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Rust Detection

04/11/2008 7:19 AM

What are methods for chemically, or otherwise, determining rust. In this case iron oxide, is present on a painted surface. I have an inquiry from a field service Rep who has sent pictures of a painted aluminum surface with rust spots (2-3 mm dots) red orange in color. Presumptions are these spots are sourced from welding or grinding steel close by the surface in question. That is , depositing the dust on this painted surface and subsequent oxidation. easy enough to surmise that but difficult to prove over the phone. Does any one know of a no destructive test to verify the oxidation is in fact ferrous metal oxide say as opposed to something that looks like metal oxide.

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#1

Re: Rust detection

04/11/2008 7:45 AM

Hmmmm is it possible to wipe these spots off the painted surface and show that the paint is intact and not rusty?

Does that prove that the corrosion is after it is installed and is due to contamination?

Is the customer complaining that the rust spots were because of your fault... i.e. supplying contaminated paint??

I'm not sure I'm following this at all... John.

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#3
In reply to #1

Re: Rust detection

04/11/2008 9:57 AM

Thanks for the fast responce. - Regarding wiping the spots off - I can presume the field personel have tried that - but will ask. I would agree that if you could wipe the spots off that the contaminates were post shipping. In the event they do not wipe off I was looking for some sort of field test that would verify that is was infact an iron oxide as opposed to some other contaminate exhibiting the same orange/red tinge.

It is possible the customer is hinting the defect came from the supplier. I have only recieved the first report of the problem and have not seen this defect reported in the past. We only use aluminum and SS metals in our product along with 2 mils of Powder coat paint - this failure mode has never surfaced. Ive checked the process eliminating any probable/possible contamination in the assembly stages.

I'm thinking there is a quick field test to verify the partical in the contaminate (other then magnets) is a ferrous metal. In this case there is no visable solids that could be picked off with a magnet - only the residue indicating that it may have been ferrous metal. Give our lack of experience in dealing with this failure mode It seemed faster to ask those who experienced similar defects..... Tom

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#2

Re: Rust Detection

04/11/2008 9:10 AM

Just run a magnet over the spot. Look at the magnet. Does the magnet show these "dots". If it does, the indication is that someone nearby was grinding or welding ferrous metal. Clean away these spots and touch up the aluminum painted surface if was damaged. Aluminum will not be attracted to the magnet.

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#4
In reply to #2

Re: Rust Detection

04/11/2008 9:58 AM

Ferrus oxide will not be attracted to a magnet either, I think?

John.

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#11
In reply to #4

Re: Rust Detection

04/12/2008 1:34 PM

Correct.

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#5
In reply to #2

Re: Rust Detection

04/11/2008 10:01 AM

Thanks for the response - Ther are no solids I can see in the picture that could be pick off by a magnet.

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#6
In reply to #5

Re: Rust Detection

04/11/2008 10:11 AM

Perhaps someone has already wiped away the grinding dust, but not before the paint was damaged. If the dust is gone, then the next step is to rub the spot and look for pitting. Galvanic corrosion is a possiblility as well.

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#7
In reply to #6

Re: Rust Detection

04/11/2008 10:17 AM

Good idea Thanks

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#8

Re: Rust Detection

04/11/2008 9:19 PM

I'm a bit rusty (excuse the pun) on chemistry, but I think you could lightly spray the surface with something that will react with the oxygen in the rust. You would want to use something that would produce a visible reaction, so that a field hand could use it.

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#13
In reply to #8

Re: Rust Detection

04/14/2008 8:00 AM

Correct - I believe I have a response that has provided the answer --Thanks

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#9

Re: Rust Detection

04/11/2008 10:56 PM

Mate,

Try using a rust converter. It is basically concentrated phosphoric acid. Turns iron oxide into iron phosphate. you will notice virtually straight away. Cheap.

Try Septone Rust Converter. Cheap about $10-20 a 250ml bottle, from your local car parts store

Used it on my EJ Holden Station Wagon. Just be careful about using it as it may fade you duco if your not careful about spills, or drops.

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#14
In reply to #9

Re: Rust Detection

04/14/2008 8:09 AM

Thanks - I believe this would correct the problem and provide evidence the stain is infact iron oxide. I suspcet we could swab some on the surface to performt he test.

Thanks for your information

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#10

Re: Rust Detection

04/12/2008 1:44 AM

The Potassium Ferricyanide test is old but reliable. There is some information here.

http://www.waterjetting.org/test.htm

The Potassium Ferricyanide solution should turn the brown spots blue very quickly if in fact they are rust.

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#15
In reply to #10

Re: Rust Detection

04/14/2008 8:13 AM

Thanks for the info - I checked out he site - very interesting approach. will pass this on to our field rep.

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#12

Re: Rust Detection

04/12/2008 1:39 PM

what is the possibility of using a rust remover such as oxalic acid?

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#16
In reply to #12

Re: Rust Detection

04/14/2008 8:16 AM

I will look into this - thanks

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