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Active Contributor

Join Date: May 2007
Posts: 18

Substitute for proton exchange membrane NAFION 117

05/23/2007 12:27 PM

I am a 2nd year engineering student and doing a research project on microbial fuel cell.i require a membrane,basically a proton exchange membrane.

the membrane basically keeps out the organic matter away from the anode and allows hydrogen ions to pass through.

but this membrane costs a lot and i am looking for a substitute.i think dilasys membrane should work,but am not sure.

please give some advice.

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Guru

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#1

Re: Substitute for proton exchange membrane NAFION 117

05/23/2007 11:19 PM

I have personally visited researchers at Case western Reserve and the canadian national research council Institute for fuel cell innovation, and they have not found a substitute for a proton exchange membrane in their room temperature aqueous fuekl cells.

You cover a lot of territory with your 'basically a proton exchange membrane' comment.

It needs to let protons through, but not electrons (must be insulator) or no electricity will flow... the way we'd like it too. presuming dilasys is dialysis- why would you think that that would let protons through? it lets whole molecules through. gap size too big. (fuel cell wants to pass protons,dialysis membrane passes sodium ions etc. much larger. the accumulatoion of such would probably stop reaction.) disclaimer, I don't work on them, only research about them.)

Its expensive because of platinum and the engineering of getting the membrane right.

Dialysis membranes are 'basically' theres that word again cellulosic polymers, the size of the gaps permits diffusion of various species. It is semi permeable and 'suction' as it were is driven by concentration gradient on either side of the barrier.

Good luck with your project, not sure you'll get protons through the

Good luck on finding a substitute. Every one on the planet will be grateful if you do.

milo

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Active Contributor

Join Date: May 2007
Posts: 18
#2
In reply to #1

Re: Substitute for proton exchange membrane NAFION 117

05/23/2007 11:47 PM

Thanks a lot for your advice,but could the membrane used in reverse osmosis plants be useful?

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Guru
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#3

Re: Substitute for proton exchange membrane NAFION 117

05/24/2007 12:11 AM

Electrodialysis uses special membranes that will either allow positively-charged cations but not negatively-charged anions to pass through, or vice versa. Of course, you need to combine the membranes with a high voltage DC source. You have to use the ED stack as a whole unit. I'm not sure if this is what you have in mind, but I assume that you actually mean to separate cations from anions when you say you need to separate protons.

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Anonymous Poster
#4

Re: Substitute for proton exchange membrane NAFION 117

10/10/2010 6:25 AM

Hi have u succeeded in making the microbial fuel cell? have u used the proton exchange membrane or have made asingle chambered one? Reply me if u have done, my mail id is april8791@gmail.com.

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