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On November 14, 1969, the Apollo 12 mission was launched. The Saturn V launch vehicle for the Apollo 12 mission had several stages, including the S-IVB third stage that was discarded into a heliocentric orbit.
Flash forward to September 2002. Bill Yeung, an amateur astronomer, found what he thought was an asteroid in elliptical orbit around the Earth. The new object was designated J002E3.
Spectroscoptic analysis of J002E3 revealed the 'asteroid" had the same chemical signature as the paint used on Saturn V rockets. It was quickly realized that J002E3 wasn't an asteroid at all but the S-IVB third stage from Apollo 12, appearing again after years in an
unstable high Earth orbit. For nine months astronomers tracked J002E3 till it left Earth's proximity in June 2003, ejected by the moon's gravity.
The good people at Wikipedia have a GIF of J002E3's orbit as modeled by astronomers.
J002E3's Orbital Motion
Also, here's a great behind-the-scenes story about the Lunar Lander.
Lunar Lander: How One Engineer's Persistence Led to Apollo Success
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