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Electric Batteries for Cars

08/18/2011 8:16 AM

EVs BATTERIES

During the last 30 years I have been preoccupied with the EV thechnology.

From the very begining I saw the following facts.

1º- We should never expect the miraculous invention of a lightweight powerfull battery. The primary electrochemical reaction at one metallic electrode is acepting or yielding one or several electrons, depending on its valence. This reaction has one definite voltage given by Thermodynamics, usually between 1 and 2 Volts,

So the maximum we can get from a battery, no matter the ingenuity of design, is one to four elecrons per atom of electrode.

So the maximum energy per atom would be the charge of the electrons times the volts of the reaction (In electron-volts).

So it is easy to calculate the maximum energy we can get from, say a Kilogram of Lithium, and it is not too much. In fact much less than from a kilogram of Gasoline.

In the battery we must add the weight of the the other electrode, the electrolite and the container.

Accepting these hard facts. How could we make the Evs really feasible?

2º The solution is simple: Make a battery that could be recharged in the same time it takes to fill a tank of gasoline. Forget about the mileage, it is NOT so important

3º- But, accepting that we'll probably never get the same mileage than gasoline cars, then we need to install more Refueling Stations, to avoid the terrible anxiety of the EV driver to get stranded.

4º- But How can we have such rapid charging batteries?. Very easy: Just make the active electrode and the electrolite both liquid, and also the resulting chemicals after reaction. So the battery would NOT be charged but reloaded with fresh electrode and electrolite, removing the spent chemicals through a parallel hose.

5º-The spent chemicals would be returned (At low cost) to the Factory for recharging by the same "Electric fuel" distribution trucks.

6º- These factories would be located close to Alternate Energy sources, thus eliminating their major drawback: The production discontinuity.

7º- As the battery structure does not undergo any cemical reaction, there is no reason why this battery cannot be made to last as long as the car itself

AT this moment you have probaly judged that everyting fits well.

So it is important to emphasize the R&D on liquid or slurry electrode batteries.

See ZINC - AIR Bateries

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#1

Re: Electric batteries for cars

08/18/2011 8:35 AM

Wot?

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#2

Re: Electric batteries for cars

08/18/2011 8:36 AM

OK.

Why not make parts of the road system "Scalextric", with a pick-up system that charges the vehicle while it is moving? The driver merely aligns the vehicle with the slot in the road, drops a steering/pickup skate into the slot, and picks up enough wallop for another N miles/km while travelling. Instant solution to range anxiety!

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#3
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Re: Electric batteries for cars

08/18/2011 8:49 AM

Scalextric?
That's easy for you to say
Del

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#6
In reply to #3

Re: Electric batteries for cars

08/18/2011 9:22 AM

About 25 years ago, I built an electric motorcycle with coils inside the tires that collected the electric power through an electromagnetc field produced by induction kitchen coils embedded in the road surface. The system worked so well that it was shown in National TV with great succes.

But I discontinued all work in this project because I saw clearly that, no matter how good R&D we may have made, the installation cost was going to be astronomical.

Even the operational cost would have been too high. Keeping an enormous amount of inducton coils "on" all the time.

Even if we could have invented a system to switch "on" only the coils directly beneath the car the system would have been too comlex and costly

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#8
In reply to #2

Re: Electric batteries for cars

08/18/2011 12:04 PM

I seem to recall a system that Buick (under GM) was doing this for their smart highway system or something like that. They had several cars running along a test strip following inches from each other and being powered by a system like the maglev.

A maglev system has no moving parts as far as energy transfer goes. It would be hellaciously expensive to do this on a scale as large as the US interstate system though.

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#15
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Re: Electric batteries for cars

08/18/2011 1:11 PM

No, any and all transportation systems must have at least one moving part for obvious reasons.

I believe the smart highway test bed did not power the vehicles but permitted intelligence to be transmitted between vehicles so that an auto-pilot drafting scenario could happen where the lead vehicle could control all in the train of self powered cars. This is completely different from what Gordon Danby and James Powell pioneered.

