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How Do Batteries Work?

04/25/2010 2:20 AM

Energy storage is becoming serious business with concerns for global warming. Any battery we know of takes 8 to 10 hours to charge and that is unacceptable.

Capacitors do not need such a long time to charge. But charge storage capacity of capacitors (even considering Ultra-caps and Super-caps etc is too low. These Ultra caps/ Super-caps can be charged in a short time without nay current limiting series resistance. Capacitor works on the principle of charge stored on the electrodes with die-electric between the electrodes aiding to increase electric field density. C = Eo* Er* A/d.

But how do batteries work? They do not follow capacitor equation !! Where is the charge stored? Is it in the rejuvenated chemical inside it?

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#1

Re: How do batteries work?

04/25/2010 3:07 AM

The best outcome for this question will be if some top electrical engineers/technologists from India address it.

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#2

Re: How do batteries work?

04/25/2010 9:06 AM

Lithium-Ion 100% depth of discharge. 1-2 hour charges.

Super Caps. I agree are the way to go but have their issues in power conditioning. The larger caps which could run cars or households still have some time before they hit the retail market.

The lead plates, the electrolyte, and the container do the storage. The lead plates will absorb the charge. (that's a little simplified) There is a formula somewhere. Learned it once never used it again!

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#4
In reply to #2

Re: How do batteries work?

04/25/2010 10:06 AM

In electrostatics - we know charges are on the plates or electrodes. Now let me push the idea a little further.

Can I take charged plates out of a battery container, and place it in another container with fresh electrolyte? What happens to the charges?

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#3

Re: How do batteries work?

04/25/2010 10:04 AM

Sigh. If this thread doesn't deserve a homework flag, I don't know what does.

Batteries work by a variety of chemical reactions. The specific chemical reaction will, of course, vary with the type of battery one has. As you may remember from elementary Chemistry; many chemical reactions are not reversible at all, some are reversible with the addition of the correct energy and/or catalyst, while some chemical reactions easily reverse and a balanced equilibrium occurs of agents and reagents exist simultaneously.

Now a capacitor must certainly rely on the laws of Chemistry to exist, stay assembled and function properly; the energy storage mechanism is not a chemical reaction. A chemical reaction in a capacitor is the most common long term cause of capacitor failure and thus MTBF values can be calculated using the Arrhenius equation.

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#5
In reply to #3

Re: How do batteries work?

04/25/2010 10:35 AM

Let me explain why I am pushing this idea further. It is not for fun.

  1. We all know all kinds of batteries take about 8 to 10 hours to charge and for this reason electric vehicles have not been commercialized. Batteries are also bulky (to enable vehicle to travel longer distances with single charge).
  2. Today to top up my tank in a petrol engine, we drive down to a petrol station and just fill tank in a few minutes and drive away- and do even 1000 or more kilometers with a single filling.
  3. Unfortunately battery based vehicles need 10 hours to charge up.
  4. One way of over coming the problem is - I drive down and change over to fully charged new battery every time
    1. It is expensive.
    2. Take another case - where the charges are in chemical / dielectric and not on the plate.
    3. What prevents me from removing / sucking out old chemical and refilling with pre-charged chemical- all in a few minutes?
    4. OR if you say charges or on the plate and not in the chemical, I will take out plates and put charged plates- all in a few minutes.
  5. I would have achieved my objective of charging battery in a shorter time.
  6. Energy filling stations can use those plates or chemicals and charge them separately.

CAN I DO THIS???? So I really look forward to Chemical Engineers, Electrical engineers to look at battery design from thsi point of view.

I am also aiming at another solution if the two above do not work.

So the problem posed is definitely aimed at finding some solving serious issues related to batteries.

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#6
In reply to #5

Re: How do batteries work?

04/25/2010 11:29 AM

Did you honestly think that you are the first to notice this desire? Explaining to us your frivolous desires to any level of detail will not inform you why your fantasies cannot be achieved today, if ever. Clearly you not only do not know any recognized relevant theory about how batteries function. You also refuse to learn anything about them. Nobody can help those who refuse help. I don't know if Tornado's assertion that you will listen to a fellow Indian or if not even a compatriot will get through your head.

I believe I have a reasonable amount of patience and understanding of other people and cultures. I work daily with people from all corners of this planet. But your impudence on this and several other threads has worn away my patience with you. Until you are willing to demonstrate some capability to learn from others ...

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#23
In reply to #6

Re: How do batteries work?

04/26/2010 10:14 AM

Me too.

And with the qualification of OP I wonder .

