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Creating power out of thin air. Article on zdnet

10/28/2007 3:29 PM

Hi guys, just read a news flash about this so called seebeck effect which generates electricity out of the different states of materials in close proximity.

Now they all make it sound as if it is all very new but I think that is not strictly true. I can remember I had a fridge for use in cars and or caravans which used a very small electric device that could cool or heat depending on the polarity of the power supply. when reading the wiki on this they also give you a diagram which looks like what I can remember that fridge used. Now that fridge must have been 15 years ago!

wiki below.

http://en.wikipedia.org/wiki/Peltier-Seebeck_effect

Does any one out there know if these are indeed being used commercially or if it is still lab tech stuff? I am relatively sure that it must have been seebecks principle.

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#1

Re: Creating power out of thin air. Article on zdnet

10/28/2007 5:51 PM

Can't remember Seebeck effect - I know the name from way back.

Peltier effect heat pumps have been used for years, typically for cooling semiconductors & sub-assemblies, and are readily available.

See, for example, RS238-2988

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#2
In reply to #1

Re: Creating power out of thin air. Article on zdnet

10/28/2007 6:02 PM

... Just looked at the article. Sounds like the usual bulls**t. Run these things backwards, and you get electrical power out - BUT you need the temperature differential (& heat flow) for it to work. The energy's got to come from somewhere.

How about jumping up & down on a Piezo crystal? You'd get lots of volts, which in theory you could convert to lower voltage/more current and use to charge batteries, heat your house etc. etc. But how long could you keep jumping up & down?

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#3
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Re: Creating power out of thin air. Article on zdnet

10/28/2007 6:10 PM

I think you miss a slightly small but important point.

They are talking about temperature differential and on car surfaces you would have that especially when you drive around. Find an exposed bit of the steel body inside your car and when you go along at 70 miles per hour it is deffinitely cold and remains so. That energy would be lost anyway so it could be reused which is not the same as for nothing but still converting waste.

Jumping up and down on a piezo crystal is not a good idea, you get a heart attack and the heat you generate is much higher than the voltage ever will be anyway

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#4
In reply to #3

Re: Creating power out of thin air. Article on zdnet

10/28/2007 6:27 PM

"They are talking about temperature differential " - you need a heat source the other side of the cold bit. If you're using the waste heat from the engine, then maybe this is a possible way of scraping back a bit of the lost stuff.

I'm all in favour of making ICE cars more efficient (we're stuck with petrol engines & similar for a while), but I don't think this is the holy grail of free energy that the article seems to be hinting at. Certainly needs a lot of cost/benefit work + study of practical application.

Maybe I'm just an old cynic...

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#11
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Re: Creating power out of thin air. Article on zdnet

10/29/2007 10:35 AM

They are talking about temperature differential ...

The article says: "Conceivably, one could take that material and fashion it into a passive fuel cell that can create power by just sitting in an ordinary room heated to about 72 degrees Fahrenheit, leading to self-charging electronic devices." That seems to specifically say they are not talking about differentials.

They go on to say: "Although the fuel cells would ultimately produce electricity by just sitting around, producing the materials for the fuel cells takes a lot of power. "Manufacturing is energy-intensive," Surany said.

The whole article strikes me as utter BS. It seems they are deliberately confusing things, by suggesting that since peltier junctions work (on temperature differentials), that their scheme will work without temperature differential.

Instead of being in a "normal" energy state at room temperature, the altered material is in a normal energy state at, hypothetically, minus 40 degrees Celsius or colder. Thus, when this material is put into a room-temperature environment, it's excited.

As far as I can tell this is gibberish. I am unaware of any "normal" energy state for a material. Any material at a temperature above absolute zero is "excited".

Perhaps it's just a poorly-written article, but is sounds like fraud to me.

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#5

Re: Creating power out of thin air. Article on zdnet

10/28/2007 10:38 PM

The article on Zdnet (and other news sites, although there only appears to be 2 or 3 versions of the story which have been copied by every man and his dog) looks really dodgy, and the reference to Enocean doesn't make sense as they only use solar cells and piezo actions to operate remote self-contained devices. Other references to piezo generator development also don't make sense as it is not comparing apples with apples.

The part regarding nuclear fusion seems very wrong. Syrdec doesn't seem to have a presence on the web (they are apparently in Princeton, N.J).

