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Anonymous Poster

Mercury Monitoring - Integrity Checks

02/12/2009 5:30 PM

I have been working on getting a Thermo 80 series mercury monitor to pass its integrity checks with no luck. The integrity check consist of running the mercury monitor with pure mercury(10ug/l) for the first portion of the test then running mercury and chlorine (10ug/l Hg and 300 l/m Chlorine) the second part. This is supposed to show that the monitor will be able to measure both elemental and oxidized mercury. The monitors are stack mounted on a coal fired boiler running a 350 Mw generator. We have two generating units with a third on the way. The mercury monitor on unit 2 passes its integrity check but the one on the unit 1 will not, they are the same model. The vendor has not been much help. We were supposed to have the channel qualified by the first of the year but need to pass a 3 level integrity check to get it qualified. This is a state requirement due to permiting for our third unit.

Does anyone have experience with Mercury CEMS and if you do have you been abe to get a passing integrity test? How?

Thanks in advance.

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#1

Re: Mercury monitoring integrity checks?

02/12/2009 6:52 PM

Will Thermo Fisher Scientific accept the monitors for re-calibration? (if so, do it; if not, why not?).

Does the documentation supplied with the monitors claim this performance? (if not, you're stuck; if so, they are).

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Anonymous Poster
#2
In reply to #1

Re: Mercury monitoring integrity checks?

02/12/2009 8:18 PM

Basically we are stuck. From what I understand it is an industry wide problem (where it is required), Thermo has been working with us. It is not as easy as taking it out and sending it in. It is part of the Continous Emissons Monitoring System(CEMS) so it is serial numbered and any replacement must go through RATA testing and certification to have valid data.

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Join Date: Feb 2009
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#3

Re: Mercury Monitoring - Integrity Checks

02/15/2009 9:00 AM

I HAVE THE SAME SYSTEM RUNNING ON TWO 750MW UNITS. We are in the process of adressing the same issue. It seems that leaks have been our main problem and will affect the Integrity the most. Also the probe filter being contaminated affects this. I have got some new write-up from TF If you are interested. I will keep you informed on what we find.

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#4

Re: Mercury Monitoring - Integrity Checks

02/16/2009 9:07 AM

I've got Mercury Freedom 80i's on three stacks. Similar in configuration to yours, 370MW T-Fired pulverized coal with Wyoming low sulphur Sub-C as primary fuel. We installed the systems last year and all three have passed relative accuracy test for contract completion. Our units all fell well below the "low emitter" thresholds.

By integrity checks, I assume you are speaking of the mercury chloride generator checks. I wish I had more information for you on that subject, but frankly our state adopted the EPA's rule by reference and when it went away, the state decided not to go forward with they're own rule. We decided not to mess with the chlorine gas and did not even hook up the system.

I attended a utility conference last year on pollution control equipment, of several hundred attendees, I didn't find one plant that had successful, accurate and repeatable results with Thermo's oxidized mercury "integrity checks." We're really hoping that our state will accept the EPA 30B Rata as proof of the system or that Thermo develops a better system before we have a new rule from the EPA.

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#5
In reply to #4

Re: Mercury Monitoring - Integrity Checks

02/21/2009 2:31 PM

Are you trying to run chlorine integrity checks? And yes thats what I was speaking of.

Regards,

Jeremy

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