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#50
In reply to #15

Re: Electric batteries for cars

08/19/2011 12:28 PM

Okay...I didn't google around about it...just went from memory.

We had a maglev train for a short time around the ODU campus in Norfolk...money ran short and it ended up a big debacle. Norfolk just commissioned a light rail system this week...but alas it was not maglev.

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#28
In reply to #2

Re: Electric batteries for cars

08/19/2011 5:26 AM

The usual slot-car system would be a bit problematic at useful power ratings. I'd put the power rails on the back side of the side crash rail. To engage, you'd just steer over, and a roller would keep you off the rail, while flipping your pickup arm underneath to grab the rail and hook up. Fortunately, carbon brushes are compact and efficient at higher voltages, which would be safe from casual human contact there. Once hooked up, you'd have a bit of compliance from the trolley arm, and could enjoy automatic steering, spacing, and braking. Thus the space taken up between lane pairs with rails would be quickly repaid with denser traffic seeking better economy.

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#30
In reply to #2

Re: Electric batteries for cars

08/19/2011 7:12 AM

Good system but why bother with the battery?

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#31
In reply to #30

Re: Electric batteries for cars

08/19/2011 7:46 AM

I also like the idea of easy to change batteries, one or two charging one in use. Not necessary to have complex equipment to change them if they and the vehicle are designed with some ergonomics around battery swaps.

So a good design might include some of this:

  • allow Joe Average to charge the batteries at home (as easy as filling a vehicle with fuel)
  • supply a solar/wind/whatever charger (these might also be available at remote locations such as parking lots, fuel stations)
  • The batteries will be standard shape/power etc. and compatible across all EVs (not like laptops and cellphones where every make and model is different - it's FUEL it should be compatible across all EV vehicles!)
  • Be designed such that Joe Average can easily remove and replace the batteries (again as easy as filling a vehicle with fuel)
  • Upgrades/future improvements to the batteries should be backwards compatible (again it's FUEL it should not require a major change to the vehicle to use the newer improved FUEL!)
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#32
In reply to #31

Re: Electric batteries for cars

08/19/2011 8:43 AM

What about the 80 year old grandma that can't pick up the battery? Do we go back to the "good ol' days" and have gas station attendants?

Just thought I'd pose the question.

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#35
In reply to #32

Re: Electric batteries for cars

08/19/2011 9:29 AM

Your are assuming the battery is a one-piece heavy unit. No reason they could not be designed to be multiple units that weigh less. Just load up as many as you need for the trip.

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#36
In reply to #35

Re: Electric batteries for cars

08/19/2011 9:48 AM

"I also like the idea of easy to change batteries, one or two charging one in use. Not necessary to have complex equipment to change them if they and the vehicle are designed with some ergonomics around battery swaps."

Many people have restrictions on what they can lift say 2-3 lbs (prescribed by their Dr.) How many would you need to change out to get a days driving in?

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#40
In reply to #36

Re: Electric batteries for cars

08/19/2011 10:24 AM

OK so it's one or two "sets" of batteries. I'm just suggesting some ides that could help if it were designed to be "easy as filling up with gas". Before any of this could come to be there would need to be improvements in technology, which is what this string kind of started out to discuss.

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#41
In reply to #36

Re: Electric batteries for cars

08/19/2011 10:42 AM

How do you think Stephen Hawking changes the battery to his wheel chair?

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#44
In reply to #41

Re: Electric batteries for cars

08/19/2011 11:51 AM

That's just wrong but had to laugh anyway. Thanks I needed that one.

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#47
In reply to #41

Re: Electric batteries for cars

08/19/2011 12:21 PM

Obviously its done by voice command!

He is one of my vary favorite people.

