleaning the cat may help clear the monitor.
The ways to clean a cat are:
1. Fill the gas tank with a 90/10 mixture of gas and lacquer thinner. Then drive the car on the freeway and push a lot of exhaust gas through the car. I've even read that you run the tank to near empty. My concern is that the lacquer thinner could damage other parts of the fuel system or strip some coating off and clog up the fuel system.
2. Take the cat off and let is soak overnight in laundry soap and water. Clean it and put it on the car and drive it until the cat is hot.
3. Take the cat off and let is soak in a strong lye (NaOH) solution overnight, then rinse well and put it back on the car and drive it until the cat is hot.
4. Run water and oven cleaner through the cat. Spray the oven cleaner in the cat and let it sit for a few minutes. Then run water through the car while blowing air in at the same time. Rinse, then install and drive the car until the cat is hot.
5. Let the cat sit in an acid bath of muriatic acid (pool acid) for a few hours. Rinse and install. Drive the car until the cat is hot. Wondering if the acid will damage the steel in the cat shell.
Anyone have an idea on how to get my old work station wagon to legally pass the smog test? I don't want to pay someone to pass the car, when the car isn't legally smogged.
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