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Converting the Specific Gravity of Water

01/26/2009 8:26 AM

I have been searching for a formula to convert the specific gravity of a water sample to Sodium Chloride content in mg/L (ppm) at any given temperature. I have been searching for an answer for weeks...

For example: I have a water sample with a sp.gr. of 1.125 at 75F (24C). How do I convert it to NaCl content in mg/L?

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#1

Re: How do I convert Sp.Gr. to NaCl (mg/L)

01/26/2009 8:53 AM

mavrick22c,

There may be a table somewhere. I doubt that it would have densities of saltwater at more than a couple of different temperatures (probably just one - 20 or 21ºC). Try the CRC Handbook of Chemistry and Physics. It is found in the reference section of most libraries.

Mike

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#22
In reply to #1

Re: How do I convert Sp.Gr. to NaCl (mg/L)

10/14/2009 9:34 AM

141.5

API=--------- -131.5

sp gr 60F/60F

for gas is air

for liquid is water and i want sp gr water in 60 F?????????????????????????????/

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#2

Re: Converting the Specific Gravity of Water

01/26/2009 11:43 PM

Some links I've seen on a snow and ice forum:

http://seagrant.oregonstate.edu/sgpubs/onlinepubs/h99002.pdf

http://www.iowadot.gov/maintenance/internetpages/chemicals/index.htm

Not exactlly what you're looking for, but maybe a jumping-off point in the right direction?

Maybe a salt producer or a salt-water fish store could help out some?

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#3

Re: Converting the Specific Gravity of Water

01/27/2009 12:13 AM

Hello mavrick22c,

I am not sure what you want this for?

But I think I may have found the answer. The salt content is directly related to Electrical Conductivity.

You may have to rework the way you do things but you will find your answer. Or from what I understand you will.

The Total Dissolved Solids (TDS), which in sea water is almost all Sodium Chloride (NaCl) is directly related to its Electrical Conductivity (EC). I do not think there is a relation between the Temperature of water and its Salinity or therefore its EC. As long as the water is not so hot as to start to boil and evaporate, leaving some NaCl behind. In that case the readings and estimates would constantly change.

If the water you want to test if very hot, take a sample and stop any evaporation by putting it in a container with a lid. When it cools or even gets cold, you can check the TDS and EC or visa versa.

To estimate the TDS from the EC reading you need to multiply the reading 0.56. To estimate the EC value from the TDS value you divide by 0.56.

The piece below explains and I have listed the site as well.

Lists the various Compounds and Chemicals in water and their properties. It is listed and very easy to follow. You will find mention of the measure of EC in water with dissolved solid in the list as well.

==========================================

This site: http://www.idswater.com/Common/Paper/Paper_212/RO%20Water.htm

This site should explain why you may be getting sediments and what they may be.

"Conductivity: Conductivity is a measurement of the ability of water to transmit electricity due to the presence of dissolved ions. Absolute pure water with no ions will not conduct an electrical current. Conductivity is measured by a conductivity meter and is reported as micromhos/cm or microSiemens/cm. Conductivity is a convenient method of determining the level of ions in a water but is non-specific in what the ions are. The electrical conductance of ions will vary by ion and will decrease as the concentration of ions increase. TDS (Total Dissolved Salts) meters utilize conductivity measurements with a conversion factor applied. Conductivity can also be estimated using individual conversion factors from the reported ion concentrations of a water analysis or by using a single conversion factor based on the sum of the ions (TDS). Carbon dioxide conductivity can be estimated by taking the square root of the ppm concentration and then multiplying by 0.6. The silica ion does not contribute to conductivity. The most accurate conductivity readings for high quality RO permeate are obtained on-site since carbon dioxide levels, being a gas, can vary when exposed to the atmosphere".

========================================

http://www.sa.waterwatch.org.au/sw_salinity.htm

  • Salinity Fact Sheet (660KB PDF) - this includes:
    • What is salinity
    • How does it occur
    • The main causes of salinity
    • The impacts of high salinity
    • Facts on the how salinity affects Australia
    • Information on how to measure salinity
    • Ideas about what you can do to help control salinity.
  • More Information Fact Sheet (272KB PDF) - this includes:
    • Website links for more information on salinity
    • Resources to help you learn or teach about salinity

How is salinity measured?

Salinity can be measured in a variety of ways. For the purpose of Salt-watch all groups are encouraged to measure salinity in Electrical Conductivity (EC) units, also known as micro-siemens per centimetre (uS/cm). If your group uses equipment, which measures in another unit then conversions will need to be made.

Electrical conductivity is the property of a substance, which enables it to serve as a channel or medium for electricity. As salty water conducts electricity more readily than pure water, electrical conductivity is a suitable measure of salinity.

How do I convert my salinity readings into EC Units?

To convert readings that are in milli-siemens per centimetre (mS/cm) the reading is multiplied by 1000. For example, a reading of 0.20mS/cm would be 200EC or uS/cm.

