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Desiccant - Dynamic Adsorption Capacity

09/21/2011 11:11 AM

Dear Members,

This question is with reference to Desiccant properties to be considered during designing of instrument air dryer (heatless type/no loss purge type etc.) used in refinery/other plants, involing adsorption/regeneration cycles.Following are the questions:

1- We define a term 'dynamic adsorption capacity' (DAC) ,to calculate the weight of required desiccant quantity. What is the basis of selection of DAC? Say 7.5 % for (Activated alumina/molecular sieve) for No purge loss type dryer units.

2-Please advice DAC values to be used for various desiccants commonly used in air dryer units.

Thank You

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#1

Re: Desiccant- Dynamic adsorption capacity

09/21/2011 4:40 PM

You could do what your competition is doing and go to competitive websites and see how they do it....or you could Google on your title and follow the descant manufacturers' recommendations, there's about 11,800 hits besides this one...


http://www.dynamicadsorbents.com/products2.htm

"What is the adsorption capacity?

Adsorption capacity is defined as the accumulation of the solute molecules at the surface of a solid. This capacity is directly proportional to the area of the surface exposed and is dependent on the solute partial pressure and the temperature. An increase in temperature reduces the adsorption capacity of activated alumina as the adsorption of water on alumina is exothermic.

Adsorption capacity depends on the surface site reactivity and is measured by the volume of adsorbed water per unit of surface area. Water in the air actually sticks to the alumina itself in between the tiny passages as the air passes through them. The water molecules become trapped so that the air is dried out as it passes through the filter. This process is reversible, and when the alumina desiccant is heated to between 350-600 F (177-316 C) it releases all of the water stored inside it. The process of heating the activated alumina is called regenerating the desiccant.

When a gas is compressed the partial pressure of the water present increases. At a constant temperature the adsorptive capacity for water increases with increasing water partial pressure (and relative humidity).

Desiccants are manufactured to meet standards such as "Standard Methods of Testing Sorbent Performance of Absorbents" published by ASTM International, as well as other US government standards."

Please note that this articles touches on process conditions that you did not state in your question thereby limiting the amount of information we can provide.

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#2
In reply to #1

Re: Desiccant- Dynamic adsorption capacity

09/22/2011 12:58 AM

GA.

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#3
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Re: Desiccant- Dynamic adsorption capacity

09/22/2011 11:54 AM

Dear RAMConsult

Thank you, that clears the basic concepts indeed. Consider the case and note the following process conditions for a No-Loss purge type instrument air dryer:

Inlet: P=7.5 kg/cm2 (g), T= 40 Degree C, Flow rate= 2500 Nm3/hr

outlet: P=7 kg/cm2 (g), T= 40 Degree C, dew point= -40 degree C

Desiccant to be used: Activated Alumina

Suplier considered the following data:

Regeneration temp=180 Degree C, cycle time-8 hours(8 hours-Adsorption, 8 hrs regeneration including 5.5 hrs heating and 2.5 hrs cooling)

DAC= 7.5%.. Pls clarify the basis for the same?

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#4
In reply to #3

Re: Desiccant- Dynamic adsorption capacity

09/23/2011 4:27 AM

There cannot be a basis for property of material. 'adsorption capacity' is a property of a particular desiccant, it can be different for even different makes of it. Only thing I can say for sure is that 'dynamic adsorption capacity' can be proportional to 'static adsorption capacity'.

Adsorption capacity greatly varies with temp and partial pressure of water in air to be dried. For instance a particular desiccant "molecular sieves" has static adsorption capacity of 22-23% at 25 degC and 11.88 mmHg water partial pressure. But for use its dynamic adsorption capacity is taken as 11-13% by the supplier for similar conditions. As per this analogy dynamic adsorption capacity is about half of the static, but this also may vary manufacturer to manufacturer.

