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Safety of Iridited Aluminum

08/30/2012 11:12 AM

I need to put a safety statement on drawings of parts that are 5052-H32 aluminum treated with Aurous 19 Iridite (hex chrome). Everyone "knows" that the aluminum parts are safe but I can't find it in writing to quote in a safety statement.

The chemical plating house that did the work for us is Nadcap certified but they only have MSDS sheets for the chemicals they use. They can not provide us with a MSDS for treated aluminum. Their Aurous 19 chemical comes from US Specialty Color Corp.

I contacted www.usspecialty.com. They found a "shall have no adverse effect on the health of personnel when used for the intended purpose" statement in MIL-DTL-81706B but that is a little weak for two reasons. First, the sentence includes "processing baths or solutions" which gives it a weak tie to the finished product. Second, I am concerned that questions like "what if they drill it, grind it or sand it (small airborne particles)" and "how to dispose of it later" might come up. They didn't find anything in MIL-C-5541.

US Specialty seems to get the chemical from MacDermid. The Aurous 19 and Iridite 14-2 apparently are the same product with different labels. MacDermid has a guy that can "probably" help me but he is on vacation today. I am trying to write the ECO for these drawings now and get them done in an hour or so. I did not expect it to be so hard to find a statement that iridited aluminum is safe.

Any suggestions on safety documentation for:

1) Normal use (if necessary I can quote MIL-DTL-81706B section 3.4)

2) Modifying later by drilling, sanding or grinding the iridited surface (airborne particles)

3) Disposal (landfill or melting with the issue of fumes)

Thank you,

Bruce

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#1

Re: Safety of Iridited Aluminum

08/30/2012 12:43 PM
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#2
In reply to #1

Re: Safety of Iridited Aluminum

08/30/2012 1:00 PM

Thanks for the links.

Both links are for the chemical used to treat the aluminum. That chemical is known to be toxic. The chemicals were used at a NADCAP certified plating house and have been fully washed off the final product. Waste chemicals were treated/disposed of by them in a manner consistent with local, state and federal laws.

Aluminum with a gold iridite finish has been around for years and no one seems to worry about it. The problem is that I can't find a safety statement in writing for the clean treated aluminum. This is further complicated by issues such as drilling/grinding and melting.

You probably know this but I'll add it to the posting for others. Iridite is a "conversion process" and might be thought of as a desirable form of rust. The surface of the aluminum has been chemically converted from the 5052-H32 to an aluminum-something compound that requires a knowledge of chemistry to understand. Thus, it is not a "paint on poison" process but rather a "convert the aluminum surface to something else" process.

Thank you,

Bruce

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#3

Re: Safety of Iridited Aluminum

08/30/2012 2:48 PM

Virtually all the information available deals with handling the chemicals used during the process, not the finished parts.

The reason for that is obvious to you, there is virtually no way to ingest any harmful chemicals from handling, or even licking, a conversion coated piece of aluminum.

I've handled thousands of parts (we used Alodine 1200, not an endorsement) after conversion coating in a large aerospace company and we just wore cotton gloves, to keep from getting finger fat on them, prior to painting.

The automotive industry may have handling guidelines, but a casual search didn't turnanythign.

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#4
In reply to #3

Re: Safety of Iridited Aluminum

08/30/2012 2:53 PM

Thanks Lyn,

Both MIL-DTL-81706B and MIL-DTL-5541F state "The conversion coatings covered by this specification are intended for use, throughout the Department of Defense, on aluminum and aluminum alloy substrates that are not anodized." I quoted this and attempted to push back a little on the requirement to add a "gloves and respirator" safety warning. Still waiting to see how it turns out.

Bruce

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#5

Re: Safety of Iridited Aluminum

09/03/2012 11:41 AM

Hexavalent Chromium is one of the substances covered by the Restriction of Hazardous Substances (RoHS) regulations in the EU. If your treatment is the same as this (I am not a chemical expert) then you would probably not be able to incorporate the parts into most types of electrical equipment sold in the EU and other parts of the world with similar regulations.

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#6

Re: Safety of Iridited Aluminum

10/10/2012 4:28 AM

Iridite coating is achieved by chemical reaction.

Coating durability is better

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