The quality of question (in fact most of them) is not commensurate with the qualification. With 38 years experience - just my gen.

But then the batteries were taught in class 11-12 (of course not the NiCd ones only the old fashined dry cell and the lead Acids) - the rechargeable dries were nowhere in horizon then.

The OP is still in the field as per the bio - then .

BTW: it is quite tiresome for an Indian too.

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#7
In reply to #5

Re: How do batteries work?

04/25/2010 3:31 PM

Sorry but all your ideas are wel known and none of them work.

Engineers have tried for years to make batteries lighter faster charging etc.

even an idea where you drive to a recharge place and swap you discharged batteries for a set of charged batteries fitted in a quick change battery case.

it is possible to dry charge plates then imerse them is electrolyte but this would be dangerous at a filling station.

most batteries are shipped dry charged and filled with electolye befor final sale.

but there is a 2 hour delay before battery can be used

http://www.ag.ndsu.edu/pubs/ageng/safety/ae1022w.htm

http://www.tpub.com/content/batteries/TM-9-6140-200-14/TM-9-6140-200-140069.htm

http://www.concordebattery.com/otherpdf/drycharg_msds.pdf

http://www.batteryuniversity.com/partone-13.htm

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#11
In reply to #5

Re: How do batteries work?

04/26/2010 12:31 AM

So what if batteries are bulky? It might make the vehicle heavier, but so what? You still save 80% by using electricity instead of petrol. However, you had some clear questions that I think I can answer.

When two chemicals react, they often produce electricity. Example, iron and oxygen, the simplest battery of all. (it is known as an "edison battery") Sometimes the reaction is one way...when the iron rusts away to nothing, there is no more electricity produced. If you don't allow the electricity to dissipate, the rust will stop. If you use the electricity produced by the rusting of the iron, the reaction will continue. So here is your first principle.... electrical production in a battery is a by-product of controlled corrosion.

Other materials corrode faster, or better, and other chemicals may assist the reaction. Lead, lead oxide, lithium, Nickel and Cadmium all corrode in their respective electrolytes in exactly the same way. An electrolyte may contain chemicals to assist this reaction, (a lead acid battery) or may simply carry ions between the two poles of the battery. (an edison battery) The technology is old, tried and proven. But if you wish to reverse the reaction, to turn rust back into iron again, it takes time and a lot of energy. More energy than you will get from the reaction in the first place. Often much more. So we usually use different metals which are more efficient. Here we are not storing electricity, we are creating a "reversible chemical reaction". Not the same thing at all! That is your second principle.

Now lets talk about the lead acid battery...the most common battery in use in the world. A little heavy, but reasonably efficient, easy to get, easy to replace, come in standard sizes, easy to re-cycle when they are damaged or sulphated.

The important chemicals are the metals, not the electrolytes. If you were to take a fully charged battery, and pour off the electrolyte, and replace it with fresh electrolyte, you would make no difference. Maybe the new stuff is a little cleaner than the old stuff, but chemically it is pretty much the same. If you examined the electrolyte of a discharged lead acid battery, you would find it was mostly water. The act of discharging the battery changes some of the acid in the water-acid solution into water. Pouring off that water and replacing it with fresh acid would not re-charge the battery....the plates formerly lead and lead oxide respectively will remain lead sulphate, and the lack of chemical difference between them means they will no longer react with each other. They would remain discharged. You must reverse the chemical reaction, in a process called "charging". However, as you charge the battery, the acid solution would get stronger and stronger until it is so strong that it will actually damage the battery. So don't do that. (The reaction is a bit more complex than that, but it doesn't matter, the results are the same.)

A battery is a complex and delicate item...and it is difficult to suck out the solutions and replace them without damaging or stirring up something nasty from the bottom....similarly it is difficult to pull out plates and replace them without damaging them. Far easier to have batteries which can be easily pulled out at the filling station, and replaced with similar ones like propane tanks in a narrow boat. Batteries on most airplanes (for instance) only take two minutes to change. Filling stations can have dozens of batteries on charge, ready to be swapped out at a moment's notice. I don't think this is an engineering problem so much as it is a matter of political will. If you start a battery co-op, you can get like minded individuals to stock batteries for your use all over the city. Nothing stopping you, no new technology needed.

I think the direction you should be bending your research into is "fuel cells". These have potential, and can be "charged" in just the fashion you have described in your post. But, they are NOT batteries. They have their own problems. Please, research fuel cells and come back and talk with us.

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#12
In reply to #11

Re: How do batteries work?

