Researches from the University of
Georgia, Princeton University and Oxford University report a new method for
nanofiber production using a permanent magnet and ferrofluid - magnetospinning.
Results of this research are published in Advanced
Materials journal - http://onlinelibrary.wiley.com/doi/10.1002/adma.201500374/abstract
A ferrofluid is a colloidal dispersion
of stabilized magnetic nanoparticles that responds to an external magnetic
field: above a critical value for a uniform field the surface of the ferrofluid
deforms and a liquid spike is formed on the surface. In addition, as a magnet
approaches an interface, the field is nonuniform, the interface always deforms,
so the spike moves towards the magnet and forms a liquid bridge. This
instability was explored in this work in a new method for drawing polymeric
nano and microfibers in which the magnetic force generated by a permanent
magnet is used to draw fibers with controlled diameters in the 0.05-5 µm range.
As the magnet approaches the ferrofluid the magnetic force attracts the droplet
towards the magnet and a liquid bridge between the magnet and the needle is
formed. The magnet moves away and draws the polymer fiber while the solvent
evaporates. The resulting nanofibers are spooled on a reel that is attached to
the opposite side of the stage.
Here is an image: https://drive.google.com/open?id=0B4pIk1QJITn9UDh5X2w2UDIzLW8&authuser=0
The
new method provides excellent control over the fiber diameter and is compatible
with a range of polymeric materials and polymer composite materials including
biopolymers. This research showcases new
technique and demonstrates its advantages to the scientific community. For
example, polymers with low dielectric constant cannot be electrospun without adding high
dielectric constant ingredients but can be easily magnetospun, for example
Teflon© fluoropolymer fibers that are ideal for the design of superhydrophobic
materials. Owing to its simplicity and low costs, magnetospinning set-up could
be installed in any non-specialized labs for broader uses of magnetospun
nanofibers in different methods and technologies. Electrospinning
is the most popular method to produce nanofibers in labs now. The total cost of
a laboratory electrospinning system is above ~$10K. In contrast, it is possible
to build a magnetospinning set-up, such as we utilize, by just using a $30
rotating motor and a $5 permanent magnet. No special equipment is needed for
magnetospinning.
Researches showed that the productivity
and scalability in magnetospinning is comparable with electrospinning methods and
demonstrated universality of the new method by fabricating several examples of
different polymeric fibers, including Teflon© fibers, fibers with aligned
carbon nanotubes, silver nanowires, and porous fibers - all obtained with the
same experimental set-up
Here is an image: https://drive.google.com/open?id=0B4pIk1QJITn9ZGdTWTFUR2RsSGs&authuser=0