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Speaking of Precision

Speaking of Precision is a knowledge preservation and thought leadership blog covering the precision machining industry, its materials and services. With over 36 years of hands on experience in steelmaking, manufacturing, quality, and management, Miles Free (Milo) Director of Industry Research and Technology at PMPA helps answer "How?" "With what?" and occasionally "Really?"

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Three Facts About Scale (Iron Oxide) Rust On Steel

Posted August 02, 2011 9:00 AM by Milo

On hot rolled bars to be cold drawn, the dark oxide surface is called scale.

What we see on the surface is "scale" - a combination of oxides of iron.

Scale is the name given to the oxides of iron that are formed on as wrought products as a result of mill operations (high temperature rolling or furnace treatment)

Rust is the commonly used term for iron oxide from weathering or corrosion.

Scale is

  • Hard
  • Brittle
  • High Coefficient of Friction

So we need to get it off the steel if you are to have any chance of keeping the tool edge sharp.

There are 3 oxides of iron:

Hematite ( Fe2 O3) has a microhardness of ~ 1030 D.P.H., is red in color, and is not soluble in acid.

Magnetite (Fe3O4) has a microhardness of ~ 420-500 D.P.H., is black in color, and is not soluble in acid.

Wustite (FeO) has a microhardness of ~ 270 -350 D.P.H., is blueish in color, and is soluble in acid. Wustite is the phase that makes up the innermost scale on the bars or rods.

Hematite and Magnetite make up the outer layers of the scale, and due to their composition, make up the larger mass of scale present. Due to their hardness and quantity they are the real deal-breakers for machining as they create tool edge wear.

One of the ways that Cold Finished Steel bars aid machinability is by removing these hard abrasive oxides from the workpiece, so that they don't destroy your tools and contaminate your cutting fluids.

Bar Coils

Editor's Note: CR4 would like to thank Milo for contributing this blog entry, which originally appeared here.

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#1

Re: Three Facts About Scale (Iron Oxide) Rust On Steel

08/02/2011 3:50 PM

Hi Milo,

I know that Magnetite is chemically created to preserve the steel on guns from rust. Are the other oxides used to preserve steel from rusting?

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Re: Three Facts About Scale (Iron Oxide) Rust On Steel

08/02/2011 10:07 PM

Hey there ozzb. Magnetite is indeed the black oxide applied commercially to items such as firearms. Hematite is the rust we are trying to prevent. Milo

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#3
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Re: Three Facts About Scale (Iron Oxide) Rust On Steel

08/03/2011 12:30 AM

This sounds like "weathering steel", such as Cor-ten. IIUC, a thin oxide layer prevents deeper oxidation.

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Re: Three Facts About Scale (Iron Oxide) Rust On Steel

08/03/2011 7:45 AM

Thanks Tornado Cor-ten is and example of using one oxide form to retard rusting. Tool black or the applied coating of black oxide another. Any examples of Wustite use?

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