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Calculation-Volume of Droplet

04/24/2008 4:08 PM

Many years back in Analytical Chemistry class we were told that for water or other aqueous solutions in air there were 20 drops in each ml of liquid. Since an ml equals 1 cubic centimeter (CC) that means a drolet of water contains 0.05 cc of water. I have measured this volume with a burette a number of times over the years and it is in the ballpark, but then I have also heard other scientists say the value is 30 drops/ml. A difference of 50% in volume.

I understand that the size of a droplet will be primarily impacted by the surface tension of the water or aqueous solution, so I expect there should be somewhere a mathematical expression allowing one to calculate the volume of a droplet from the basic physical properties of the water solution. If that is known, then it should be possible to calculate the size of a droplet for any liquid in air (or other alternative fluid) if all the physical properties are known.


Can any CR4 member direct me to a text that provides a mathematical analysis of the specifics of this problem? There are several situations where calculation of droplet size in air (or particularly in other fluids) from basic physical properties would be helpful. Unfortunately, I am unaware of an appropriate text. Suggestions anyone?


Thanks.

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#1

Re: Calculation-Volume of Droplet

04/24/2008 4:56 PM

Very interesting question.

I have spent a short time looking and cannot find any text that is free. Obviously I am not sure if any of the ones you need to register for is about your subject as I cannot read them, and I am too stingy poor to pay for them

I would initially think there is more to this than water tension alone. The situation under which you have the droplet is also important i.e. sitting on surface, hanging of edge, falling short time or having fallen long time.

I know that rain can come in different shapes and forms and you can have a drizzle with little drops or those painfully large slow falling drops. I don't know how they can be different if water tension is the only parameter here.

I noticed, once on holiday in Spain, when i threw water out a glass down this little mountain, as my brother was walking down there so it had to be done, the droplets gathered speed up to a point and than suddenly they all splat out-wards and became all very many small drops as if the air pressure was holding them back and spreading them out. I don't think they would accelerate after that point but it meant that I could not throw a large amount of water over my brother as it would always spread out before it got to him down there.

Could you not use your burette to drop a measuring jug full to a point and count the drops?

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#3
In reply to #1

Re: Calculation-Volume of Droplet

04/25/2008 12:18 AM

While there are several methods to measure the number of droplets in a given volume and come up with an average droplet size, I would assume (maybe ass-u-me ?) that someone has developed an analytical calculation that relates the physical properties to the droplet size.


Like you, I am not in a position where I have access to the "pay for view" science papers and personally, I balk at the thought of paying to retrieve scientific literature from a journal. Whatever happened to free libraries? Over the years, I and many others have contributed to scientific literature and I (we) never received any remuneration from the publishers, but it was always open literature to the technical public. {But then my wife says I'm just a crabby old man.}

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#2

Re: Calculation-Volume of Droplet

04/24/2008 5:48 PM

Hey Doc,

Just happens that I am working on the development of a performance calculation package for screw compressors and one of the problems in a machine that uses oil spray for cooling is to relate the mass flow of the oil as a fraction of the gas and its effect on compression.

So in one of my references I came across the concept of Sauter Mean Diameter. Not sure I fully understand it yet, but maybe it will help you too.

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#4

Re: Calculation-Volume of Droplet

04/27/2008 4:30 PM

Hi,

I shall try to give you an answer an use same opportunity to give some explanations to the reason rain has different droplet sizes.

If you look at the way a droplet forms you can observe two phases:

- first a hemispherical dome builds up (in fact down) and

- second at a given moment a kind of neck forms becomes thinner and a drop falls down.

All is due to the superficial tension. This force can be considered as a thin membrane which takes a form so that all acting forces will find an equilibrium.

Let us consider the drop as a sphere radius R and the neck as a cylinder diameter "d" < 2*R. The tension in a plane perpendicular to the neck axis will give as a resultant a pressure directed toward the axis and which increases when the diameter decreases. This is the reason why the neck goes thinner. Now the sphere has a weight = 4/3*R^3*ρ*g. The neck has a circumference π*d and the superficial tension on this circle generates a force = π*d*σ. When the 2 values are equal the droplet parts and falls. If we make the computation with σ=73E-3 N/m , ρ=1000kg/m^3 and g=9.81 m/s^2 considering d=2*R we have R=(1.5*73E-3/(1000*9.81))^0.5= 334E-3m which leads to a volume of 4.9723E-8 m^3. 1ml= 1E-6m3 ^thus the number of droplets /ml= 20.11. Value which corresponds amazingly well with literature. This computation shows that at different temperatures since as well superficial tension as specific weight change the number of droplets will be different.

Now with respect to rain droplets dimensions. When for any reason water vapor condenses water droplets appear, some are very small but due to their movement (air turbulence) they collide with other and grow. Their form is in this situation spherical.

Those spheres will fall due to attraction but due to the relative movement to air a aerodynamic force resists the fall. The drag is proportional to the square of the diameter (cross area) and the weight proportional to the 3rd power of the diameter (volume, mass). The ration area/weight is proportional to 1/d which means that for small drops the drag is relatively important and thus the fall will be at low speed, when drops aggregate and the diameter grows up drag becomes relatively smaller and the fall speed increase. Due to the bigger dimensions the own frequency of the spere decreases reason for which the drop changes its form according to the aerodynamic forces acting upon.

