I can't see any way in which you would be able to easily determine the concentration directly. But what about trying a two step reaction where the sulphates are first precipitated and removed from the solution after which a cation analysis on the aluminium can be done. This should give you a total aluminium concentration which you can rework to Al2O3 concentration by using the sulphate concentration you calculated in the first step.
I'm not a chemist so I have no idea whether this will work but if you're struggling it might just be worth a try.
Also, procedures for both these analyses should be easy to find in almost any analytical chemistry textbook. (I have Vogel's Textbook of quantitative inorganic analysis.
Good luck
Rgds
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