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Anonymous Poster #1

Thermal Storage

03/25/2011 10:35 PM

Has anyone any thoughts or ideas how to store energy from a Solartron water unit. Too bad we couldn't store the energy for winter use. All I can think of is sending the energy into the well that supplies the heatpump system ????

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#1

Re: Thermal Storage

03/26/2011 10:31 AM

Water has a high heat capacity (specific heat), which makes it useful for transferring and storing heat energy. However, seasonal (rather than daily) energy storage still requires a large amount of water, and the large volume must be insulated to keep the stored heat from dissipating into the surroundings. This is usually too expensive to be useful. You could inject warm water into a well, but some of the water would leak away into soil porosity, and over a long time much of the heat would also be conducted away.

There might be some possible but unusual situations that would enable decent heat storage for a while, but for the most part it is not practical or efficient on a long-term basis. As thing stand at the moment, pumped storage and batteries are the best medium-term storage methods, and there are some possible uses of flywheels or capacitors, but even these methods are best for only fairly short-term storage.

I don't claim any crystal ball for the future, but I wouldn't anticipate much improvement of this situation.

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#2

Re: Thermal Storage

03/26/2011 11:01 PM

you can store heat from a solartron in a phase change energy storage unit.

This is something you melt at the high temperature, and keep in an insulated box, and when you want the heat, you circulate water and the material freezes and you draw off the heat until it is all frozen. Now water expands on freezing and has zero C, so it is not quite what you want. Glaubers salt is another. Here is a list of others.

Phase change heat storage links

Now day to night is short term, summer to winter is long term. Long term requires very good insulation and a large enough mass to store the heat you require.

The old measure of freezers and tons is based on the water they freeze in a day. One ton = 1 ton per day. The latent heat of fusion for ice is 144 BTU/lb. For one ton, that is 2000 lb times 144 BTU per pound, or 288,000 BTU. which is 12,000 BTU per Hour required to make one ton of ice in one day.

So if you want 6 months of cooling from ice water at 12,000 BTU per hour = 183 ton of ice in your basement. The reverse is what is needed for heating. Water has higher heat of fusion than most materials, so figure you need 400 tons of PCM to do the job.

this will take a space of ~12,800 cubic feet, well insulated with 20 inches of foam.

This is a box about 24 feet on a side, or a 40 x 40 basement 8 feet deep, or 42 x 42 x 10 with insulation. Of course, you will also need a network of tubing in this volume to circulate the fluid by which you add/subtract the heat, and pumps etc. Now you can reduce this by using the solartron in the winter, most places outside the arctic/antarctic have some sunny days in winter. This will mitigate the size of the tank. This can also be used for air conditioning, with a cold phase change material that freezes without expansion at some low temperature where you have enough cold days to freeze this mass.

A simple well - you can see that a 6 foot well will need to be quite deep to hold 12,800 cubic feet of water and would also have to be insulated.

deep wells can be used for heat pumps, as both heat/cold sinking, in that case the mass of earth close to the well is the thermal mass you use, but that is another topic.

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#8
In reply to #2

Re: Thermal Storage

03/29/2011 9:25 AM

You are suggesting that this could be a cost effective solution? Or a theoretical possibility?

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#3

Re: Thermal Storage

03/26/2011 11:09 PM

Swimming pools have been used as heat sinks for heat pumps (cooling the house, heating the pool). Before long the pool becomes too warm, however. Ideally, the too warm point would come at the end of the season, when you could extract heat to warm the house.

People have buried rocks underground (in a volume about the size of a basement for the house) and insulated the outside of this chamber. Hot air is pumped in to warm the rocks, and then the rocks are used for subsequent heating, often for many cold days without sunshine. A similar thing could be done with water, although I suspect that a water to air heat exchanger (and the use of rocks) might be more economical.

Warming the well and the ground around it might have a beneficial effect, if you live where it is cold much of the year. But you'd have to think hard about it, if your heat pump is used much for cooling (for which you want the ground cold).

As I ramble on here, I am probably restating what Tornado has stated... it is hard to make use of stored low grade heat on a long term basis. For supplying heat at night, however, the systems like rock storage or interior thermal mass (large concrete interior walls), etc, can work well.