04/26/2010 1:02 AM

I appreciate your answers here and elsewhere. Keep it up!

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#30
In reply to #5

Re: How do batteries work?

08/27/2010 10:41 AM

point #3. There is a "Redox flow battery". the 2 electrolytes can both be pumped out and replaced in minutes and continue on your way. the filling station could actually recharge the spent electrolyte and keep in continous circulation. theoretically anyways.

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#31
In reply to #30

Re: How do batteries work?

08/30/2010 11:39 PM

These are fuel cells. Should work.

Now why do you suppose they have not taken over the battery business? Could it be there are some inherent problems that need to be solved? Just wonderin'

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#9
In reply to #3

Re: How do batteries work?

04/26/2010 12:07 AM

I don't want to seem overly naive, but, what is a homework flag? I am fairly new to this and I haven't seen that term before; I assume, from your message, it is a negative.

Larry

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#10
In reply to #9

Re: How do batteries work?

04/26/2010 12:26 AM

When one talks about a homework flag, one thinks that the question appears to be coming from a student who either needs help with a homework problem because of a lack of understanding of the material or a lack of desire to do the homework him/hser self.

No, it is not a positive comment. After a while you will develop a feeling for questions of this type.

Sometimes it is not a student but an employee who is either lazy or over employed.

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#13
In reply to #10

Re: How do batteries work?

04/26/2010 1:34 AM

Thanks for your explanation. When I first read your message, to be honest, it seemed to be quite intense and impolite. However, I can see why it could become irritating to have someone using the groups to, as you point out, do homework or "job" work for the wrong reasons. I'll try not to do that...

I somehow wound up at your profile while clicking to get to your reply (?). I noticed you are an "RM". I am also; I am from Utah but served in the north-eastern US, after my conversion at age 18. Finished the mission in 1970; married and had 3 kids before getting back to college in 1975, etc. very much like your profile shows. I also am "semi-retired" for reasons due to poor health; I am only 60 though. Small world!

In my case, there is hope I may be able to get back to work, which I am trying to do with great determination. In the meantime, over the past 10+ years I have been struggling, I have used the internet to help keep up with technology (I am an EE; BYU 1978) and also to communicate with thinkers and doers, which is hard to do when stuck at home alone all day etc.; thank goodness for the internet! I've sorely missed the day to day interactions that come with working as a professional engineer.

I will probably ask some unusual questions from time to time, but in my case, it is not due to homework, or anything to do with a job etc. It will be about a new technology I have "invented" during this time of inactivity and poor health. I didn't want to waste my time and I'd had an idea for quite a while I wanted to pursue; after a couple years of feeling sorry for myself and wasting time, I found I could get enthused and fill my days working on it; I would not have been able to pursue it had I not been forced to stop working. I've almost got it ready to patent but, as you probably know, the last 10% of any project can be the most difficult and take more time than the first 90%, as the most stubborn, perplexing issues are often pushed along without being solved to prevent them from stalling the project earlier on. By the time you are 90% or more finished, there is no way to push the issues along any further, so they must be resolved. That is where I am at now, so I may ask for opinions or help at some time in these forums. Is that appropriate for these forums?

My best to you. Do you ever become involved in emergencies and disasters due to your radio hobby?

I will try to find a way to send this separately, but if I can't, it will have to go into the thread marked off topic. If so, I beg your tolerance until I figure out better ways of using these groups.

Larry

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#8

Re: How Do Batteries Work?

04/25/2010 11:19 PM

http://en.wikipedia.org/wiki/Zinc-air_battery

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#14

Re: How Do Batteries Work?

04/26/2010 2:13 AM

Charge time of 8-10 hours is fine for a large number of applications. Many battery systems could be charged faster, like 2-3 hours for lithium-ions, with no damage or reduction in service life. Longer charge times are usually more a function of practical power availability and charger cost.

The specific problem of recharging an EV in 3 minutes, like a typical petrol refueling stop, is a HUGE problem on several levels. Many people, all over the world, have been working on this for decades. Progress is slow, but some advances are being made.

Assuming you already had magic-supercap-batteries, have you even thought about HOW you would provide the charging energy?

A practical EV battery bank should contain about 32 [kW-hr] or 115 [MJ] of energy.