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#4

Re: Electric batteries for cars

08/18/2011 9:12 AM

Once again you've shown a grossly inaccurate use of technical terms, but have stumbled onto a new concept being researched today. There is a team at MIT that is working on a liquid battery that can be refueled.

I agree that rapid refueling will be the answer to the electric vehicle. What I do not understand is why all EV batteries are so difficult to remove? With the possible exception of a liquid battery, I expect that the EV of the future (if there is one) will have a standard battery pack that can be either recharged in-situ at home or swapped out at recharge stations with fully charged batteries. One could even own two battery packs, one re-charging at home while the other operates the vehicle.

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#5
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Re: Electric batteries for cars

08/18/2011 9:15 AM
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#37
In reply to #5

Re: Electric batteries for cars

08/19/2011 10:11 AM

why can not this is developed again from details available ? Surely there are fearless people to do this ? In early 20th century there was another claim and final result was tragic.

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#42
In reply to #37

Re: Electric batteries for cars

08/19/2011 10:54 AM

Because it doesn't work! If it did work, it would be on millions of vehicles. It doesn't work.

I'll be happy to hook you up with an HHO advocate, if you like. Just PM me. And, just because I know an HHO freak, does not mean I think the technology is viable.

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#39
In reply to #5

Re: Electric batteries for cars

08/19/2011 10:24 AM

I agree whole-heartedly with that link. I am preparing my whole family for what is to come. Here is a picture of my long lost cat. He just wouldn't keep his hat on and now he's gone.

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#16
In reply to #4

Re: Electric batteries for cars

08/18/2011 1:11 PM

WOW! So finally somebody (MIT) is working in just the same direction that I propose!.

They are using slurries of metal particles. Aluminium has an enormous potential, it is extremely cheap, and extremely nontoxic or dangerous. Plus its extreme light weight.

I hope they are using it solving all the problems previously found..

The battery swap system is not as good as this.

Think of the poor litle "Electric Gas Station" in your neighborhood that needs to have a complex swapping machine, plus a certain amount of batteries for peak hours, instead of a simple pump and a storage tank.

Most, even small, refueling station have several pumps in a row. Imagine the cost of several Swapping Machines, plus the space they would need around.

No match.

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#21
In reply to #16

Re: Electric batteries for cars

08/18/2011 3:20 PM

"... instead of a simple pump and a storage tank."

No, two pumps and two storage tanks (keeping it simple).

The electrolyte must be drained/pumped out of the vehicle and stored.

Or, will unscrupulous dealers mix de-energized 'juice' with the good 'juice'? How would you know?

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#22
In reply to #21

Re: Electric batteries for cars

08/18/2011 3:38 PM

Well actually if you look at the MIT diagram I would expect at least four storage tanks (new anode, old anode, new cathode, old cathode) and a minimum of two pumps. All of the plumbing would have to be non-reactive.

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#24
In reply to #22

Re: Electric batteries for cars

08/18/2011 5:02 PM

I think electric cars are a great idea... but today there are simply too many operational restrictions to them... Not enough range; too slow to recharge; won't work well in cold weather, and won't go at all in the snow; underpowered; initial expense... blah, blah, blah, we have had these discussions at CR4 before.

When electric battery (or maybe some version of Mr Fusion) powered fire apparatus (a fire truck) is the norm, I will know that the electric vehicle has evolved into full bloom. These small steps of discovery will get us there... maybe... eventually.

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#52
In reply to #24

Re: Electric batteries for cars

08/19/2011 12:33 PM

I thought that torque was strong in an electric vehicle. Wouldn't that be what you would need in the snow? The cold weather problem has been partially solved by Leaf and Volt engineers.

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#7

Re: Electric Batteries for Cars

08/18/2011 10:45 AM

Why not just invent something that sucks electrons out of the air and shoots them into your battery.

Picture a bunch of fly swatters stuck all over the body of the car (and underneath, too) that magically extract all that wasted power just waiting to be used.