.....and it gets worse, this was found........

Theoretically, one could heat the material, too, to get better results. If you heated one square meter of the material to 100 degrees Celsius, or the boiling point of water, the material could absorb 1.2 kilojoules of heat energy. Converting 5 percent of that heat to electricity would give you enough energy to power a car, Surany asserted.

Something smells here .

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#6

Re: Creating power out of thin air. Article on zdnet

10/28/2007 11:51 PM

I haven't read the link yet (I will later) but let me explain what the Seebeck and Peltier Effects are.

The Seebeck effect is the phenomenon that makes thermocouples work. These devices produce an electrical DC voltage when subjected to a temperature differential. The voltage increases as the temperature differential increases. Note that the voltage produced is very small (in millivolts).

These are mainly used for measuring temperatures. If you want to use them as a power source, say to produce even just 12 volts, you'll need about a couple hundred of these things. You'll need less if the temperature differential is higher. Not practical, in my opinion.

The Peltier effect is the phenomenon that makes Peltier devices work. You inject a DC voltage one way and it gets cold. Reverse the polarity and it gets hot. They are commercially available and in use in a lot of stuff. Yes, in laboratory equipment also.

In computers, they can be used to cool the microprocessor chip. They are usually not included in commercial computers though. You buy and install them separately. I think you also need a separate power supply for them.

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#8
In reply to #6

Re: Creating power out of thin air. Article on zdnet

10/29/2007 9:32 AM

Remember small is beautiful by schumacher? he created a thermopile of these devices, used a candle as the heat source and used them to power radio receivers in India.

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#12
In reply to #6

Re: Creating power out of thin air. Article on zdnet

10/29/2007 11:00 AM

Hello Vulcan

Peltier devices are interesting , can i get links on web , any way i too will search but i expect better links from you , thank you

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#13
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Re: Creating power out of thin air. Article on zdnet

10/29/2007 11:12 AM

woof! getting dinged for "quality of links?" that's harsh! tough crowd.

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#17
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Re: Creating power out of thin air. Article on zdnet

10/29/2007 2:56 PM

I really am looking for quality ,i have chinese links presently with me now , but my applications screams for quality , is crowd moving in right direction

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#20
In reply to #12

Re: Creating power out of thin air. Article on zdnet

10/30/2007 12:08 AM

What links? I didn't provide any links. What are you talking about? Do you mean that you want me to provide links?

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#21
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Re: Creating power out of thin air. Article on zdnet

10/30/2007 12:23 AM

If you're looking for links, this site has a list of various sites. Okay, it's a link to more links but you get a lot of choices depending on what you want to learn. Happy hunting!

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#29
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 2:20 PM

ohh , thank you , i was just looking for some source and supplyers so i could get some for my experiments on heat conservation , waste heat manegement and cooling for small devices where fan cooling was inefficient ..,,thank you once again

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#22
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Re: Creating power out of thin air. Article on zdnet

10/31/2007 11:11 PM

Don't forget the thermocouples used to turn off the gas flow to water heaters etc. when the pilot light goes out. Its a single junction, so very low voltage, but enough current to operate an electromagnet that holds the valve open as long as the temperature differential is there.

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#24
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 4:07 AM

May be talking out the back of my head, here, but I can't imagine any practical thermocouple/electromagnet combination that would work in this context. Sure it's not a bimetal strip thermostat?

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#25
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 11:25 AM

Absolutely! I have replaced several; to buy one, you ask for a water heater thermocouple. In fact I cut one open just a couple of months ago, and still had most of it laying on my workbench. You did force me to educate myself a bit further. The thermocouple consists of a Ø 3.1mm copper tube enclosing a Ø 1.4mm wire with apparently fiberglass mesh keeping them separated. I had always assumed that the wire was made of the second metal, but as far as I can see, the wire is copper at the point where I cut it. Unfortunately I discarded the tip, which was badly oxidized. There was a mounting clip a few cm from the tip; I now surmise that the cold junction must be at that clip. Of course the hot junction is the tip, which is placed directly in the pilot flame. This construction would have the lowest possible resistance, so it does make sense. I can't get the camera in position to show the tip in use, but here are photos of the old one. This is the cut end, showing the wire and insulation:

and here is the electrical connector end: There was a threaded collar that held it in place at the valve.

