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The whatsit point.

02/13/2009 11:38 PM

I can find many pages where properties of plastics are given including the melting points. What I want to know is at what temperature will polypropylene lose it's diminisional stability and what is this point called.

The reason is that I need to resize the ID pn the ends of extruded tubing a few thousandths. The manufacturing tolerance is plus or minus .020 on the bore. Suppliers tell me ten thousandths is the very best they can offer.

I have in mind heating it to the whatsit point and cooling it by slipping it over a highly polished and cooled mandrel. There will be lots of cut and try here.

Thanks in advance.

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#1

Re: The whatsit point.

02/14/2009 2:28 AM

You could try vicat softening point (ASTM D1525) or deflection temperature under load (ASTM D648)

http://www.matweb.com/reference/deflection-temperature.aspx

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#2

Re: The whatsit point.

02/14/2009 8:50 AM

Glass transition temperature.

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#3

Re: The whatsit point.

02/15/2009 12:11 AM

I have the exact issue with PVC pipe. Suggestion on temp would be great. I was also looking at boring out the ID as Wall thickness was not an issue. Any suggestion would be great.

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#4

Re: The whatsit point.

02/15/2009 2:15 AM

Pure organic substances have a "melting point" - an exact temperature at which they liquefy. This is used in chemical analysis. Polymers and plastics have a "softening Point" as the change is gradual. Some polymers have a memory - and although they can be distorted under temperature they try to return to their original shape when cooled some just stay put - as used in blow moulding. You need to establish if the plastic you are dealing with has a memory. If you need to shrink plastic tube onto another tube then some memory is useful. Heat the tube until it is soft enough then insert the other part in it. If you get a firm grip then it has shrink-wrapped itself on and you are in business - if it is loose then you are in trouble and will need a different plastic or a sealant.

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#7
In reply to #4

Re: The whatsit point.

02/15/2009 8:23 AM

Some clarity here.

We're talking about thermoplastics. Thermoplastics soften when heated and can be extruded or molded or vac-formed. The Tg of thermoplastics is not as easily defined as with a thermoset, both polymers.

All thermoplastics try to return to their relaxed state. All thermoplastics have memory.

If you vac-form a hemisphere using PVC, it will eventually return to the flat shape it had before it was heat formed. Heating it up will speed the process.

The same is true of extruded PVC pipe. You can heat and stretch it and get it in the ballpark, but depending on the environment, it will try to return to it's original configuration.

Cheers

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#9
In reply to #7

Re: The whatsit point.

02/16/2009 5:29 AM

Then how come plastic bottles keep their shape when cooled?

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#10
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Re: The whatsit point.

02/16/2009 9:22 AM

Because "normal" temperatures are not hot enough to cause the plastic to revert to it's pre-molded form.

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#11
In reply to #10

Re: The whatsit point.

02/16/2009 9:43 AM

NOW I AM COMPLETLY CONFUSED!!!

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#12
In reply to #11

Re: The whatsit point.

02/16/2009 10:18 AM

No need to shout.

Polymers can be divided into two groups, generally. Thermosets are the two part kind that you mix together. They harden by virtue of a chemical reaction between the two chemicals mixed. Heat speeds the curing process. Some of these compounds even make their own heat. Exothermic reaction. Some require heat. Endothermic, they're called. Thermosets don't melt if heated. They get softer, and once beyond their Tg will expand rapidly and loose strength. Once cured, they cannot be reused, as can thermoplastics.

Thermoplastics are solids that get soft when heated and can be molded. When heated again they can be remolded. Since no chemical crosslinking takes place(as with thermosets) their molecules are free to "slide" over each other, under pressure and heat and can be formed into useful objects, such as pop bottles. Heat the pop bottle enough and it will revert back to a flat mass.

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#13
In reply to #12

Re: The whatsit point.

02/17/2009 8:11 AM

Heat the bottle as much as you like you will get a mess - some plastics have a memory at certain temperatures - problem with acrylics in the paint world.

Back to the original - some substances do not have a melting point no abrupt change eg ice/water - they just get softer when you heat them they generally get more liquid as you heat them until they decompose.

Thermoplastics (as defined!) do not change viscosity with heat - no softening or melting point - they will just decompose. Off subject!

Sorry I don't shout - I am just a rotten typist !

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#14
In reply to #13

Re: The whatsit point.

02/17/2009 8:59 AM

Check out the thread in Software ad Programming : changing CAPS to lower case.

There are many ways to change from caps to lower case.

LL

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#15
In reply to #14

Re: The whatsit point.

02/17/2009 9:12 AM

Too b------ idle to retype. Easy in word (Shift F3) Doesn't work otherwise -

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#5

Re: The whatsit point.

02/15/2009 5:48 AM

Skelley,

Yup! That'll do it.

Keep it simple.

How many do you need to do? Do you need to automate it?

"droop" springs to mind.

Cheers,

Stu.

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#6
In reply to #5

Re: The whatsit point.

02/15/2009 6:28 AM

Hello Stueywright:

You say 'droop'?...........I have that problem all the time!

Take care.................

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#8

Re: The whatsit point.

02/16/2009 2:48 AM

I think the point should be "Vicat Softening Point "or "Glass Temperature"(Tg)

But the Vicat Softening Points are different from material grades,so you should tell us what grade of polypropylene(e.g. PE-10GF Polyone ) is going to be used.

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#16

Re: The whatsit point.

02/17/2009 9:49 AM

There are generally two types of thermoplastics (plastics that can be heated, melted, and molded into new shapes): crystaline and amorphous. The crystaline plastics (nylon, polypropylene, etc.) form a semi-crystal microstructure when they cool. Amorphous (polycarbonate, polystyrene, etc.) form a non-crystaline, generally random, microstructure as they cool. Crystaline plastics are generally more opaque, and amorphous are more clear. (Glass, by the way, is amorphous. It does not form a crystaline microstructure, even though some glass is designated as "crystal.") Generally speaking, amorphous plastics have a wide softening range where they begin to lose their rigidity and strength and gradually change to a liquid state. Crystaline plastics, polypropylene included, have a sharper, more defined melting point. Because they are technically "semi-crystaline", there is a softening range rather than a sharp melting point like ice, which has a very definite crystaline structure, but the range is much narrower than amorphous plastics. Each brand of polypropylene may have its own narrow softening range, and that range may vary slightly from one lot to another. It will take some experimenting to find the high and low temperatures for the plastic you are using, and then it might change slightly for the next batch of tubes. You will need good control of your heating equipment to be able to stretch the tubing without melting it. The plastic may revert back to its original size somewhat, but probably not completely. The best way to find out how much it will change is to stretch it, measure it, leave it sit overnight or longer and measure it again, then subject it to the service temperature it will see and measure it again. That should give you a pretty good idea on how much oversize you will need to make it to hit your specs.

Dennis

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#18
In reply to #16

Re: The whatsit point.

02/17/2009 11:32 PM

Nice job! I thought I even saw "the whatsit point" referred to in there.

LL

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#17

Re: The whatsit point.

02/17/2009 10:35 AM

Sorry for showing up late.

I have a small book that gives reference data on PP blown film extrusion.

Three temps are given;

  1. Crystallization, 110 °C
  2. Melt, 200 °C
  3. Frozen Line, 90 °C

I would start around the 160° mark by Corraussians link in post 1.

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