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#4

Re: Thermal Storage

03/26/2011 11:44 PM
  • What can be done, and what can be done with feasibility are two different things.
  • A great rule of thumb is to match production with demand so that you can achieve maximum efficiency, or put another way,
  • don't store energy, only fuel.
  • storing heat for long periods is very expensive versus producing it.
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#5

Re: Thermal Storage

03/27/2011 6:42 PM

There are other ways of storing heat that do not involve any losses on standing. These are "chemical heat storage" methods. Much work has been done by the Germans and Israelis for decades. Here are a couple of examples:

1) Heat (from a solar concentrator for instance) is used to dehydrate magnesium sulphate heptahydrate (MgSO4.7H2O - "Epsom Salts") in an endothermic reaction. The anhydrous material and water are stored separately. During the winter, the two reactants are brought together again. The reaction is exothermic and the heat evolved is used for space heating.

2) Gaseous reactions such as methane and steam plus heat produce carbon monoxide and hydrogen, which are stored. Upon recombination with a catalyst, heat is evolved and the reactants restored.

Experimental work is in progress on inorganic hydroxide/oxide reactions, the decomposition of ammoniated salts, sulfur trioxide decomposition, ammonium sulfate decomposition and others.

I realise that these are not suitable for most home experimenters, but maybe one of these days some enterprising company will commercialise one of them and we will realise our dream of free, non-polluting heating. Bring it on!

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#6

Re: Thermal Storage

03/29/2011 6:08 AM

Oh for goodness sake - until someone invents the perfect insulator - or an infinitely zero loss chemical store - put it up a mountain - or above a hole and recover it via gravity.

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#7
In reply to #6

Re: Thermal Storage

03/29/2011 9:22 AM

Recover what? When "you put it up" you just spent some energy, and you won't get it back on the way down. Anybody who has built thermal storage knows of significant BTU relative losses, in addition to minor pumping losses. It still works, but don't kid yourself, you'll not get out what you put in. Anybody who denies this is not being very transparent, which is the basis for innovation and improvement. I see a close parallel in the WVO movement. Guess where the denied losses are? Labor! Just because you think something is neat, doesn't mean you get it for free.

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#9
In reply to #6

Re: Thermal Storage

04/05/2011 9:27 AM

Turbine generation seems effective...how does one get a home based turbine system that is cost effective or in neighbourhoods at least to minimize power transmission losses and maintenace of the thousands of km of wire strung across all contin=ents with step up and step down modulating transformers requireing replacement at regular intervals..Yes gravity feed of falling liquid through a turbine seems the best approach long term..This is in response to put it up a mountain or above a whole..:)

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#10

Re: Thermal Storage

04/09/2011 5:53 PM

I haven't done any calcs on it, but here are my thoughts:

If it is for new building construction maybe a grid of metal pipes in the ground under the new building would heat the ground in the summer. This should reduce floor heat loss for awhile in the fall/winter. Not sure if the pipes would benefit from fins or not, or if so, what the size/spacing should be. Might be best if the perimeter of this heated section of earth was insulated so the heat did not go out horizontally so quickly. Also, a horizontal layer of insulation at grade level around the building perimeter would be needed. Doubt it would be real practical, but that's one idea.

Another idea would be if the heat was of high enough grade to produce electricity (doubt it) then you could power grow lights to grow plants (food), can them, and eat them in the winter. Of course, in the summer, you don't need grow lights to grow plants if you have land exposed to sunlight! This unit might generate the electricity you would need:

http://www.stirlingenergy.com/

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#11

Re: Thermal Storage

04/16/2011 7:12 PM

Here's a link with info on Thermal Storage:

http://en.wikipedia.org/wiki/Seasonal_thermal_storage

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#12

Re: Thermal Storage

04/16/2011 7:25 PM

One other idea:

If you can use the heat to separate out a gas or other chemical that can be stored and burned later, you might do that. For example you could use power from PV panels or a dish-type collector (www.stirlingenergy.com) to create hydrogen via electrolysis; and burn the hydrogen later. Don't blow yourself up.

Electrolysis: http://en.wikipedia.org/wiki/Electrolysis

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#13

Re: Thermal Storage

12/23/2011 5:56 PM

There has been a new development on heat storage using wax(Parafin) and graphite.

Google "CCNY's Solar Pod Innovative Technology"

"It transfers solar heat via a system of copper pipes coiled within the thick-walled tank filled with a composite powder composed of graphite (like pencil lead) and a paraffin, or wax, that melts inside the tank. The material transfers heat well and can store it for days. "So what we have now is a very powerful thermal battery that can drive our cooling machine, or heating or whatever is needed," says Professor Gonzalez."

They mention at least 2 days heat storage in a small package and give the figure of 10 Kilowatts. The construction seems low - tech as well.

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