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Boiling Temp of ETO @ .865 bar

02/25/2015 7:30 AM

Hi, Can anyone help this poor MD to figure out the boiling temperature of Ethylene Oxide at a pressure of .865 bar ? At one Bar boiling point is 10.7ºC. Vaporization enthalpy is 25.5 Kj/mol

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#1

Re: Boiling Temp of ETO @ .865 bar

02/25/2015 9:52 AM

Here's a plot of vapor pressure vs temperature C. 0.865 bar = 648 mmhg.http://www.unit-conversion.info/pressure.html
Vapor Pressure of Ethylene Oxide

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#2
In reply to #1

Re: Boiling Temp of ETO @ .865 bar

02/25/2015 10:21 AM

I think the above plot is incorrect. This plot agrees with your numbers. Sorry, I grabbed the wrong plot.

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#3
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Re: Boiling Temp of ETO @ .865 bar

02/25/2015 12:07 PM

Thanks Rixter! I must confess I went the complicated way, wanting to figure the value out using a complicated (to me) mathematical formula.... forgetting to do the more obvious like searching for a graph, as you did

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#4
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Re: Boiling Temp of ETO @ .865 bar

02/26/2015 10:36 AM

The formula for vapor pressure is usually a simple exponential, wherein the energy barrier used is the heat of vaporization.

For transitions between a gas and a condensed phase with the approximations described above, the expression may be rewritten as

from the wikipedia article on the Clausius-Clapeyron relations (equations). In the above formula, R is the ideal gas constant, with the units is KJ/mole (or Kcal if L is Kcal), L is the latent heat of vaporization, T is absolute temperature (Kelvin degrees), and c is the logarithmic offset (normally called a scale factor to the exponential. This is accurate to first-order approximation, and the link included below has a more elaborate formula where the curvature of the coexistence line (second derivative) is included in considerations. Rixter already gave you a good enough answer though.

Ethylene oxide is nothing to be playing with at any pressure. Are you the Industrial Hygienist at your location? Are you dealing with a spill or a leak? I hope you and everyone else is able to stay upwind of this, and there are no civilians downwind.

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#5

Re: Boiling Temp of ETO @ .865 bar

02/26/2015 3:44 PM

Here's another form of the Clausius-Clapeyron Equation:

I plugged in the following values:

P1 = 1 bar

T1 = 283.86 °K

P2 = 0.865 Bar

ΔHv = 25.5 Kj/gmole

R = .0083145 Kj/gmole-°K

If I didn't make any errors... T2 = 280.1°K (= 6.9°C)

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#9
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Re: Boiling Temp of ETO @ .865 bar

02/27/2015 6:25 AM

Thank you a lot ! We have applied the same equation, arriving to the same results.

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#6

Re: Boiling Temp of ETO @ .865 bar

02/26/2015 4:12 PM

I guess you already know that ETO is highly, highly toxic.

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#7
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Re: Boiling Temp of ETO @ .865 bar

02/26/2015 6:43 PM

Not only toxic.... but also explosive! :-)

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#8
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Re: Boiling Temp of ETO @ .865 bar

02/26/2015 9:12 PM

Hmmm.

One cannot help but wonder what your endevour is.

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#10
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Re: Boiling Temp of ETO @ .865 bar

03/02/2015 8:37 AM

My guess is this MD is somehow responsible for attempting to kill very dangerous pathogens with ethylene oxide. My question is this: Is there anything worse you could try such as Polonium 210, or another alpha emitter that would make the place uninhabitable for a longer period of time than ethylene oxide. How do you propose to get rid of the EO? Are you going to use high intensity UV light - be warned that inducing free radicals in this will make it explode, IMHO.

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#11
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Re: Boiling Temp of ETO @ .865 bar

03/02/2015 9:17 AM

Hello James Stewart, thank you for your concern and wise opinion!

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