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Anonymous Poster

Reviving an Acid Tank

05/03/2006 11:23 AM

Hugh Sauer writes:
We have a 10,000 gal. acid cleaning tank. We use it to de-smutt aluminum parts that have been chemically milled. The tank is old and not working very well. Although a tank rebuild is not out of the question I was wondering if there was some economical process, say plating for instance, that would remove some or all of the dissolved crud that is in solution? The acids in the tank are nitric @ 23 oz/gal. and about 15 gal of hydrofluoric. There are some metals from the aloys of the aluminum and residue from the caustic chem mill tank. Thank you

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#1

fix the tank cheap

05/03/2006 9:31 PM

ENCAPSILLATION---handyman--p.s.--inner & outer.

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#2
In reply to #1

Re:fix the tank cheap

05/04/2006 7:29 PM

You might test a sample: add a few drops of sulphuric acid, (H2SO4), to the sample and see if you can precipitate out some of the 'crud` as insoluble sulphates. If it works, and the presence of some residual H2SO4, (probably not much), is acceptible for your process, you can proceed to treat the tank. Due to the presence of HF, I would be reluctant to try electrollysis as Fluorene might be produced. Even a little of that is too much. - Pragmatist

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#3

forget the chemical method, apply elbow grease

05/04/2006 11:31 PM

Has anybody done an actual analysis on the sludge? I would suggest that it is checked rather thouroughly because as I recall most fulminated metals have a nasty habit of being explosive... If the sludge is stable, send a guy in a HAZMAT suit in there with a pressure washer and a vaccum recovery system so waste can be containerized and disposed of per EPA rules.. Once it is clean enough to repair, go with the "fix the tank cheap" suggestion.by handyman (1095) ENCAPSILLATION---handyman--p.s.--inner & outer. --handyman. Hey you'll get a "solution to you solution problem" :) and the guy in the HAZMAT suit will get a great story for his lunch room buddies.

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