Greetings,
Here are some photos of a project I've been working on for the past few weeks: an inexpensive, large-area LED made entirely from inexpensive, readily available materials. Some months back I was experimenting with doping silicon carbide with phosphorus in order to study its properties as a semiconductor. As luck would have it, the SiC glowed where it made contact with the aluminium anode (the cathode, being made of copper, did not seem to have any effect even when I reversed the polarity, and the glow disappeared from the Al:SiC junction when I reversed polarity, and so it appears I had created some sort of diode which emits a bluish-white light. An LED! Not extremely bright, but to have produced this effect at all was serendipitous at least. I've run the simple apparatus you see in these photos for several weeks now on just two AA alkaline cells, the ones you see in these photos. It is still running.
The materials themselves are readily available:
1. Sintered silicon carbide disk (look on ThomasNet or GlobalSpec)
2. Phophoric-acid based toilet bowl cleaner.
3. Aluminium wall-patch screen. Most hardware stores carry it.
4. Copper disk for cathode. You can snip this out of copper sheet which you can find at most at hobby stores.
5. A 3-volt power source. Two AA batteries have served for several weeks with no obvious decrease in light output. Battery holder from Radio Shack.
I soaked the disk for 24 in the toilet bowl cleaner, then put it in the oven for 3 hours at 400F. Let cool then rinse in distilled water. (Clean the disk before treatment to ensure that it is free of contaminants. Place back in oven at 180F for 15 minutes to ensure it is completely dry.
Solder a length of insulated wire to the copper cathode and place at the bottom of the shallow tray (a Pringles lid, if you must know).
Place the SiC disc on top the cathode.
Place the aluminium screen on top of that.
Compress stack to ensure everything makes uniform contact. I used a clear acrylic block for the weight. Don't compress too much or the brittle sintered SiC disk will break.
Apply power and watch it glow!