When I was teaching physics, I had a complete unit that I used regularly to illustrate the thermocouple. The coil is wound around a U-shaped steel core, which attracts a flat piece of steel about 10mm x 15mm x 4mm thick. The surfaces where the two pieces of steel meet are ground to an almost mirror finish, so the magnetic gap is extremely small.

To light the water heater, one must press a spring-loaded button that opens the gas valve and moves the flat steel into position. One then lights the flame, and must continue to hold the button down until the thermocouple produces enough current to hold the valve open. In my demonstration unit, I simply had the flat steel tied on the end of a string; when the tip cooled, it would just fall off. These have been the standard safety devices on gas water heaters, and I think on older gas furnaces, for at least 50 years. Newer furnaces have electronic ignition, so no pilot light and therefore no thermocouple. Water heaters, however, normally have no electrical connection, so still use the thermocouple.

Dick

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#27
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 12:07 PM

Thanks, Dick. Must say I'm pretty amazed !

Also glad I didn't say anything out of order. It's temping at times like that to immediately think "what a load of rubbish!", and say as much.

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#26
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 11:26 AM

If it were not currently rather cold here, and if I were made of money, I'd take apart the fuel valve on my furnace. Just a couple of weeks ago I replaced the thermocouple for my control valve, and despite the fact that it only produces 35 millivolts, it can operate a latch on the gas valve, so that when the pilot light goes out, the valve closes.

While trouble shooting the failure of this device, I'd guessed that it was a mercury expansion device -- supported, I thought, by the fact that a copper tube connects a bulb in the pilot flame to the gas valve. Mercury expansion would provide ample force to latch a valve. I thought. But as I poked around, I found that it is indeed just a thermocouple -- and I assume that Dick is correct -- that it operates an electromagnetic device. The mechanical end of it must be pretty nicely designed to allow such a tiny bit of energy to reliably do the job. Given that the valve for the pilot light remains open for (often) years at a time, there'd seem to be a high probability for sticking open due to corrosion.

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#28
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Re: Creating power out of thin air. Article on zdnet

11/01/2007 1:14 PM

While writing my previous post, I originally wrote iron core, but then I remembered that after many years of use in the classroom, the almost-mirror surfaces were still shiny. That made me change the wording to steel. I have no idea what alloy is used, but it is obviously magnetic, and essentially stainless.

You're right - my previous one lasted at least 10 years, so I was surprised when this one lasted only 2 or 3 (brand new WH 2 or 3 years ago).

Dick

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#7

Re: Creating power out of thin air. Article on zdnet

10/29/2007 9:13 AM

Yep, the Peltier effect. I've used Peltier devices in several novel applications. The problem is that they are very inefficient for cooling and you have to dump the heat somewhere close to the cool side, so you have to have some air or fluid cooling system for the hot side.

The typical use for Peltier devices is for chips, CCD devices in telescope cameras and the "Icy Esky" type of cooler. But you really have to have power to spare to make this workable.

As far as use for generating power I can see that it would be easy to get some high temperatures on one side of the device, but how are you going to get and keep) the cold side cool? The temperature differential has to be significant (like, freezing on one side and boiling on the other) to get a lousy 12vDC out at 8 - 10A. So call it 100w out of a 1600mm2 area with the cold side at 0C.

It's not at all straightforward to get the cold side cold in a car application. Without active cooling of the cold side you might get enough power to play the radio. By the time you power a cooling device you've used more power than you've gained.

This is why Peltier devices are really used only in a few niche areas. They just aren't that efficient and usually require a lot of peripheral hardware to deal with cooling.

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#9

Re: Creating power out of thin air. Article on zdnet

10/29/2007 9:35 AM
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#14
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Re: Creating power out of thin air. Article on zdnet

10/29/2007 12:07 PM

As a development of the technology, this seems more serious:

http://nextreme.com/

It is so small that it can be integrated to generate usable power, w/o nuclear fusion tough.

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#10

Re: Creating power out of thin air. Article on zdnet

10/29/2007 10:09 AM

Using conductors with dissimilar materials that have their conduction band electrons in shells further apart would certainly help increase the efficiency of a peltier device, but radically change the cost advantage in a direction one would not want to go.

