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The Feature Creep

Join Date: Feb 2005
Location: Boston, MA
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Waterproof Paper

07/24/2006 2:57 PM

In a moment of serendipity a new waterproof paper was created, completely on accident. Here is a video link. In Akron, OH a scientist has accidentally created a coating for paper that is waterproof, but still allows for things to be printed or written on it.
It also doesn't require a long drying time; it's UV curable in a few seconds. I can think of a tons of applications for something like this. Anyone have any guesses as to the "metal-oxide" she was using?

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Join Date: Jan 2006
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#1

Metal Oxides used in Waterproof paper?

07/25/2006 10:19 AM

Hmmm....if you watched the video there was some kind of diagram on a whiteboard. It had a circle or an "O" (Oxygen?) with several parallel lines indicating either bonds or that it was traveling towards a large capital letter "P" (Phosphorus?). An arrow from "P" pointed to a little "pac-man" character, with the result showing at the bottom as a long carbon-based organic molecule. Apparently, "Pac-Man" was gobbling up something to form the resulting organic molecule which coats the surface of the paper.

My interpretation of this is that "metal-oxide" is a mis-nomer, since Phosphorus is a non-metal, yet oxides of Phosphorus are used as drying agents due to their anhydrous qualities, and so, logically, could be used as a coating to keep paper dry. I believe the diagram somehow indicates that that the phosphoric oxide (Phosphorus Pentoxide, P2-O5) reacts with the cellulose fibers of the paper. In fact, experiments have been done to crosslink cellulose acetate (itself created by exposing cellulose to an alkali) with phosphorus pentoxide. See the URL link below.

I am not a chemist or chemical engineer so this is just supposition based on the diagram I saw in the video. Any other thoughts?

http://www.msu.edu/~narayan/crosslinkingofcellulos e.pdf

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