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The Engineer
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Solar Power - It's For Real Now

11/05/2008 12:22 PM

Came across this article today and was stunned by the implications. If this is correct, and there is no reason to believe that this isn't correct, then the energy game just changed, a lot. Introducing the Silicon Solar Cell that absorbs 96% of the sunlight that hits it, no matter the angle, thanks to a clever antireflection coating developed by Shawn-Yu Lin from RPI. Please don't make the mistake of confusing efficiency with absorption percentage, it's different, still, such a development is significant.

Bottom line, we are getting very close to a cost effective Solar Cell energy solution.

Here is the wikipedia link for Solar Cells (At the bottom this lattice breakthrough is mentioned).

Here is a link to the article (I've pasted the article below)

Solar Power Game-changer: 'Near Perfect' Absorption Of Sunlight, From All Angles

ScienceDaily (Nov. 4, 2008) — Researchers at Rensselaer Polytechnic Institute have discovered and demonstrated a new method for overcoming two major hurdles facing solar energy. By developing a new antireflective coating that boosts the amount of sunlight captured by solar panels and allows those panels to absorb the entire solar spectrum from nearly any angle, the research team has moved academia and industry closer to realizing high-efficiency, cost-effective solar power.

"To get maximum efficiency when converting solar power into electricity, you want a solar panel that can absorb nearly every single photon of light, regardless of the sun's position in the sky," said Shawn-Yu Lin, professor of physics at Rensselaer and a member of the university's Future Chips Constellation, who led the research project. "Our new antireflective coating makes this possible."

An untreated silicon solar cell only absorbs 67.4 percent of sunlight shone upon it — meaning that nearly one-third of that sunlight is reflected away and thus unharvestable. From an economic and efficiency perspective, this unharvested light is wasted potential and a major barrier hampering the proliferation and widespread adoption of solar power.

After a silicon surface was treated with Lin's new nanoengineered reflective coating, however, the material absorbed 96.21 percent of sunlight shone upon it — meaning that only 3.79 percent of the sunlight was reflected and unharvested. This huge gain in absorption was consistent across the entire spectrum of sunlight, from UV to visible light and infrared, and moves solar power a significant step forward toward economic viability.

Lin's new coating also successfully tackles the tricky challenge of angles.

Most surfaces and coatings are designed to absorb light — i.e., be antireflective — and transmit light — i.e., allow the light to pass through it — from a specific range of angles. Eyeglass lenses, for example, will absorb and transmit quite a bit of light from a light source directly in front of them, but those same lenses would absorb and transmit considerably less light if the light source were off to the side or on the wearer's periphery.

This same is true of conventional solar panels, which is why some industrial solar arrays are mechanized to slowly move throughout the day so their panels are perfectly aligned with the sun's position in the sky. Without this automated movement, the panels would not be optimally positioned and would therefore absorb less sunlight. The tradeoff for this increased efficiency, however, is the energy needed to power the automation system, the cost of upkeeping this system, and the possibility of errors or misalignment.

Lin's discovery could antiquate these automated solar arrays, as his antireflective coating absorbs sunlight evenly and equally from all angles. This means that a stationary solar panel treated with the coating would absorb 96.21 percent of sunlight no matter the position of the sun in the sky. So along with significantly better absorption of sunlight, Lin's discovery could also enable a new generation of stationary, more cost-efficient solar arrays.

"At the beginning of the project, we asked 'would it be possible to create a single antireflective structure that can work from all angles?' Then we attacked the problem from a fundamental perspective, tested and fine-tuned our theory, and created a working device," Lin said. Rensselaer physics graduate student Mei-Ling Kuo played a key role in the investigations.

Typical antireflective coatings are engineered to transmit light of one particular wavelength. Lin's new coating stacks seven of these layers, one on top of the other, in such a way that each layer enhances the antireflective properties of the layer below it. These additional layers also help to "bend" the flow of sunlight to an angle that augments the coating's antireflective properties. This means that each layer not only transmits sunlight, it also helps to capture any light that may have otherwise been reflected off of the layers below it.

The seven layers, each with a height of 50 nanometers to 100 nanometers, are made up of silicon dioxide and titanium dioxide nanorods positioned at an oblique angle — each layer looks and functions similar to a dense forest where sunlight is "captured" between the trees. The nanorods were attached to a silicon substrate via chemical vapor disposition, and Lin said the new coating can be affixed to nearly any photovoltaic materials for use in solar cells, including III-V multi-junction and cadmium telluride.

Along with Lin and Kuo, co-authors of the paper include E. Fred Schubert, Wellfleet Senior Constellation Professor of Future Chips at Rensselaer; Research Assistant Professor Jong Kyu Kim; physics graduate student David Poxson; and electrical engineering graduate student Frank Mont.

Funding for the project was provided by the U.S. Department of Energy's Office of Basic Energy Sciences, as well as the U.S. Air Force Office of Scientific Research.


Journal reference:

1. Kuo et al. Realization of a near-perfect antireflection coating for silicon solar energy utilization. Optics Letters, 2008; 33 (21): 2527 DOI: 10.1364/OL.33.002527

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#1

Re: Solar Power - It's For Real Now

11/05/2008 12:38 PM

Could be good...
I was browsing through Machine Mart cataloge the other day...some solar panels in there...still ludicrously expensive in terms of £/Watt.