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#5
In reply to #4

Re: Desiccant- Dynamic adsorption capacity

09/24/2011 5:58 AM

Dear Pritam,

With ref. to ur sentence "There cannot be a basis for property of material. 'adsorption capacity' is a property of a particular desiccant", pls note that:

i have used the word basis, as i want to know the selection criteria for this. If its a property of material then it must be experimentally determined or should be mentioned on the supplier certificate. If u check the desiccant supplier certificates, they always mention static adsorption capacity at test conditions.

DAC for Activated alumina if used in No loss purge type dryer is 7.5%.

Same activated alumina if used in heatless type dryer is much less than that around 0.2%.

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#6
In reply to #5

Re: Desiccant- Dynamic adsorption capacity

09/24/2011 8:53 AM

"As per this analogy dynamic adsorption capacity is about half of the static, but this also may vary manufacturer to manufacturer"

I think above sentence of my last comment is OK. You have not given the SAC of activated alumina. You agreed that static adsorption capacity is a property and I said dynamic adsorption capacity depends on static or a fraction of it. For the case I narrated, it is around 0.5. Now you want the basis of this fraction. Deciding the basis for this fraction is always a complicated matter because it depends on several factors like temp, RH, pressure, velocity, contact area etc. The most important factor besides all above is reliability factor. I will explain it taking a general case as follows.

Suppose considering all the factors like temp, RH, pressure, velocity, contact area etc. at rated condition a drier bottle filled with desiccant of bed hight 'L' is fully saturated in 'T' hours. From this information you can get DAC of the desiccant (as air flow rate, RH and weight of desiccant are measurable). But then comes reliability factor to find practical DAC. To take care of eventualities of wide variation in the factors affecting it, to take care life of desiccant (deterioration of quality) and also to take care any untoward problem in regeneration cycle (like failure of heating etc.) value of DAC is taken about 60 to 75% of measured DAC.

So, in your case, suppose this reliability factor is 70%, in 8 hours only 70% of activated alumina bed hight will be saturated. So bed will be OK even you prolong changeover up to 11 hrs.

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#7
In reply to #6

Re: Desiccant- Dynamic adsorption capacity

09/26/2011 11:36 AM

The current situation is:

Process data sheet of a propane dryer unit specifies Molecular sieve to be used as a desiccant. No grade has been specified for the same.

one of the bidder's has quoted for supplying dryer unit considering dynamic adsorption capacity as 7%.

Another bidder has considered the same as 12% and has obivously arrived at lesser size of desiccant vessel and hence is getting the cost advantage.

How to compare the above 2 cases or i have no other option just to accept the present cases?

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#8
In reply to #7

Re: Desiccant- Dynamic adsorption capacity

09/27/2011 12:19 AM

This application is different from your original post which was about instrument air drier. I have experience with instrument air driers and huge process air driers. But basic philosophy must be similar.

Now you have stated a real problem of selection between the two. Suppliers size the dryer units considering dynamic adsorption capacity of desiccant and maximum moisture load. Dynamic adsorption capacity of desiccant depends on its static adsorption capacity and the cushion considered by the supplier for reliability of operation over a period. Again it may be relevant to quote from my previous comment.

"To take care of eventualities of wide variation in the factors affecting it, to take care life of desiccant (deterioration of quality) and also to take care any untoward problem in regeneration cycle (like failure of heating etc.) value of DAC is taken about 60 to 75% of measured DAC."

The cushion considered by different suppliers are different as per their experience (here I mentioned 25 to 40%). Some suppliers may take low cushion to be more competitive without considering reliable performance in a long run. So it is better to specify these aspects in the process data sheet before tendering.

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#9
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Re: Desiccant- Dynamic adsorption capacity

09/30/2011 12:33 PM

"This application is different from your original post which was about instrument air drier".

GA pritam, OP (mayank) has started another thread about it, but he should respond to your so nice comments on this issue.

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#10
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Re: Desiccant- Dynamic adsorption capacity

10/02/2011 1:04 PM

GA (prdp & pritam)!

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