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#9
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Re: Electric Batteries for Cars

08/18/2011 12:18 PM

I thought that was the 'Ionacceleratorencabulator' (automotive version) someone was talking about?

But what happens to all the leftover protons anyway? Do they have to be gathered and stored, creating huge proton mountains (or lakes) that the EU has to subsidize, eventually selling off cheap to third-world nations or using taxpayers money to dispose of them in oceans or outer-space?

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#10
In reply to #9

Re: Electric Batteries for Cars

08/18/2011 12:36 PM

Silly boy. You've heard of carbon sequestration, right?

Well LynDoor™ Industries has just patented a proton sequestration system that will revolutionize the generation of power. These sequestered protons will strip an electron off of carbon atoms, or dirt, and will rise to the surface to be recycled by the next passing vehicle equipped with LynDoor™ Swattergetter technology.

At night when you get home, just plug it into your household wiring and power the house all night.

LynDoor™ Industries, your window to the future.

OK, this is at least as believable as some of the stuff our friend has proposed.

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#11
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Re: Electric Batteries for Cars

08/18/2011 12:44 PM

stop....I am running out of off-topic clicks!

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#12
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Re: Electric Batteries for Cars

08/18/2011 12:52 PM

Tell me again, what is the topic?

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#14
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Re: Electric Batteries for Cars

08/18/2011 12:56 PM

I've almost forgotten myself.

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#18
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Re: Electric Batteries for Cars

08/18/2011 1:19 PM

Thanks, I feel greatly reassured, and will sleep well tonight.

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#25
In reply to #7

Re: Electric Batteries for Cars

08/18/2011 9:52 PM

You never forget lyn.

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#13

Re: Electric Batteries for Cars

08/18/2011 12:55 PM

I think it would be easier (if you went pure electric) to make the battery packs easily interchanged, i.e., a service station that would swap out discharged battery packs for fresh ones for a fee. Inventory management would be hugely necessary along with a billing cycle for users. I would think these would be primarily along the interstates.

We already do this with city cars on some scale.

Here is the problem we have with this in the US though: We have immense distances to travel to move people and goods. One of the reasons we have cheap fuel in this country is that we simply could not afford to pay transportation costs to run a truck from a distributor to a delivery point 2,000 miles away. Spain is approx 195,000 square miles in size. This is miniscule compared to the US' 3,794,000+ square miles. Where you have commuters in the US covering 50+ miles to work and the same home, some countries' populations would never hear of such a thing. EV technology for the US needs to go a long way before making it more popular.

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#17

Re: Electric Batteries for Cars

08/18/2011 1:16 PM

I cant quite figure out where your numbers are coming form but from what I understand of battery technology over the last 30 years the battery's based on the lithium variants are pushing at least 10x the storage power per volume as what the common lead acid battery's did 30 years ago.

Thirty years ago the first real production EV's like the Ford Electrica, I owned, where even then able to run 20 - 30 miles on a single charge at typical 55 MPH highway speeds and even further in low speed stop and go situations on nothing more than 16 deep cycle golf cart batterys.

What seems odd to me is that some 30 years later and a 10x plus gain in battery energy storage density only gave us a 2 - 3x increase in rage on average despite the supposed efficiency gains on the drive trains and the additions of such energy savers as regen braking ability and light wheight composit body structures.

So how do these supposedly super efficient drive trains and 10x more capacity battery's only gain a marginal increase over what is basically nothing more than electric forklift drive tech from 30+ years ago?

If I had taken my old original design 1984 Ford Electrica and doubled its motor and controller capacity and then had changed to a lithium based battery system it could have easily ran at 65 MPH average speeds for well over 100 miles between charges or possibly close to 300+ in stop and go traffic which would make it practical and competitive with the vast majority of daily inner city and suburban driving situations.

So where did the EV tech spiral out of control at to end up giving us what is available today which are little more than fashion statements and expensive golf carts for rich tree huggers to stroke their ego's with?

