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Cast Iron Grade Identification from Spectroscopic Analysis

06/01/2024 5:49 AM

Can anyone shed some light on identification of a grade of cast iron based on the XRF Spectro shoot pictured ?

Cast Iron would usually be 2 - 4 % Carbon with Fe and other alloys in small concentrations.

78 % Zinc does not make sense and Cobalt shouldn't be anywhere in this sample ?

The test instrument is calibrated and tested other samples correctly prior to this one.

Testing on the other side of the component yielded a result of 84 % Zinc and 14 % Iron.

The component is part of a hydraulic cylinder.

Any metallurgists got ideas of whats going on here ?

Fe 21.19 %
Co 0.444 %
Cu 0.123 %
Zn 78.07 %

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#1

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/01/2024 8:48 AM

Maybe diecast Zinc rather than cast iron.

Some places simply used whatever was available for the melt.

Or else you're measuring a thick Zinc coating rather than the parent metal.

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#4
In reply to #1

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/02/2024 5:24 AM

Correct , it was a very thin zinc plating , silly i overlooked that when "The evidence was right under my nose" .

actual Spectro of the cast iron is 97 % Fe , 1.4 % carbon , 0.44 % Cu , LEC remainder.

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#5
In reply to #4

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/03/2024 10:04 AM

An iron alloy of carbon 2.1% or lower is defined as steel, not cast iron.

A small variation in percentage of carbon has a big impact on material property.

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#6
In reply to #5

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/03/2024 10:15 AM

I did a test weld with MIG , welding a round bar to it with a fillet weld then tapped it with a hammer , the weld broke off the casting leaving a 0.5 mm indentation in the cast with no fusion , just as you get if trying to weld a gray cast iron.

The item has a fracture in it from impact , if it was steel it would deform rather than fracture.

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#7
In reply to #6

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/03/2024 11:28 AM

Yes.

My point, reading again my comment in #5, wasn’t stated very clearly.

I do not doubt the characteristics of the subject material. The spectro analysis sample seems to have been contaminated, or compromised, or adulterated...

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#2

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/01/2024 9:49 AM

It looks like galvanized iron. Maybe the copper and cobalt are impurities from somewhere else.

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#3

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/01/2024 10:45 AM

"The component is part of a hydraulic cylinder."

I think you need to be more specific.

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#8

Re: Cast Iron Grade Identification from Spectroscopic Analysis

06/11/2024 7:15 AM

Yes. The original equipment manufacturer certainly can. That's what the telephone is for.

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