I just tried for the first time ever, obtaining free samples from about 10+ semiconductor manufacturers. Texas Instruments has by far in my limited one day experience, come out on top. I bagged about 5 items at 25 items a lot. Their support is perceived to be miles ahead (as is their software) from other manufacturers I viewed today.
I had to look very hard for free samples on other sites and was lucky to get one or two items only...if I could find where they have hidden them...even was going to be slugged $15US from one other popular manufacturer for postage on a free sample single IC chip 
....if I get results in the mail from Texas Instruments, I will have been won over by this company, willing to invest in a little loss for a probable monetary gain in the future.
What are your experiences...mine is only a day old