To convert readings which may be in parts per million (ppm) or mg/l which is an estimate of the Total Dissolved Solids (TDS) in the solution - a conversion is required. In South Australia, there is a conversion table that is used by Waterwatch programs, which is based upon a conversion factor of 0.56.

To estimate the TDS from the EC reading you need to multiply the reading 0.56. To estimate the EC value from the TDS value you divide by 0.56. For example, an EC reading of 700 would be multiplied by 0.56 to obtain a TDS value of 392 ppm. To convert 392 back to EC units you divide the value by 0.56 to get 700 EC units.

======================================

Micromhos to Microsiemens Conversion Calculator

Use the following calculator to convert between micromhos and microsiemens. If you need to convert micromhos to other units, please try our universal ...
www.unitconversion.org/electric-conductance/micromhos-to-microsiemens-conversion.html - 8k - Cached - Similar pages

Hope this helps

Take care................

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#9
In reply to #3

Re: Converting the Specific Gravity of Water

01/27/2009 6:37 AM

I appreciate your info on electrical conductivity (EC) and its relationship with NaCl when dissolved in water (which I was aware of but definitely not to that extent) but the only tools I have are:

1.) 1000 ml beaker

2.) Hydrometer set (Specific Gravity calibrated at 60F)

3.) Thermometer

And the water sample comes out of a natural gas well between 110 – 120F. I allow it to cool 75F and then drop in a hydrometer to determine the specific gravity. With this information, I reference a chart to determine the Sodium Chloride content in the sample. Testing for the level of NaCl content can determine the "health" of the well.

The reason I am looking for the formula to convert Sp. Gr. is that I have recently discovered that the chart that I am using may not be very accurate and I would like to create a new one in Excel. I also want to be able to enter any given temperature. I have everything set up in Excel except one vital component, the formula to convert Sp. Gr. to NaCl mg/L

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#12
In reply to #9

Re: Converting the Specific Gravity of Water

01/27/2009 8:15 AM

Hello vincenzo, you sound like me not trusting what charts you use. Especially importation if you use wikki as they can be edited. You may have already done this, but, you can start making a chart by measuring you well water every degree it cools from boiling to see if there is any difference. Do the same with distilled water and see the difference also. Sorry I have to go but, you have the stuff tesser gave you and the sights and definite way of working things out. You just need to focus now. that, and buy another couple of beakers and an evaporator? Good luck and keep in touch.......................

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#16
In reply to #9

Re: Converting the Specific Gravity of Water

01/27/2009 6:43 PM

Hello mavrick22c:mavrick22c:mavrick22c:mavrick22c:

My punishment, must write 1000 times your name is mavrick22c! Not vincenzo!

Sorry Mavrick22c, I was trying to sent a lot of short posts and sent you one with another correspondents name. Please forgive me? It was at a time I was getting the IE freeze repeatedly, and was trying to rush to send as much as I could before the next crash!

Sorry once again.

Take care and good luck..................

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#17
In reply to #16

Re: Converting the Specific Gravity of Water

01/27/2009 7:55 PM

Not a problem at all. I simply thought you were referring to someone else. As for your IE issues, why not try Mozilla Firefox? I'm extremely prejudice against IE.

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#18
In reply to #17

Re: Converting the Specific Gravity of Water

01/27/2009 10:11 PM

Hello mavrick22c,

As for your IE issues, why not try Mozilla Firefox? I'm extremely prejudice against IE.

With regard to this I was thinking of either getting a cheap laptop or, even a mac rather than have these constant problems. That I could handle, it is when you have to 'jump through loops' on the Microsoft site, then they just send you round in a circle? You end up back at the same page after following their advice.

I really need another computer to allow me to get this one back to A1 condition. I have XP on it at the moment but I can always get Firefox.

What has your experience been with Mozilla/Firefox?

Take care................

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#20
In reply to #9

Re: Converting the Specific Gravity of Water

01/29/2009 8:58 PM

You can buy a TDS meter for about $15.00.

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#4

Re: Converting the Specific Gravity of Water

01/27/2009 3:05 AM

The NaCl content is approximately 17 per cent. If you want a more exact figure, weigh a known volume sample of the solution (say 100ml) and evaporate to dryness. you should then have around 17 grams of solids left.

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#10
In reply to #4

Re: Converting the Specific Gravity of Water

01/27/2009 6:49 AM

Sorry, but that was not the question. That was just an example. You are correct though. I also carry with me a refractometer. It tells me the %NaCl in the sample and with that I can calculate the mg/L but the refractometer does not give me the level of accuracy that I am looking for.

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#5

Re: Converting the Specific Gravity of Water

01/27/2009 4:39 AM

If you are talking about solutions of Sodium Chloride in water, then Perry's Chemical Engineers' Handbook gives a table of densities of Sodium Chloride solutions (as well as a lot of other compounds) in water from 1% to 26% NaCl at various temperatures from 0 to 100 Deg. C.

You could input the data into Excell and use the 'add trendline' feature to determine equations.

If you are talking about sea water then information can be found in Section 2.7.9 of Kaye and Laby available at:

http://www.kayelaby.npl.co.uk/toc/

The Corrosion Handbook edited by Herbert H. Uhlig also gives information about sea water properties.

