Mythbusters did a program on this. Google "Mythbusters mentos and coke episode" It's a combination of nucleation on the rough surface of the Mentos and the aspartame, preservative and caffine in the Diet Coke reacting with the gum arabic and gelatin in the Mentos, according to their website.
They managed a 30 ft fountain, by the way. Impressive.
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"Just a little off the top" - Marie Antoinette
I haven't a clue but while answering this might one of you refresh my memory on the issue of a shower of sparks when chewing certain flavors of Lifesaver candy?
L.J.
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"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer
An internet search tells me Triboluminescence is the culprit of the phenomenon. From Wiki:
"...when sugar crystals are crushed, tiny electrical fields are created, separating positive and negative charges that then create sparks while trying to reunite. Wint-O-Green Life Savers work especially well for creating such sparks, because wintergreen oil (methyl salicylate) is fluorescent and converts ultraviolet light into blue light."
Or, as they say on Mythbusters "CAUTION: Science Content."
I don't know if this was planned by the manufacturer, or just a luck happenstance.
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"Both the revolutionary and the creative individual are perpetual juveniles. The revolutionary does not grow up because he cannot grow, while the creative individual cannot grow up because he keeps growing." Eric Hoffer