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Conversion from mg/m3 to mg/kWh

03/28/2007 9:06 AM

I made an inspection to gas operated (using CH4) hot water boiler and made a measurement of combustion products with analyzer. measurements include CO SO2 NOx ... in unit ppm. But in regulations limits are mentioned in units mg/m3 and mg/kWh. I know the calculation of conversion factor from ppm to mg/m3 but i could not find a way to calculate coversion factor from ppm to mg/kWh for burning gases CH4 C3H6 C4H10 for CO SO2 NOx.

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#1

Re: conversion from mg/m3 to mg/kWh

03/28/2007 9:23 AM

http://www.longman.co.uk/gcsechemistry/worksheets/pdfs/worksheet8.pdf explains all.

CH4 = 16g/mol

C2H6 = 30g/mol

C3H8 = 44g/mol

C4H10 = 58g/mol

Then use the conversion 1kWh = 3.6 x 106 Joules.

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#2
In reply to #1

Re: conversion from mg/m3 to mg/kWh

03/28/2007 10:44 AM

First off all thank you,

But as you know these are correct for complete combustion.

for example i measured 20 ppm CO = 20 x 1.25 mg/m3 = ? mg/kWh

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Guru
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#3
In reply to #2

Re: conversion from mg/m3 to mg/kWh

03/28/2007 10:48 AM

One could do an engineering approximation by proportioning the CO2 to unburnt materials to give an estimate of the energy needed to produce the flue gases present.

Try it, and see what happens?

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#6
In reply to #2

Re: conversion from mg/m3 to mg/kWh

04/13/2007 7:36 AM

Could you elaborate on this for a novice to the topic - the equation you give suggests knowing the relation of m3 gas output in relation to boiler KWh rating. Is there a distinction between combusted and non -combusted products output etc . The situation is clearly more complicated than I can appreciate at present , but it may be worth the time to explain it in more detail (ie does it amount to knowing volumetric gas output etc ). Some questions can find answers if explained in terms that the uninitiated are familiar with - it may be familiar or straightforward to yourself , but the more people that can comprehend the problem the better chance there is of a useful reply. I'm sure the description makes perfect sense to somebody in the trade , but if an answer is not forethcoming , I think you need to broaden the terms.

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#7
In reply to #2

Re: conversion from mg/m3 to mg/kWh

03/19/2008 11:35 AM

do u solve your problem

because I have same problem :(

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#4

Re: Conversion from mg/m3 to mg/kWh

03/29/2007 4:09 AM

I would suggest that your easiest approach would be to use the rated value of the burner for your Kw figure. In my part of the world our regulations simply work on PPM. Assuming your burner is working at a reasonable level of excess air it all comes down to the same thing. PPM is simply a percentage of flue gas. The flue gas volume is directly related to the output of the burner.

20PPM is a quite respectable CO figure so unless you have to present actual figures in mg/kwh I would not be too concerned. If that's high fire I would say your burner is running well.

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#5
In reply to #4

Re: Conversion from mg/m3 to mg/kWh

03/29/2007 7:06 AM

My measurements ;

excess air = 1.2 CO2 = 10 % vol CO = 21 ppm SO2 = 2 ppm O2 = 4.2 % vol

Burner Heat İnput Qn = 1450 kW Test Gas = CH4

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#8

Re: Conversion from mg/m3 to mg/kWh

10/20/2008 5:51 AM

1 ppm No2 = 2.05 mg/m3

8.9ppm No2 = 18.245 mg/m3

Natural Gas E = 9.45 kWh/m3

A gas boiler uses 11.4 m3/hr of gas (from boiler manufacturer)

(18.245 mg/m3 x 11.4 m3/hr) / 9.45 kWh/m3 = 22 mg/kWh

Susan

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