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Descaling of Plate & Frame Caustic Heat Exchanger

06/22/2018 2:44 AM

Hey there, In my chloralkali industry a P&F HXchanger (constructed out of Ni) is used to cool 32 w.t% NaOH from 87 to 75 Celsius using Cooling water (CW) available at 32C (in summers)

For previous x2 months the duty of HXchanger duty decreased such that outlet NaOH temperature cannot be decreased below 80C

Flowrates of NaOH, its entering temperature is same (thermocouples & flowmeter). CW flowrate is also same (indicated by pressure gauge at the inlet to HXchanger)

In an attempt to insitu descale HXchanger without disturbing running process I utilized an opening to inject HCl (34 w.t%) at the inlet of CW. Stopped CW flow completely for ~2mins & initiate HCl flow while keeping outlet temperature rise in check! Then again CW flow is resumed & HCl flow stopped after ~15min again the previous ~2min HCl cycle was repeated. In whole of this process outlet point of CW was open to drain (instead of being returned to Cooling Tower)

This HCl flush cycles were done ~6 times after the 4th cycle the outlet pH of HCl stopped increasing indicating no HCl consumption while descaling salt deposits.

The performance of HXchanger (after above activity) slightly increased but to no avail ..it now approached minimum temperature of 79C (a decrement of only 1-1.5C)

Now is there any other activity I should try, anything other than HCl! I believe that our Cooling Tower has deposited silica based impurities & what cleaning agent I should try to remove it.

Regarding Cooling Water specs: 6-6.5 pH; chromate inhibited; 2barg pressure

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#1

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/22/2018 2:54 AM

1: Discuss the cooling water treatment regime with the supplier of the treatment chemicals. Discuss the exchanger performance with the original equipment manufacturer.

2: Consider stripping-out the exchanger for a deep chemical and mechanical clean, and then reassemble.

3: Consider increasing the number of plates in the exchanger.

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#3
In reply to #1

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/22/2018 8:22 AM

good answer, especially #2, actually all most of them

we have material running through our plate HX's where fouling is a problem and normally CIP just doesn't cut it. We have to wash the plates by hand.

On number #3, by adding more plates, don't you reduce the flow rates through the plate decks where possible creating a laminar flow..?

(ΔP would be reduced some what also)

But also contacting the Chemical Rep. for recommendation would be prudent.

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#2

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/22/2018 4:22 AM

4. Investigate and rectify sources of unexpectedly low flowrate in the cooling water system.

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#4

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/22/2018 11:40 AM
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#5

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/23/2018 12:29 AM

Thanks for the answer guys.

Lower CW flowrates (at some times) ...hmmm this can be the problem which needs remedy because CW inlet pressures aren't logged at DCS. Thanks

Increasing # of plates cannot be justified because the required performance was being achieved since 2011.

Taking out HXchanger will cause production loss ...which though is an option but not currently when caustic prices in international market are at peak. Thus I am looking for insitu solutions

I did add CW specs to make it comprehensible what may be the kind of fouling we are dealing with.

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#7
In reply to #5

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/25/2018 9:38 AM

<... what may be the kind of fouling...>: 3 kinds -

  1. Biofouling
  2. Chemical deposition
  3. Corrosion
  4. Some combination of 1-3

If <...Taking out HXchanger will cause production loss...but not currently when caustic prices in international market are at peak...> then one may assume the following:

  1. Off-spec product is acceptable, and therefore the production specification needs widening to accommodate that which can be manufactured, thereby removing the concern.
  2. There is no justification for installing duty/standby <...HXchanger...> in parallel in readiness for the next time this phenomenon happens.
  3. The problem is simply constrained beyond the point where a solution may be applicable.
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#8
In reply to #7

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/25/2018 6:55 PM

The problem is simply constrained beyond the point where a solution may be applicable.

PWSLACK, were you writing this comment while reading Mathematics book on Stochastic optimization?

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#6

Re: Descaling of Plate & Frame Caustic Heat Exchanger

06/23/2018 10:51 PM

32% NaOH at approx. 75 C is a VERY good way of removing mild silica deposition- that is,if you can think of somewhere to get some.

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