8 [hr] recharge @ 4 [kW]; 220 [V] @ 18 [A] is quite practical for most homes.
2 [hr] recharge @ 16 [kW]; 220 [V] @ 73 [A] is a large load since many older homes here only have a 100 A service.
0.5 [hr] recharge @ 64 [kW]; 220 [V] @ 291 [A] is beyond the typical 200 A capacity of all but a very few homes here.
3 [minute] recharge @ 640 [kW]; 440 [V] @ 485 [A] 3ph is only realistic for commercial/industrial sites.

The logistics and infrastructure needed to safely provide megawatt recharging stations is not a trivial issue. Safety is also a major concern since any mistakes using this level of electrical power will melt your face off before you can blink.

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#15

Re: How Do Batteries Work?

04/26/2010 2:48 AM

You keep trying to get others to come up with a get rich quick scheme for you.

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#17
In reply to #15

Re: How Do Batteries Work?

04/26/2010 3:35 AM

Capacitors are the electrical equivalent of a spring. They store energy by a progressive accumulation of charge with increased voltage and reach their limit at the insulator breakdown point. They are also governed by the problem that the voltage declines to zero as they charge is consumed in a straight line, so the load will have to tolerate a variable voltage, or a built in circuit will stabilize the output to a regulated voltage. Once the voltage falls below the useable voltage, the rest of the charge cannot be used. bateries create a voltage that depends on an electromotive chemical transition and the voltage is constant until the chemical (charge) is consumed and it goes to zero, more or less.

http://en.wikipedia.org/wiki/Capacitor

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#16

Re: How Do Batteries Work?

04/26/2010 3:30 AM
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#18

Re: How Do Batteries Work?

04/26/2010 5:50 AM

Batteries are still a mystery to the scientific world, the math does not complete an equation. Ha

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#19

Re: How Do Batteries Work?

04/26/2010 6:03 AM

Here is a simple answer. In certain chemical reactions called oxidation-reduction reactions, one substance gives up electrons (is oxidized) and another substance accepts the electrons (is reduced). These electrons are made to flow through an external circuit where they give up energy which was stored chemically in the battery. In a rechargeable battery, the process is reversed where the electrons are forced back into the original configuration.

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#20
In reply to #19

Re: How Do Batteries Work?

04/26/2010 7:49 AM

He is looking for someone to come up with a workable idea for him - for free. He cares less how the things work.

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#21
In reply to #20

Re: How Do Batteries Work?

04/26/2010 8:33 AM

Thank you russ123,

You precisely pointed out the reason of my foul mood with this individual. I can tolerate people who pay my salary making money from my knowledge. I am eager to share my knowledge with those willing to learn. I accept that I can be tricked into helping somebody I despise into making money. But I will not tolerate anyone trying to profit from me that won't even buy me a beer.

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#24
In reply to #20

Re: How Do Batteries Work?

04/26/2010 10:16 AM

Hey Russ, I want to get rich too what else have you got??????????

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#25
In reply to #24

Re: How Do Batteries Work?

04/26/2010 10:20 AM

Already tried my ideas and they didn't work so İ am stuck as a poor slob!

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#22

Re: How Do Batteries Work?

04/26/2010 9:31 AM

Suggestion: Read about batteries basics before you post.

8-10 hrs is completely wrong. LI batteries are on the market that can be charged in 10 minutes (search A 123).

But how do batteries work? They do not follow capacitor equation !! Where is the charge stored? Is it in the rejuvenated chemical inside it?

To confirm your understanding: you are correct, batteries to not follow the capacitor equation, and that is indeed a shocker !! About the "rejuvenated chemical": no one outside the alchemist society is allowed to know this. For consumption by ordinary engineers: The charge is stored in magichrons.

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#26

Re: How Do Batteries Work?

04/26/2010 11:34 AM

Go to YouTube. Type in MIT. Choose the appropriate lecture. Pay close attention to the part that the professor takes apart a Leyden jar then puts it back together.

Watch all their lectures, it will help!

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#27
In reply to #26

Re: How Do Batteries Work?

04/26/2010 11:49 AM

Won't help. If he cannot make a million rupees ripping people off with public information he cannot grasp, it doesn't interest him. He's just a salesman. One day he'll commit his company to something that is theoretically possible but financially impossible. The company will fold and he'll blame the engineers as incompetent.

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#28

Re: How Do Batteries Work?

07/19/2010 8:02 PM

Maybe someone can uncharge Nature for its part in Global Warming:

http://naturesglobalwarming.blogspot.com/

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#29
In reply to #28

Re: How Do Batteries Work?

07/20/2010 9:46 AM

A remarkable blog entry. From a brand new blog.

It will take a lot of evidence to the contrary to convince ME that less smoke in the air might not be a good thing.

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