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I Thought I Knew Thermocouples...But

08/30/2013 9:21 AM

We have a sulphur furnace for acid production that has a couple type R thermocouples for process temperature monitoring. They are mounted in the furnace with ceramic wells. Temperatures run around 1000 C. We have had problems with the wells failing and then a few days later the elements go from the gases.

The last set of wells put in have done, well.. 'well'. No failures as of yet. But the element for one was reading ~100 C lower than expected. When inspected we found that one of the wires coming out of the element was hanging by two strands. One bump and it was gone.

Went to the warehouse to get another and wouldn't you know it, they had none. So we went through our boneyard and discovered a couple of elements that had been pulled from the previous installations where the wells had failed. Yea! we had two but we weren't out of the woods yet.

The elements are single junction type R, probably 22 awg wire on a ceramic shaft 24" long. The termination head on one was the standard ceramic base with four screw heads for terminating. The other one had a stainless head and two #18 leads coming out of an epoxy type seal.

The SS element was in the best shape and read good at ambient and under a little heat. When installed it read nothing. So we went back to the second element. It was a bit rougher but read okay. When returning to the furnace the first element was reading 1900. Way to high. Replaced it with the second but that one only read 420. THe first element had cooled to ambient ~30 C but was still reading 900. Never had seen this occur. What is happening?

If we subtract the 900 degree ambient reading we get about process temperature expected. Transmitter loops are okay and readings were cross verified with a Fluke 725. The low readings on the second were found to be bad connection on the ceramic base. Extension wire is of the same type- R, and polarity was checked on both elements.

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#1

Re: i thought i knew thermocouples.... but

08/30/2013 9:55 AM

I'd go with a "no contact" sensor myself

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#2

Re: i thought i knew thermocouples.... but

08/30/2013 10:05 AM

I agree with Fredski. A no contact temperature sensor would likely be best here.

I'm not sure what the OP wants here?

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#4
In reply to #2

Re: i thought i knew thermocouples.... but

08/30/2013 11:43 AM

I want to know how a TC can shift or change to a higher value. I understand how it can read low. Most of the time in this application they just open up. Have not seen this before.

As far as a non contact measurement, what can you use to peer through a 2" hole in refractory? That sounds interesting.

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#5
In reply to #4

Re: i thought i knew thermocouples.... but

08/30/2013 11:59 AM

I like Tony's answer below as a plausible reason for a thermocouple to read high. You also have to remember that a thermocouple produces only a very small voltage. A thermocouple does have a very low source impedance so interference does not easily get induced but any that does get on these wires can produce a very high error.

There is a large spectrum of non-contact measuring instruments. Here is one of the most well known.

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#3

Re: I Thought I Knew Thermocouples...But

08/30/2013 11:22 AM

>> [W]e went through our boneyard and discovered a couple of elements that had been pulled from the previous installations where the wells had failed

If these thermocouples had been exposed to the corrosive atmosphere of the furnace due to well failure, there's a good chance the metal wires inside have been chemically attacked. If this is the case, there might be a point along the thermocouple's wires where some sort of galvanic action is taking place, generating a small millivoltage equivalent to 900 degrees for a type R thermocouple. That's my best guess at this time.

This is an interesting problem, which I just might share with my students this Fall quarter when we study thermocouples. Thanks for sharing!

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#6

Re: I Thought I Knew Thermocouples...But

08/30/2013 3:21 PM

Thermocouple effect appears on each and every junction between disimilar metals or alloys according to that paticular junction or connection termperature. The total voltage you get is the algebric sum of those voltages and not necesarily the wanted couple voltage. To eliminate the errors from this issue, the connections of any extension cable MUST be of the same metal as each TC metal, OR both connections be of absolutely same metals AND temperatures. S.M.

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#7

Re: I Thought I Knew Thermocouples...But

08/30/2013 9:05 PM

What you are seeing is drift.

Drift is caused by chemical pollution so that the thermocouple wire is no longer the pure metal or alloy for the type thermocouple on the national standards table; rather one or both metals are chemically altered to a different alloy.

Therefore the standard tables are invalid. It's still a thermocouple generating a millivoltage over the temperature gradient, but it's got its own mV:temp table, an unknown table.

Drift can be positive or negative, the direction will depend on the pollution chemistry.

High heat allows ion transfer of metal ions through the mineral insulation. So metal ions from the sheath can pollute the junction.

The graph at the link below is a test with several manufacturers base metal thermocouples done by a company that developed a mineral insulation with substantially higher resistance than the conventional MgO, which tends to delay high temperature ion migration.

