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Inline Refractometer Selections

06/04/2008 11:51 AM

I am in the process of designing a simple and cost effective system for mixing a solution of sodium hydroxide on the fly. One thing I want to do is monitor the concentration of the sodium hydroxide with reasonable accuracy and to have the ability to detect failures in the system before product is lost.

The dilution system will be diluting 50% sodium hydroxide down to 4% +/-.5% at a flow rate that will range between 10-70gpm depending on plant needs.

I have looked at mass flow meters for monitoring the SG but they run around $6,000 so I also looked at inline refractometers. While I have used handheld and benchtop refractometers I have no experience with inline models.

I have used multiple search engine's and have found several models so I do not need people to blindly posting links to refractometer manufactures. What I am looking for is input from people that have ACTUALLY USED inline refractometers and that can attest to ease of use, reliability and any short comings or strengths of a particular model.

For on the fly chemical dilution I am looking at using Dosatron proportional dosing pumps which operate off of feed water pressure. The goal is to be cost effective in the design....say less than $5,000 USD and to have it take up the smallest footprint possible. I literately have a 12inch X 24 inch area to work with but I do have a 23 foot ceiling so building tall is an option. The dilution system will be diluting 50% sodium hydroxide down to 4% +/-.5% at a flow rate that will range between 10-70gpm depending on plant needs. Any thoughts?

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#1

Re: Inline Refractometer Selections

06/04/2008 2:33 PM

Hi Richard,

Have you thought about conductivity measurement as a method for determining the concentration? I found this bit on the net:

Concentration

Temperature

Conductivity

(weight %)(°C)(°F)(µS/cm)(µS/in)
11864.446500118100
101864.4309000784900
201864.4328000833100
501864.482000208300

It looks like there's a good enough spread in the values between 1 and 10% to give you enough resolution to be within your stated specs. In-line conductivity is probably a lot cheaper than density, refractometry or sonic solutions.

I'll get into my CRC tonight when I go home and see if there's some expanded data. I'll let you know.

Mike

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#2
In reply to #1

Re: Inline Refractometer Selections

06/04/2008 6:00 PM

A 50 cell constance will cover that range, how flat is the curve between 1% and 10%?

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#3
In reply to #2

Re: Inline Refractometer Selections

06/05/2008 8:31 AM

Dang! Got into doing something else and didn't crack open the CRC last night. I'm pretty sure that info is in there & I'll let you know either tonight or tomorrow.

Question: Conductivity is also temp-dependent - do you have an idea of how stable the temperature of the mixed solution will be?

Mike

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#4
In reply to #3

Re: Inline Refractometer Selections

06/05/2008 11:40 AM

The feed water is from the city and is normaly in the 55-60 deg F range. So yes the temp will be stable.

I finaly got in touch with one of the Ch. E's at Honeywell (I have a lot of Honeywell in my plant) and she was kind enough to email me file filled with graphs showing uS vs conc for about 100 chemical. The sodium hydroxide slope looks fairly flat between 0% and 15%. From 15% to 20% the slope takes on a sharp curve then drops.

Most of my experience with conductivity cells has been in Ultra-Pure DI water sytems were a platinum sensor can last for decades with zero maintenance. What are some issues I may face with a 4% sodium hydroxide solution?

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