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#7
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Re: Converting the Specific Gravity of Water

01/27/2009 5:38 AM

tesser,

That was my first thought exactly. My mind went right to Perry's Handbook page 3-83. For some reason after almost 20 years I still know what page that information is on (Sixth Edition). GA

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#8
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Re: Converting the Specific Gravity of Water

01/27/2009 6:26 AM

Hello tesser,

GA to you for such detailed info'!

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#13
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Re: Converting the Specific Gravity of Water

01/27/2009 8:26 AM

I think this solution awesome, thank you.

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#15
In reply to #13

Re: Converting the Specific Gravity of Water

01/27/2009 9:00 AM

Hello prof vincenzo!..........

So how are you working it out?

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#6

Re: Converting the Specific Gravity of Water

01/27/2009 5:17 AM

A liter of pure water weighs 1000 grams. A liter of your solution weighs 1125 grams. Wouldn't there be approximately 125 grams (125000 mg) of salt in a liter?

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#11
In reply to #6

Re: Converting the Specific Gravity of Water

01/27/2009 6:53 AM

No, the temperature also plays a large role in the equation. Your answer would be true if the sample was 60F.

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#14
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Re: Converting the Specific Gravity of Water

01/27/2009 8:56 AM

From Perry

Tad

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#23
In reply to #6

Re: Converting the Specific Gravity of Water

10/23/2009 8:58 PM

Hi Guest,

I think you are confusing the specific gravity of water with the amount of salinity.

Take care

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#24
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Re: Converting the Specific Gravity of Water

10/24/2009 3:46 PM

Not confused.

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#26
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Re: Converting the Specific Gravity of Water

10/24/2009 7:08 PM

Hi Guest,

Not confused.

OK, fair enough.

Take care.

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#19

Re: Converting the Specific Gravity of Water

01/28/2009 5:47 AM

The specific gravity of a liquid varies with many other things apart from the salt content, like the alcohol content for example, so SG-to-salinity is not the best way to do it.

Conductivity-to-salinity (at a fixed temperature) is a lot easier, and there are a number of previous discussions in CR4 on the topic.

There is an article on the salinity of seawater in Wikipedia [other on-line encyclopaediae are available], which might be of interest, perhaps?

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#21
In reply to #19

Re: Converting the Specific Gravity of Water

02/04/2009 1:06 AM

Hello PWSlack:,

I appreciate the info, thank you. It is not my thread but, I think it is pretty interesting!. Thanks again..............

Take care..................

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#25
In reply to #19

Re: Converting the Specific Gravity of Water

10/24/2009 4:55 PM

Let me explain once more. This time, in more detail. When oil/gas companies search for reserves, they look for salt caps using seismographic data because most oil reserves all old sea beds. After they find a nice place to punch a hole in the ground, they do just that and then "frac" it. This involves pumping anywhere between 30k bbls (1,380,000 gal.) to 160k bbls (7,360,000 gal.) of fresh water down into the well. Mixed in the water is a large part sand plus a small part various chemicals (no alcohol) to reduce friction as the mixture travels down the well. When the process of "completion" is done, then the well is ready to open. This is where my job comes in. Because they pump so much water down the hole, it's basicly a water well when we first open it up. My job is to get this water out of the well so the gas can make its way up. Some flow water on thier own until the gas hits, some need help and may flow water for weeks until they hit gas. The entire time I'm out there trying to get the well going, I collect a large amount of data to send off to the gas company each day. Amoung this data is salt content or "chlorides" (as they say in the oil field) or salinity. How ever you wish to call it. The amount of salt content in the water can tell a person the health of the well. The Barrnett Shale (Name of the underground formation or layer of rock that contains the gas) is in between two auqifers. A freash water one on top (can't recall the name at the moment) and a salt water one below (Ellenburger.) If they frac into either of these, depending on how sever, could render a well useless and goes about $2.2 million down the drain. (The idea of it all is to get the water OUT of the formation.) 60,000 ppm to 80,000 ppm This is a good sign that the salt is mostly coming from the salt cap or salt in the formation. Too low means may have tapped into the freash water table. Too high means may have tapped into the salt water table.

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#27
In reply to #25

Re: Converting the Specific Gravity of Water

10/24/2009 7:30 PM

Hi Guest,

Appreciate the detail, thanks.

The problem is, if the 'Trinity-Woodbine' aquifer is hit or it collapses there is a serious problem to the supply of fresh water to Texas!

Thanks for your post.

Take care

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#28
In reply to #27

Re: Converting the Specific Gravity of Water

10/25/2009 1:01 AM

Okay... I'm not seeing how that applies to anything I've mentioned... maybe I missed something...

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#29
In reply to #28

Re: Converting the Specific Gravity of Water

10/25/2009 1:33 AM

Hi Guest,

That was the name of the fresh water aquifer under a good chunk of Texas, which you said you could not recall the name of?

Or have I got this totally screwed?

Take care.

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