The chart shows the test of several different brands over hundreds of hours. One T/C was initially low, but drifted high.
http://www.accutru.com/subcategory.php?subcat_id=13&catid=5

You can read Accutru's story of a better thermocouple insulation on the ISA site here:
http://www.isa.org/Content/ContentGroups/InTech2/Features/2003/July22/Its_HOT!_Darn_HOT!_Real_HOT!.htm


http://www.accutru.com/subcategory.php?subcat_id=13&catid=5

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#8

Re: I Thought I Knew Thermocouples...But

09/01/2013 6:45 AM

Just a thought. Have you considered a type N t/c? They will work happily at 1000°C and are less expensive than type R. OK you will have to change the comp cable, but if your indicator/controller is modern it may accept different t/c inputs. Also, if you use a mineral insulated t/c of say 6 mm diameter which should fit into your ceramic well, then you've got further protection.

As I said, just a thought.........

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#9

Re: I Thought I Knew Thermocouples...But

09/02/2013 7:55 AM

it may be because of sulbher affecting the thermocouple as your T/c is ss 308/309 so u replace the termocouple with Inconnel 600 material & also termowell with Inconnel 600 then sulfher does not effect on T/c

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#10

Re: I Thought I Knew Thermocouples...But

09/02/2013 11:06 AM

Thanks for the input folks. No solution as of yet but I can tell you what we have looked into and some of the results.

We tried the noncontact method with several of the handheld IR meters but they only worked up to 500 C. The cone sensing (target gets larger as distance increases) made it very difficult to get measurements 24" into the well without averaging in cold refractory along the edges. The thermal imager worked the best once it was finely focused but it gave us no electrical feedback.

THe extension wire was of the same type but we tried a section from another roll just to be sure. No change in readings.

There were several ideas on chemical contamination of the wire or junction. These elements are bare thermocouple wire that is ran through a 6mm ceramic tube with two tiny holes that the individual wires travel. At the tip is the exposed junction. There is no mineral insulation or stainless material on the element. At the termination end which is outside the furnace the ceramic tube is swaged into a SS tube and may have some sort of MI at that point to the exit wires ~3 -4 inches.

The millivolt range for this TC is ~ 0 to 21. At 900c the rated output is 9.2 mV or about 40% of the output.

We should have our new TC elements here this week so we'll get to do some more tests and hopefully get something working properly.

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#11

Re: I Thought I Knew Thermocouples...But

09/02/2013 1:20 PM

Your style thermocouple assemblies do not have MgO insulation, but the tip and wires are exposed to whatever the atmosphere is inside the ceramic protection tube. I suspect that your elements have become chemically polluted because of the symptoms you describe.

Thermocouples that are chemically polluted (and drift) increase in resistance compared to a new thermocouple of the same type.

Why not test and see?

The best way to measure resistance is when the thermocouple is isothermal, that is, it has no temperature gradient across it because when a thermocouple has no temperature gradient it outputs zero millivolts. Zero millivolts will not alter the measurement taken by an ohmmeter, which always applies a voltage to the circuit to make the measurement. A thermocouple is near to isothermal when has been sitting on a bench for a period and both ends of the T/C are at the same temperature.

I'd suggest that when you get your new thermocouples, you put the news and the old ones on a bench, let them sit for period and equilibrate to whatever the ambient temperature is and then take a resistance reading with an ohm meter. Swap the meter leads and take a 2nd resistance reading with the opposite polarity. Write the results down.

Do the same (at the same time) for your used thermocouples. I suspect you'll see significant resistance differences between the new thermocouples and the old thermocouples, indicating chemical pollution.

I only have base metal thermcouples (type K) to work with (no noble metal, like Type R or S). New, unused base metal thermocouples are less than a couple ohms. Base metal thermocouples drift at around 80 ohms and I've seen them go as high as 200 ohms.

Base metal extension wire has a fairly high resistance compared to copper wire, and I'm not talking about measuring extension wire resistance as part of this measurement, this is about the resistance of the thermocouple itself.

Please keep us posted as to your findings.

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#12

Re: I Thought I Knew Thermocouples...But

09/09/2013 3:04 AM

The results are in. Iris and tonykuphaldt were correct. There was a combination of wire contamination and MgO insulation contamination. The new thermocouples measured ~1.2 ohms. the defective one was 200k.

We separated the ceramic element at the point the SS started at the termination end. The TC wire to the junction side read 1.2 ohms. The TC wire on the SS side to the + output lead read 70k. The other TC wire to the - output was 1 ohm. Somewhere inside the SS section there was a junction where the output leads were connected to the TC leads and this area had what appeared to be this MgO insulation. From the positive lead to the SS surface there was a potential of 215 mV and on the negative side there was a potential of 112mV.

Thanks again for the help and the insights.

Cheers

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