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Uses for Formic Acid

08/31/2020 11:16 AM

I recently read where they are considering using formic acid in fuel cells to produce hydrogen.Not as efficient as methane or other fuels,but might be viable for portable devices.

There is an abundant source of formic acid available naturally,with a small amount of processing required.

The source is fire ants.They produce copious amounts of formic acid and their colonies can be smelled from a great distance.

The shoulders of interstates are populated by thousands of colonies that stretch many miles.Trillions of little formic acid factories.

Many farms are also plagued by these pests.

Instead of pesticides,they could be harvested for value.

A simple way to harvest the ants would be a large vacuum truck,like used for septic tank cleaning,and partially filled with water,with a dump valve for debris,dirt,etc. when it reached a certain level.

Fire ants cling together in water,and there could be a divider wall in the tank to allow them to escape into another dry chamber.

It should be easy to extract the formic acid from these insects.

Reduce pests,and harvest a free energy source at the same time.

Sounds like a win win situation to me.

I put out this idea on a public forum so that it may be freely explored and developed without a patent.

I am sure there will be other incarnations of this basic idea,and probably some will be more efficient.I am counting on it.

All constructive comments are welcome.

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#1

Re: Uses for Formic Acid

08/31/2020 12:11 PM

Great for killing the mites, that are killing the bee's...

What you want are Wood Ants....

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#2

Re: Uses for Formic Acid

08/31/2020 3:26 PM

That's an interesting concept. Over 99% of formic acid is currently produced in Asia (mainly China) and in Europe. Out of 720000 tonnes produced annually, less than 1000 tonnes is produced on other continents.

There are several production methods, but no mention of extraction from insects. HCOOH is a fairly simple chemical, and I'm wondering if insect extraction is economically competitive with chemical production.

https://en.wikipedia.org/wiki/Formic_acid

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#3
In reply to #2

Re: Uses for Formic Acid

08/31/2020 5:00 PM

I do not know the feasibility of this,but I have seen these fire ant mounds stretch for hundreds of miles along the interstate I-40,spaced about 50 ft apart.

There are approximately 250,000 ants per colony,average.

If each ant weighs approximately 1 gram,that works out to approximately 500 lbs per colony.

Even if only 10% is acid,that's 50 lbs per colony and at 100 colonies per mile,it could add up quickly.

I don't know how much formic acid is in each ant,but it might be worth studying.

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#6
In reply to #3

Re: Uses for Formic Acid

09/01/2020 12:18 AM

"If each ant weighs approximately 1 gram..."

Remember that one cubic centimeter of water "weighs" one gram. The density of an ant is a little higher than water, because they sink if there is a little soap to break the surface tension, but an ant with a volume of a cubic centimeter would be HUGE! I've done no measurements, but I suspect your weight estimate is at least an order of magnitude too high.

I'm pretty sure the highway folks don't want you digging up the sides of the roads, so you could only vacuum up those at or very near the surface. you could disturb the surface and wait a while for more ants to come out, but I doubt if you would be able to suck up more than something like 10% of the ants of a given hill. There's another order of magnitude.

Again, I am talking without measurements, but I suspect the volume of formic acid in each ant is closer to 1% of the weight of the ant, and there's another order of magnitude.

Without even giving a number to the fraction of formic acid that could be recovered from the processed ants, I easily see a thousand-fold overestimate on the volume of your source.

I suspect rather strongly that you couldn't recover enough fuel to even power the vacuum trucks.

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#7
In reply to #6

Re: Uses for Formic Acid

09/01/2020 7:25 AM

Perhaps a little genetic modification would be necessary...?

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#8
In reply to #3

Re: Uses for Formic Acid

09/01/2020 7:37 AM

that's crazy that there are that many colonies down south. i hope they dont like cold weather.. i remember my first experience with them.. dropped my drawers in the middle of the street in residential La town. was doing water leak detection for a town, evedently the little buggers took up residence in a meter vault. before i knew it, my junk started stinging as if i had fiberglass underwear.

kiler bees, fire ants, scorpions, rattlesnakes, cottonmouths..geez what did i leave out? i will take a little snow anyday then deal with all that.

to answer the question for uses..i remember using formic acid years ago to reduce platinum and iridium from an acid salt. i had a process to coat small dia. ceramic fibers with a thin noble metal layer for oxide ceramic composites..

i think bees also inject this when they sting ya, could be wrong.. been a while since i messed with this stuff.

