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Commentator

Join Date: Oct 2008
Location: India
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Oxidization over flex wire - solution

12/06/2008 1:22 AM

Hi,

One of transformers found to be oxidized(light brownish color) in the tinned(SAC 305-Solder material) leads of flex wire..( Refer the attached fig.,)

We packed the components & kept closed & stored in room temp for around 6 months.

How this happens ??Is this subject to the environment conditions (We're shipping to customer in both sea & Air/Road mode) or any other means??

What are the methods(Packing/Any oxidisation resistant (solution) to wipe on the

tinned area ) to protect it from the oxidization formation??

Waiting for your valuable suggestion as earlier as possible..

Hari

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Commentator

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Location: India
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#1

Re: Oxidization over flex wire - solution

12/06/2008 3:26 AM

Sorry, one correction in the above information..

Material is not an soldered(SAC 305) coated material , it is an silver coated material.

Is the silver coating oxidize w.r.to change in the environmental factor? Confirm....

Hope to get your valuable feedback as sooner!!!

Hari

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Guru

Join Date: May 2006
Location: Placerville, CA (38° 45N, 120° 47'W)
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#2
In reply to #1

Re: Oxidization over flex wire - solution

12/06/2008 11:31 PM

Silver plated wire always appears to oxidize faster than copper. Most of the silver plated wire I've dealt with had Teflon insulation. Only the exposed wire and a very short distance inside the Teflon normally oxidizes, so don't pre-strip the insulation. Leave the stripping to the installer. If the bags are sealed in a humid climate, it may still be necessary to include a dessicant.

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#3
In reply to #1

Re: Oxidization over flex wire - solution

12/07/2008 11:07 AM

The discoloring(tarnishing) of silver plate is caused by a reaction between silver and airborne sulfur compounds. One easy way to prevent it is to put the silver in an airtight bag along with an anti-tarnish strip made by 3M (and others). I have been told that a piece of chalk will also do the same job. The tarnish is unsightly, but does not hurt the properties of the silver plating.

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#4
In reply to #3

Re: Oxidization over flex wire - solution

12/07/2008 12:21 PM

I have to disagree with your last phrase!

In my experience, it is extremely difficult to obtain reliable solder connections to tarnished silver plated wires without thorough cleaning before soldering. This was using ordinary 60/40 solder with rosin flux. I haven't tried it with any of the lead-free solders.

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#5
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Re: Oxidization over flex wire - solution

12/07/2008 1:12 PM

Everyone has different experiences. It depends on the degree of tarnish and the activity of the rosin flux. Non-activated rosin is called "water white" and has minimal tarnish removing qualities. Most rosin flux is activated. The degree of activation and the soldering temperature will determine how well it reduces silver tarnish. YMMV

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#6
In reply to #3

Re: Oxidization over flex wire - solution

12/08/2008 11:46 PM

HI welderman,

Thanks for your valuable input..

Two clarification:

1.what is anti tarnish strip?? Any website ref.

2.How the chalk will protect the silver coated area from tarnishing ? To my knowledge,I think as this absorb the sulphur compounds from air..

Hoping to get your answer....

Hari

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#7
In reply to #6

Re: Oxidization over flex wire - solution

12/09/2008 8:18 AM

Haricool, if you perform a Google search, you will find numerous sources for 3M Tarni-Shield strips. They are inexpensive and provide the corrosion protection you seek. I believe these strips (as well as chaulk) are getters for sulfur compounds in the air. They absorb and trap sulfur compounds much the same way that silica gel absorbs water molecules from the air, making the air dry.

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