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#19

Re: Electric Batteries for Cars

08/18/2011 1:41 PM

OFF TOPIC:

Let me express my anger with the fact that, being a poor man, I cannot have access to the article from MIT. I find this extremely injust (unjust). Science is for the advance of the whole Mankind. If an article HAS BEEN PUBLISHED, I do not see the reason why it cannot be made accesible to everybody, including poor people, that may have something to add. Please do not use the argument that poets need to put a price to their books. Scienists get paid otherways.

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#20
In reply to #19

Re: Electric Batteries for Cars

08/18/2011 1:50 PM

Well...I suppose you could go to the library and request that they purchase a subscription. Published simply means it was released to the world. Getting it to a consumer requires money (and so does research).

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#23
In reply to #19

Re: Electric Batteries for Cars

08/18/2011 3:40 PM

Why do people who believe that knowledge is power, also believe that knowledge should be free.

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#26
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Re: Electric Batteries for Cars

08/19/2011 12:08 AM

"The development of the technology was partly funded by grants from the U.S. Department of Defense's Defense Advanced Research Projects Agency and Advanced Research Projects Agency - Energy (ARPA-E)."

Maybe because we paid for it, at least partially???

And the newly developed technology is being licensed to a private company set up by the researchers!! Where is the return (to us) on our research investment?

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#34
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Re: Electric Batteries for Cars

08/19/2011 9:12 AM

Public research funding does not guarantee free public access. If it did then there would be no public funding of any research.

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#43
In reply to #34

Re: Electric Batteries for Cars

08/19/2011 11:15 AM

That would work for me. When I was at NASA all our research was available for no monetary compensation to private industry. But they did not have exclusive rights.

If it's developed from tax money, it should not have exclusivity, unless it's sensitive to national security.

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#45
In reply to #43

Re: Electric Batteries for Cars

08/19/2011 11:54 AM

Some research groups (NASA, many DOE facilities) do have as their charters that all work must be available to the public, but not all research groups have this policy. MIT is a private school. While there are researchers that want their knowledge to be given to the world for free, there are also many researchers and librarians that have bills to pay.

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#48
In reply to #45

Re: Electric Batteries for Cars

08/19/2011 12:24 PM

I'm well aware of all that, but that doesn't mean I think it's the right policy.

Just like when MIT tried to ban military recruiters from campus on career days. Because they take gov't funds, they can't do that anymore. There's private, and then there's "private".

It's my nickle. I should have the right to see it. Again, barring national security interests.

Hooker <--- now repeating myself

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#27
In reply to #19

Re: Electric Batteries for Cars

08/19/2011 5:09 AM

That is odd. MIT has also made it free to audit any of their courses on-line at one time. Perhaps a student can help out. The Sustainable Tech field will always have skilled workers who choose to stay low-budget in all things.

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#29

Re: Electric Batteries for Cars

08/19/2011 6:40 AM

Dear Redfred. By your comments it seems that you got access to the MIT paper.

Would it be possible to get a copy from you?.

Thanks.

chorete

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#33
In reply to #29

Re: Electric Batteries for Cars

08/19/2011 9:00 AM

While my work does grant me access to the MIT paper, I have not read any of the scholastic paper. All that I did read came from a search on the name MIT gave their fluids. I got the name from another search using the words "liquid battery". I will not give you a copy of the original paper because this can quickly get me fired with the latest tracking software available at work. Giving away another person's work is highly frowned upon at work.

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#46
In reply to #33

Re: Electric Batteries for Cars

08/19/2011 12:01 PM

If it's a "published" paper available in the public domain, wouldn't it be the same as giving someone your old newspaper? Is it illegal if I paid for the access and then passed it on to someone when I was done with it? Is this akin to piracy?

I don't see it as giving away someone's work...more like sharing a book.

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#49
In reply to #46

Re: Electric Batteries for Cars

08/19/2011 12:26 PM

It's intellectual property. Not the same as a newspaper.