I think most of the limitations of a peltier device have already been listed above, so I won't go into those, but my challenge in trying to use them in the past was getting a device with a large enough active area to really be useful with the temperature gradiant that I had to work with (which for me was less than 50'C).

I think the current state of Peltier-seebeck devices is still very nascent and there is a lot more which can be done. Perhaps a hybridized approach of more exotic materials actually optimized for reverse peltier operation and capitalizing more on thermionic emissions would be workable in the not so distant future

In the words of Orville Wright, "If we all worked on the assumption that what is accepted as true is really true, there would be little hope of advance"

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#15
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Re: Creating power out of thin air. Article on zdnet

10/29/2007 12:41 PM

Here's a different approach to "free" energy, the negative electron-affinity cathode.

All of us who are old enough to remember vacuum tubes know about thermionic emission. If you run a hot (2000C) cathode in a diode, you can actually get a current, but, of course, the cost of heating the cathode, electrically, is much greater than the current produced.

If a similar diode were made with a "room temperature" cathode, it might be a useful source of electricity. The heat supplied to the cathode provides the energy to get the electrons (to tunnel) out of it. Based on some Chinese research, here is how to do it.

Start with a suitable substrate, probably a semiconductor, possibly metal or carbon. Deposit a half monolayer of cesium and a half monolayer of fluorine or oxygen. (I've tried it, and the vacuum system has to be more perfect than I could get it) The result is a very bipolar "molecule" on the surface, and ordinary thermal electrons can tunnel through and be repelled by the surface. The cathode would be cooled by the departing electrons, but any low grade heat source (eg. air, sea water) could keep it warm.

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#19
In reply to #15

Re: Creating power out of thin air. Article on zdnet

10/29/2007 9:22 PM

This reminds me of a Chinese researcher named Dr. Fu who claims to have converted ambient thermal energy into measurable electrical current -- without using a temperature gradient. In other words, rectification of thermal electrons/Johnson noise. Yes, a violation of the second law of thermodynamics! (here we go again). Now I think it's far more likely that he is mistaken. But if so, the mistake is very subtle and difficult to point out (the skeptics on the Yahoo Free_Energy group offered some critiques, but nothing that definitely nailed down the error). Anyway, I offer these links for your bemusement:

Realization of Maxwell's Hypothesis: an Experiment against the Second Law of Thermodynamics
X. Y. Fu and D. T. Fu, Shanghai, China, November 2003
arxiv.org/ftp/physics/papers/0311/0311104.pdf

Another Way to Realize Maxwell's Demon
X. Y. Fu and D. T. Fu, Shanghai, China, September 2005
arxiv.org/ftp/physics/papers/0509/0509111.pdf

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#16

Re: Creating power out of thin air. Article on zdnet

10/29/2007 2:41 PM

This is the best use for peltier coolers :)

http://www.grynx.com/projects/peltier-beer-cooler/

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#18

Re: Creating power out of thin air. Article on zdnet

10/29/2007 6:03 PM

Peltier effect heating and cooling "car fridges" are on sale in Australia and they work quite well.

Have not used one for heating but excellent for cooling.

The Peltier effect is used quite a bit in some industrial purposes.

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#23

Re: Creating power out of thin air. Article on zdnet

11/01/2007 1:00 AM

I used to be involved in the TEC (Thermo-Electric Cooling) community at one time while an employer was developing a TEC industrial cabinet air conditioner. Even 10 years ago, people were discussing the Seebeck effect as it applies to Peltier devices. The main thrust of the discussion was in how, if cheaply mass produced, they could be used in places where heating was necessary for something else, but was essentially being wasted afterwards. An example would be hot flue gasses from a furnace or boiler.

Here is a wealth of links and information for those who are interested.

http://www.zts.com/

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#30

Re: Creating power out of thin air. Article on zdnet

04/11/2008 1:33 PM

I have seen pictures of a themopile in a kerosene lamp chimney which, "for free", allegedly provided enough electricity to power a tube-type radio during WW-2.

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#31
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Re: Creating power out of thin air. Article on zdnet

04/11/2008 6:49 PM

Neglecting capital costs, it was free - to the extent that the lamp was otherwise only used for illumination; the thermopile didn't degrade the light output or cause the lamp to use more fuel - it just used some of the waste heat.

Just been looking around and found this:

Identified as a Russian device from the '50s, which was used for powering radios.

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