Hopefully we'll see prices come down... (but I'm not holding my breath)

Del

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#2
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Re: Solar Power - It's For Real Now

11/05/2008 12:44 PM

Yeah, I agree they are still waaaay too expensive, but 10 years from now we might be seriously considering Solar Panels as the way to heat our homes. Man that would be awesome.

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#8
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Re: Solar Power - It's For Real Now

11/06/2008 8:02 AM

A few months ago I read an article,can't remember where, about a process of printing solar panels like a newspaper. Anyone recall this?

oilcan13

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#14
In reply to #1

Re: Solar Power - It's For Real Now

02/02/2010 11:50 PM

Solar panels are getting a lot cheaper though.

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#3

Re: Solar Power - It's For Real Now

11/05/2008 1:08 PM

I agree. A very promising development (unlike the previous similar attempts by others). Will have to keep a close eye on this one also, but it is a long way off being a commercial product yet.

Only time will tell. I will wait until they have a prototype built and tested under real-world conditions before I start to get really excited.

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#4

Re: Solar Power - It's For Real Now

11/05/2008 2:19 PM

Of course it is a breakthrough but the comment that orientation is not any more requested is false. For a given panel area and considering the sun light rays parallel the earth daily rotation leads to an cosine effect. At sun rise and sun set the panel will absorb 96% of incoming light which means less than at noon.

The fact that so much energy is harvested leads to the idea to combine electrical generation and heat harvest for instance for heating as Del uses it. Same panel with both outlets.

With respect to prices I met a couple of month ago a guy from a lab who told me that new approaches with less purified silicon and with a different structure could drastically reduce the cost.

The combined generation as mentioned above could make it even more interesting and increase the market which automatically reduces prices.

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#5

Re: Solar Power - It's For Real Now

11/05/2008 11:23 PM

Roger,

I suspect the practical benefit will be limited by the diminished effective area of the cell's surface as the incident angle of the sunlight deviates further from normal (i.e. vertical to the surface). At some point, the cost of automatically aiming the cell array will likely be less than the increased overall gain in energy. Consider that at 45°, the effective area is 0.707 (cos45°), and decreases rapidly thereafter.

However, for the vast number of arrays which are in fixed positions, such as permanent mounting on a roof, the ability to minimize reflective loss from larger off-normal angles is a real benefit. This will particularly be good for the large number of installations which are parallel to the slope of the roof.

--John M.

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#9
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Re: Solar Power - It's For Real Now

11/06/2008 9:24 AM

Jmueller,

Yeah, I think you're right regarding the effective area, but even if you make new solar arrays that move twice a day, that should save a lot of power and minimize the loss due to this angle effect.

Where there really needs to be improvement is in the efficiency of converting the light to electricity. Right now 30% (40% if there is a super nova near by) is just not cutting it. If we could get to 50% with this new antireflective coating, well then, we could be in business. This should be doable, but we need funding to research (we being the scientists and engineers of the world).

It's clear to me though that there will be a significant transistion to solar arrays for many energy applications in the next 40 years. Cool.

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#12
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Re: Solar Power - It's For Real Now

11/08/2008 2:52 PM

It's clear to me though that there will be a significant transistion to solar arrays for many energy applications in the next 40 years. Cool.

Yes, harvesting energy from the natural nuclear fusion engine in the sky will probably become mainstream long before we can rely on human-made fusion. But I'm more optimistic -- I would guess within 20 years, Thanks for the heads-up, very exciting breakthrough.

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#6

Re: Solar Power - It's For Real Now

11/06/2008 12:04 AM

Look for our monthly energy bills to skyrocket when the suppliers learn of this advancement in solar cell technology.

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#7
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Re: Solar Power - It's For Real Now

11/06/2008 3:43 AM

As long as we don't get bills from 'Big Sol' ....

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#10
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Re: Solar Power - It's For Real Now

11/06/2008 11:19 AM

Amen - they'll have to make up for the losses somehow...

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#11

Re: Solar Power - It's For Real Now

11/06/2008 11:33 AM

Since we are talking about silicon solar cells, we must recognize these are photovoltaic cells and the capacity to absorb sunlight does not necessarily mean an increase in the conversion of light to electricity. That is the real question, absorbing more light in photovoltaic cells that just get converted to heat probably would not prove all that useful. So I would be interested in how much this improves the energy conversion efficiency for generating electricity.

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#13

Re: Solar Power - It's For Real Now

11/09/2008 12:35 AM

Sounds like a great improvement it making electrical power from light. The array can be smaller for the same output.

There is a finite amount of power per square meter [or square yard, or any given area], because that is all that comes from the sun and you can't get more than the sun puts out. That is an absolute limit. Also it only works in the daytime and we also need electricity at night. That requires the use of batteries or some equivalent to store the power for when it will be needed. Present electrical storage is bulky and expensive.

What is needed is a better way to store electricity or even the most efficient solar generating scheme will have only limited usefulness. At present, solar generating can only supplement the traditional electrical power grid, not replace it.

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