Most PLC's use the RS-232 port for programming. The listing of PC/PLC cables in the instruction sheet infers that the COM1 port is RS-232 for programming with either the handheld programmer or the Windows program.
This model CPU can handle Modbus ASCII and Modbus RTU over RS-485. It isn't clear whether the RS-232 port is dedicated to programming only, but it is clear that it talks Modbus over the RS-485 comm port 2.
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