This is the reason why it is possible to have different dimensions even during same rain since the droplets can come from heights with different conditions for condensation of the water vapor.

I hope that my answers will help I was not able to frind a source so that i tried to become the source.

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#5
In reply to #4

Re: Calculation-Volume of Droplet

04/27/2008 4:34 PM

"I hope that my answers will help I was not able to frind a source so that i tried to become the source."

You watch too many Star Wars movies I think

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#7
In reply to #5

Re: Calculation-Volume of Droplet

04/28/2008 5:29 AM

I am sincerely surprised that you did not notice the spelling error. It is positive that you start to look at more important aspects. Never the less I mentioned month ago that English is neither my mother nor my father language so that I may use expressions which can be misunderstood in the frame of English private jokes.

I would have preferred a comment on the results that means on the content.

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#6
In reply to #4

Re: Calculation-Volume of Droplet

04/28/2008 12:37 AM

Nick Name--heavy but good looking answer. One additional point which significantly affects drop size is the effective diameter of the tip from which each drop is falling. A micro dropper gives perhaps 30 drops per ml while a larger one gives 15-20. Before the common usage of IV infusion pumps, nurses routinely had to use these values to calculate the flow rates of IV solutions based on drops per minute and the dropper type. Also, holding a dropper at an angle other than vertical changes its effective diameter, so accurate results always required holding the pipette or dropper vertically.

--JMM

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#10
In reply to #6

Re: Calculation-Volume of Droplet

04/28/2008 6:44 AM

I totally agree with you. I considered the most general case with an horizontal fluid separation surface before the droplet forming. I am also not very found of buying expensive books for such problems so that I try, respecting the laws of physics, to find an answer by myself even if not totally correct in general it is a good approximation.

In my previous computation I considered the "neck diameter" = 2*R. If we assume an other value in place of the factor "2" the relationship becomes:

R=(3*δ*σ/(4*ρ*g))^0.5 where δ=d/R.

It is also possible to introduce a value for "d" and use the equation→ R=(3*d*σ/(4*ρ*g))^(1/3).

As an example for a needle with d= 1.3 E-3 m the computation gives R= 1.93 E-3 m and the number of drops/ml n ≈ 104.

I have not the tools to make a true investigation but I tried with available tools to check the order of magnitude.

Shortly before leaving the needle the diameter of the droplet was ≈ 3.3 mm.

From the computation it should be 3.86 mm. I consider that the convergence is for the imprecision of my equipment quite ok.

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#11
In reply to #10

Re: Calculation-Volume of Droplet

04/28/2008 6:56 PM

I am impressed!

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#12
In reply to #11

Re: Calculation-Volume of Droplet

04/29/2008 2:29 AM

Thank you for the kind words

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#13
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Re: Calculation-Volume of Droplet

04/29/2008 7:23 AM

Please accept mine, too. Along with a GA vote, and a personal award:

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#8

Re: Calculation-Volume of Droplet

04/28/2008 6:13 AM
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#14
In reply to #8

Re: Calculation-Volume of Droplet

04/29/2008 3:37 PM

Dear Guest,

it was very interesting to read the paper. I tried to check if the simplified model with which I computed the drop volume could bring coherent results with experimental ones mentioned in the text.

I considered some data available via Google as for instance the Cw of a sphere function of the Reynolds number and the "internal pressure" generated by the superficial tension.

For the fall speed I assumed as a limit the value for which the drag force and the weight are equal. It was necessary to proceed by successive approximations since Cw is function of Reynolds, Reynolds is function of speed and speed function of Cw.

The pint = σ/R for a sphere is generated by superficial tension and pstop = V²*ρ/2 is the static pressure where the air flow meets the drop surface and where the flow speed is=0.

The results are quite converging to the experimental values:

for small d≤ 2mm one sees that pint >> pstop so that the drop surface form is dictated by the internal pressure and for minimal energy it has to be a sphere.

If the diameter increases the difference between pint and pstop decreases so that the radius at the contact zone between droplet and air flow cannot be any more the same as in the opposite region where outer pressure is a lot less.

For a diameter between 3 and 4 mm both pressures are equal which suggests that the contact surface should be plane and for higher "d" pstop>pint. This means that for an equilibrium the surface has to change the sign of curvature i.e. it should become concave!

But such a drop form will for many reasons have a tendency to part which could explain why only one drop was found in the 5 mm range.

The different stages are sketched in above picture.

There is a last point to clarify: the maximal speed. In the graph the drop has been considered as spherical and at d=5mm a fall speed of ≈ 10m/s was obtained. If we consider as a rough approximation that the deformed drop is a full hemisphere the falling speed will be 6.85 m/s since the corresponding Cw is a lot higher than the one for the sphere. But the drop has a more rounded form so that its Cw will be less and it is coherent with the model that the fall speed will be found between 10 and 6.85 m/s value mentioned in the text is 8m/s which is well in the interval given by above limits.

Thank you for the link it was really interesting to make this check and pleasant to obtain a good convergence.

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#9

Re: Calculation-Volume of Droplet

04/28/2008 6:16 AM

There are several factors that influence this, and I plan to do a bit of research to see if there's an "official" discussion available.

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