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Surface Tension And Vessel Blanketing

09/16/2014 1:34 AM

Hello everyone,

I have a vessel containing mineral oil at 300 degree centigrade, we use niitrogen gas to pressurise and isolate system from external environment (to avoid oxidation).

My question is, Does surface tension of fluid play any role in maintaining the solubility of nitrogen gas into mineral oil ??

Please, do share your views on this.

Thanks,

- NTR

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Guru

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#1

Re: Surface tension and vessel blanketing

09/16/2014 1:42 AM

Not as much as the pressure of the gas and temperature of the oil.

Probably not any, but I'm not 100% sure.

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Guru

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#2

Re: Surface tension and vessel blanketing

09/16/2014 2:52 AM

Surface tension and maintaining solubility?

If any it will be more of a hindrance.

Do you want the gas in the oil?

What did your internet search come up with?

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#4
In reply to #2

Re: Surface tension and vessel blanketing

09/16/2014 6:19 AM

No, I don't want gas in the oil.

I have seen oil datasheets specifying surface tension of liquid at a temperature, but have never seen anyone referring surface tension for any of the design purpose.

Thanks,

_NTR

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Guru
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#3

Re: Surface tension and vessel blanketing

09/16/2014 4:02 AM

Not as much as temperature. In general, the higher the temperature, the lower the solubility, though there is a distinct absence of data here.

Might be worth some experimentation, perhaps?

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#5

Re: Surface tension and vessel blanketing

09/16/2014 6:29 AM

My understanding is that, a fluid with higher surface tension will have larger tensile forces at the top layer and thus gas cannot dissolve in the liquid. But considering the different fluid at same temperature and pressure with lower surface tension, the solubility would be more.

Please correct me, if I'm wrong

Thanks,

- NTR

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Guru

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#7
In reply to #5

Re: Surface tension and vessel blanketing

09/16/2014 11:49 AM

Highly unlikely it would make any discernable difference. Gas solubility likely to be different for a different fluid, but not because of change in surface tension.

And as you're dealing with a specific fluid it's irrelevant.

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Guru

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#6

Re: Surface tension and vessel blanketing

09/16/2014 8:48 AM

ASSUMING (yes, there's that word again!) that the temperature and pressure are static and that the mineral oil is being held in the container as opposed to circulating through it and then to a process area of different parameters- NO.

Temperature and pressure are parameters that affect the solubility of gases in liquids. Surface tension may affect the rate of exchange, but it will not affect the overall solubility. So, providing the system is maintained at a steady state and the materials are in contact long enough to reach equilibrium the levels of dissolved gas will be the same. If you are using this as a buffer tank the answer may be different.

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#8

Re: Surface Tension And Vessel Blanketing

09/17/2014 1:04 AM

Thank you all for sharing your ideas and making me clear that surface tension has no effect on solubility.

But, what would be the reason for specifying Surface Tension in Oil data sheets ??

Thanks,

- NTR

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Guru

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#9
In reply to #8

Re: Surface Tension And Vessel Blanketing

09/17/2014 12:13 PM

Several possibilities. It is a physical parameter, and there are situations where someone may want to know it. Usually though, I find things like that are because "we had to do it for X situation so we just put it down for all the products".

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