More like a computer program... what happens if you share those?

[edit] The MIT link doesn't have a price for the paper; you have to place an order (I guess) to find out how much. I have ordered a few of this type of thing in the past, they were something like $35.00. Saved me WEEKS of investigation. How many months/years of someone's work can Chorete (in this circumstance) gain for $35.00?

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#51
In reply to #49

Re: Electric Batteries for Cars

08/19/2011 12:31 PM

Some researchers, thankfully, also publish their intellectual property to the net after it appears in "print" somewhere.

I would assume, however, that the authors would rather have their information out there for everyone to use. That is the entire purpose for the research being released to begin with. The institutions they work for are the ones who make it a pay-to-play issue.

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#38

Re: Electric Batteries for Cars

08/19/2011 10:18 AM

Liquid recharge is the best solution.

Another option is smaller cars with Compressed Air drive. Tata's in India are launching this car soon. Compressed air can also be charged in a short time/ equal to Gas filling time.

2nd car in every home for just office/train station/bus station/shopping be on non gasoline fuel. That can bring in huge benefits and you do not need host of charging stations. It can be a small car.

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#53
In reply to #38

Re: Electric Batteries for Cars

08/20/2011 12:29 PM

Guest 1949.

Now that yo mention it, Air Cars are interesting but have a serious drawback that usually nobody mentions.

When you compress air in a typical compressor, the compression, due to the short duration of the piston stroke, is practically adiabatic. The air comes out at a high pressure and also at a high temperature. Usually you have a radiator to dissipate this heat. An this is a loss of energy. The energy in the tank is much less than the energy spent in compression.

The good news is that, if you use an expasive air engine, the air cools down to very cold temperatures. If you use an heat exchanger to add heat from the environment, then you get back all your energy. But it is difficult to invent a good heat exchanger for this purpose. I have tried, and failed.

chorete

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#54

Re: Electric Batteries for Cars

08/20/2011 3:12 PM

Congratulations, you just reinvented the flow battery.

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#55

Re: Electric Batteries for Cars

08/20/2011 5:44 PM

I envision another system

steam powered

the boiler is fired with stacks of $100 bills

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#56

Re: Electric Batteries for Cars

08/22/2011 7:41 AM

You might be interested in this:

http://www.physorg.com/news/2011-08-energy-storage-device-recharge-electric.html

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#57
In reply to #56

Re: Electric Batteries for Cars

08/22/2011 1:16 PM

The article on graphene batteries is very confusing. It is suspicious that they refer to the battery capacity in kW/Kg (Wrong unit).

It appears that the battery does not have more capacity but it is able to take a full charge very fast due to the enormous surface of the graphene.

May be,it is possible to have a capacitor that stores energy by capacitance and also by an electron exchange reaction at the electrodes.

So I was wrong when I said that the maximum energy you can store in a battery depends only in electronegativity of the electrodes used. Independent of the type of design. NO if you use the same electrodes as a capacitor too.

I do ot know if this is possible, but it looks like this is not what the graphene battery is intended to do.

chorete

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#58
In reply to #57

Re: Electric Batteries for Cars

08/22/2011 1:41 PM

The article states ..."except that it's not a battery".

It also states "...power density of 100 kW/kgcell". This is the power delivery as if it were a power generating apparatus, such as a generator, which it is.

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#59
In reply to #58

Re: Electric Batteries for Cars

08/22/2011 2:49 PM

Actually this is more like a super duper capacitor* and not a generator. Maybe one could relate this to a gyroscopic flywheel and generator/motor combination of inertial energy storage that won't have the complication of rotational inertia to the handling of a vehicle.

*Since there are already super capacitors and this new technology will likely exceed a super capacitor (if successful) I had to use this silly term.

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#60
In reply to #59

Re: Electric Batteries for Cars

08/22/2011 3:34 PM

You could say "The one meeelion dollar capacitor"

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