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#4

Re: Uses for Formic Acid

08/31/2020 5:50 PM

Unfortunately, fire ants are not of the family Formicinae, the only family of ant that produces formic acid in appreciable quantities as venom.

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#11
In reply to #4

Re: Uses for Formic Acid

09/01/2020 11:21 AM

You are right..they produce an alkaloid venom.

Guess that blows my idea right out of the water.But,if you get within 100ft of a fire ant mound ,it smells like a freshly cut,hot Formica sheet.

Perhaps they have mutated?

I wonder if there is any use for the alkaloids?

Anyway,probably not a lucrative venture.

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#17
In reply to #11

Re: Uses for Formic Acid

09/05/2020 12:35 AM

There are several piperidines in fire ant venom. Solenopsin is considered the main toxin, though several closely related peperidines may contribute to the sting effects.

Solenopsins have been researched for a wide variety of effects from treating psoriasis to cancer, as well (oddly enough) solenopsins show insecticidal properties as well as antibacterial film properties.

Apparently the mix of closely related chemicals in fire ant venom makes obtaining pure solenopsins a difficult task.

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#5

Re: Uses for Formic Acid

08/31/2020 11:22 PM

Harvesting red ants for their formic acid has a long history - here's a 1907 newspaper report of the plan:
Los Angeles Herald, 2 July 1907 article

But the idea goes back even further. Large scale Asian synthesis of formic acid saves plenty of ant souls, compared with formic acid that was first extracted in 1671 by the English naturalist John Ray by distilling a large number of crushed ants.
To save all those ant souls, I prefer the 1907 method of washing the acid from harvested ant nest sand, leaving the ants to rebuild the nest. Tread carefully, PETA is watching!
https://www.peta.org/living/humane-home/tips-humane-nontoxic-ant-control/

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#12
In reply to #5

Re: Uses for Formic Acid

09/01/2020 11:24 AM

I don't hate ants,but these are an invasive species.(I will not try to eliminate them from South America.)

(Aunts are important...without aunt holes we would not have cousins)

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#9

Re: Uses for Formic Acid

09/01/2020 8:55 AM

Personally I like the idea! I'm sure a fair amount of research would be required to work out logistics of getting at colonies affordably, in that the easiest colonies would quickly die out requiring more effort to find new harder to reach colonies. With that said having been bit by a few over a life time, I don't like them anyway.

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#10

Re: Uses for Formic Acid

09/01/2020 10:13 AM

I've heard you can eat those ants, but you may have a problem with the ant acid.

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#13

Re: Uses for Formic Acid

09/01/2020 11:31 AM

IMHO:

A good home remedy for insect stings,bites,etc. from an elderly friend of mind is this and it works for me:

Hand cream,any brand, and Ammonia.

Approx25% ammonia to 75% hand cream.Ratio not critical.

Shake well before each application.

The ammonia neutralizes the venom,and the hand cream prevents skin drying out.

Works better than the sting sticks,which are basically ammonia.And it is a lot cheaper too.

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#14

Re: Uses for Formic Acid

09/01/2020 11:36 AM

I wonder if an anteater will eat fire ants?

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#15
In reply to #14

Re: Uses for Formic Acid

09/01/2020 2:39 PM

Tex-mex ant eater tacos. Pre seasoned.

.? So.. can a formica countertop be processed to produce hydrogen?

I hate those counters. And there are also 500 per mile in most communities.

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#16

Re: Uses for Formic Acid

09/01/2020 5:59 PM

Perhaps the <...they...> might work on a combined mass and energy balance calculation to assess viability, the way that a qualified Process Engineer might. That would be a worthy consideration, together with the Energy Cost of Energy Supply, as well as sustainability issues.

One can, in principle, obtain hydrogen from anything that contains it. The easiest feedstock to harvest, is water, which doesn't depend on mining anthills. Repeating the above assessment on water might suggest its preference on economic grounds. Formic acid is a solution looking for a problem.

It pays to remember that hydrogen is only a carrying and storage technique, much like electricity.

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